公开(公告)号：US5151473A

公开(公告)日：1992-09-29

申请号：US609680

申请日：1990-11-06

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C08G77/38 ,  C08G77/392

CPC分类号： C08G77/38 ,  C08G77/392

摘要： The invention relates to novel organopolysiloxanes which contain sulfosuccinate groups and consist of average units of the general formula ##EQU1## in which R is the same or different monovalent hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical or monovalent halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, Z is a radical of the formula ##STR1## in which Y represents a radical of the formula ##STR2## R.sup.1 is a hydrogen atom or an alkyl radical having from 1 to 4 carbon atom(s) per radical, M.sup.+ represents a hydrogen ion and/or an alkali metal ion or an ammonium ion, a is 0 or 1, with an average of from 0.03 to 1.0, b is 0, 1, 2 or 3, with an average of from 1.0 to 2.5, and the sum of a+b is no greater than 3, with the proviso that the compound contains at least one radical Z per molecule.

摘要翻译： 本发明涉及含有磺基琥珀酸盐基团并由通式（I）的平均单元组成的新的有机聚硅氧烷，其中R是每个基团具有1至18个碳原子的相同或不同的一价烃基或单价 每个基团具有1至18个碳原子的卤代烃基，Z是下式的基团，其中Y表示下式的基团R 1是氢原子或具有1个 至4个碳原子，M +表示氢离子和/或碱金属离子或铵离子，a为0或1，平均为0.03至1.0，b为0,1,2或 3，平均为1.0〜2.5，a + b的总和为3以下，条件是该化合物每分子含有至少一个基团Z。

公开(公告)号：US5134203A

公开(公告)日：1992-07-28

申请号：US691912

申请日：1991-04-26

申请人： Friedrich Hockemeyer ,  Christian Herzig

发明人： Friedrich Hockemeyer ,  Christian Herzig

IPC分类号： C08L83/05 ,  C08L83/06 ,  C08L83/07 ,  C08L83/08 ,  C09D183/04 ,  C09D183/06 ,  C09D183/07 ,  C09D183/08 ,  C09J7/02 ,  C09J183/00 ,  C09J183/07 ,  D21H19/32 ,  D21H27/00 ,  D21H27/06

CPC分类号： D21H27/001 ,  C08L83/06 ,  C08L83/08 ,  C09D183/06 ,  C09D183/08 ,  D21H19/32 ,  D21H27/06

摘要： Crosslinkable compositions containing(1) An organopolysiloxane having alkenyloxy functional groups and containing Si-bonded radicals Y of the formula--(CH.sub.2).sub.2 --R.sup.1 --(A--R.sup.2).sub.z --O--R.sup.3 --CH.dbd.CH.sub.2, in whichA represents --O--, --S--or ##STR1## group, R.sup.1 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical of a cycloalkylene radical having from 5 to 7 carbon atoms per radical,R.sup.2 represents a straight-chain or branched alkylene radical having from 2 to 4 carbon atoms per radical, which can be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group,R.sup.3 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical, and z is 0, 1 or 2,(2) an organopolysiloxane containing Si-bonded hydrogen atoms, and(3) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.

摘要翻译： 含有（1）具有烯氧基官能团并含有式 - （CH 2）2 -R 1 - （A-R 2）z O-R 3 -CH = CH 2的Si键合基团Y的有机聚硅氧烷的交联组合物，其中A表示-O- ，-S-或基团，R 1表示每个基团具有5至7个碳原子的环亚烷基基团具有1至7个碳原子的直链或支链亚烷基，R 2表示直链或 每个基团具有2至4个碳原子的支链亚烷基，其可被羟基，甲氧基，乙氧基或三甲基甲硅烷氧基取代，R 3表示每个基团具有1至7个碳原子的直链或支链亚烷基 ，z为0,1或2，（2）含