公开(公告)号：US10017592B2

公开(公告)日：2018-07-10

申请号：US15397805

申请日：2017-01-04

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Jeff F. Greco ,  Max P. McDaniel ,  Youlu Yu ,  Gary L. Glass ,  Tony R. Crain

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are ethylene-based polymers having a melt index less than 50 g/10 min, a ratio of Mw/Mn from 4 to 20, a density from 0.90 to 0.945 g/cm3, and a substantially constant short chain branch distribution. These polymers can be produced using a dual catalyst system containing a boron bridged metallocene compound with a cyclopentadienyl group and an indenyl group, and a single atom bridged metallocene compound with a fluorenyl group.

公开(公告)号：US20170283521A1

公开(公告)日：2017-10-05

申请号：US15622114

申请日：2017-06-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Youlu Yu ,  Qing Yang ,  Richard M. Buck

IPC: C08F210/02 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/02 ,  C08F4/65912 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.

公开(公告)号：US09645066B1

公开(公告)日：2017-05-09

申请号：US14960047

申请日：2015-12-04

Applicant: Chevron Phillips Chemical Company LP

Inventor： Youlu Yu ,  Qing Yang ,  Paul J. Deslauriers ,  Mark J. Lamborn ,  Yongwoo Inn

IPC: G01N11/04 ,  G01N5/00 ,  C08F110/02 ,  B29B13/10

CPC classification number: G01N5/00 ,  C08F110/02 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08L23/06 ,  G01N11/00 ,  G01N11/06 ,  G01N33/442

Abstract: A method of preparing a polymer article comprising determining a zero-shear viscosity for a polymer sample; sieving the polymer sample to produce a plurality of sieved polymer samples; determining a molecular weight distribution for each of the plurality of sieved polymer samples; determining a zero-shear viscosity for each of the plurality of sieved polymer samples; determining a compositional diversity of each of the plurality of sieved polymer samples based on a ratio of the zero shear viscosity for each of the plurality of sieved polymer samples to the zero shear viscosity for the polymer sample; identifying a polymer sample having a ratio of the zero shear viscosity to zero shear viscosity for the polymer sample of from about 0.5 to equal to or greater than about 3; and preparing a polymer article from the identified polymer sample.

公开(公告)号：US09574031B2

公开(公告)日：2017-02-21

申请号：US14945540

申请日：2015-11-19

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Jeff F. Greco ,  Max P. McDaniel ,  Youlu Yu ,  Gary L. Glass ,  Tony R. Crain

IPC: C08F210/16 ,  C08F4/653 ,  C08F4/6592 ,  C08L23/08 ,  C08F210/14 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are ethylene-based polymers having a melt index less than 50 g/10 min, a ratio of Mw/Mn from 4 to 20, a density from 0.90 to 0.945 g/cm3, and a substantially constant short chain branch distribution. These polymers can be produced using a dual catalyst system containing a boron bridged metallocene compound with a cyclopentadienyl group and an indenyl group, and a single atom bridged metallocene compound with a fluorenyl group.

Abstract translation: 本文公开了具有熔体指数小于50g / 10min，Mw / Mn为4至20，密度为0.90至0.945g / cm 3的密度和基本恒定的短链分支分布的基于乙烯的聚合物。 这些聚合物可以使用包含具有环戊二烯基和茚基的硼桥联金属茂化合物和具有芴基的单原子桥连茂金属化合物的双重催化剂体系来制备。

公开(公告)号：US20170008984A1

公开(公告)日：2017-01-12

申请号：US15194622

申请日：2016-06-28

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Youlu Yu ,  Qing Yang ,  Richard M. Buck

IPC: C08F210/02 ,  C08F210/16

CPC classification number: C08F210/02 ,  C08F4/65912 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.

Abstract translation: 公开了具有茂金属催化剂组分和齐格勒 - 纳塔组分的催化剂体系。 这样的催化剂体系可以含有茂金属化合物，活化剂 - 载体，有机铝化合物和包含负载在氯化镁上的钛的齐格勒 - 纳塔组分。

公开(公告)号：US09102821B2

公开(公告)日：2015-08-11

申请号：US14069469

申请日：2013-11-01

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Youlu Yu

IPC: C08L23/08 ,  C08F4/653 ,  C08F210/02 ,  C08F210/16 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659

CPC classification number: C08L23/0815 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04

Abstract: The present invention provides a polymerization process utilizing a dual metallocene catalyst system for the production of broad or bimodal molecular weight distribution polymers, generally, in the absence of added hydrogen. Polymers produced from the polymerization process are also provided, and these polymers can have a Mn in a range from about 9,000 to about 30,000 g/mol, and a short chain branch content that decreases as molecular weight increases.

Abstract translation: 本发明提供了一种利用双茂金属催化剂体系生产广泛或双峰分子量分布聚合物的聚合方法，通常在不加入氢气的情况下。 还提供了由聚合方法生产的聚合物，并且这些聚合物可以具有在约9,000至约30,000g / mol范围内的Mn，并且随着分子量增加而降低的短链分支含量。

公开(公告)号：US20150141593A1

公开(公告)日：2015-05-21

申请号：US14284689

申请日：2014-05-22

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Jeff F. Greco ,  Max P. McDaniel ,  Youlu Yu ,  Gary L. Glass ,  Tony R. Crain

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are ethylene-based polymers having a melt index less than 50 g/10 min, a ratio of Mw/Mn from 4 to 20, a density from 0.90 to 0.945 g/cm3, and a substantially constant short chain branch distribution. These polymers can be produced using a dual catalyst system containing a boron bridged metallocene compound with a cyclopentadienyl group and an indenyl group, and a single atom bridged metallocene compound with a fluorenyl group.

Abstract translation: 本文公开了具有熔体指数小于50g / 10min，Mw / Mn为4至20，密度为0.90至0.945g / cm 3的密度和基本恒定的短链分支分布的基于乙烯的聚合物。 这些聚合物可以使用包含具有环戊二烯基和茚基的硼桥联金属茂化合物和具有芴基的单原子桥连茂金属化合物的双重催化剂体系来制备。

公开(公告)号：US20140296453A1

公开(公告)日：2014-10-02

申请号：US14306449

申请日：2014-06-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Qing Yang ,  Youlu Yu

IPC: C08F4/76 ,  C08F4/16 ,  C08F2/01 ,  C08F4/52

CPC classification number: C08F4/76 ,  B01J31/2243 ,  C07F7/003 ,  C07F7/28 ,  C08F2/01 ,  C08F4/025 ,  C08F4/16 ,  C08F4/52 ,  C08F4/64158 ,  C08F4/659 ,  C08F110/02 ,  C08F2500/03

Abstract: Catalyst compositions containing N,N-bis[2-hydroxidebenzyl]amine transition metal compounds are disclosed. Methods for making these transition metal compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.

Abstract translation: 公开了含有N，N-双[2-氢氧基苄基]胺过渡金属化合物的催化剂组合物。 还提供了制备这些过渡金属化合物和在催化剂组合物中用于烯烃聚合的方法。

公开(公告)号：US20140243491A1

公开(公告)日：2014-08-28

申请号：US14277140

申请日：2014-05-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Joel L. Martin ,  Albert P. Masino ,  Qing Yang ,  Youlu Yu

IPC: C08F4/76

CPC classification number: C08F4/76 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/12

Abstract: The present invention provides polymerization catalyst compositions employing half-metallocene compounds with a heteroatom-containing ligand bound to the transition metal. Methods for making these hybrid metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.

Abstract translation: 本发明提供了采用具有与过渡金属结合的含杂原子的配体的半茂金属化合物的聚合催化剂组合物。 还提供了制备这些杂化茂金属化合物和在用于烯烃聚合的催化剂组合物中使用这些化合物的方法。

公开(公告)号：US08703972B2

公开(公告)日：2014-04-22

申请号：US13860604

申请日：2013-04-11

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Albert P. Masino ,  Joel L. Martin ,  Youlu Yu

IPC: C07F11/00

CPC classification number: C07F11/00 ,  B01D71/26 ,  B01J31/00 ,  C07F17/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  C08J5/18 ,  C08F4/69 ,  C08F4/78 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

Abstract: A catalyst system comprising a half-sandwich chromium complex, an activator support and an optional cocatalyst. A compound of formula Cp′Cr(Cl)2(Ln), where Cp′ is η5-C5H4CH2CH2CH═CH2 and Ln is pyridine, THF or diethylether. A compound of formula Cp″Cr(Cl)2(Ln), where Cp″ is η5-C5H4C(Me)2CH2CH2CH═CH2 and Ln is pyridine, THF or diethylether.

Abstract translation: 包含半夹心铬复合物，活化剂载体和任选的助催化剂的催化剂体系。 式Cp'Cr（Cl）2（Ln）的化合物，其中Cp'为5-C5H4CH2CH2CH = CH2，Ln为吡啶，THF或二乙醚。 式Cp“Cr（Cl）2（Ln）的化合物，其中Cp”为5-C5H4C（Me）2CH2CH2CH = CH2，Ln为吡啶，THF或二乙醚。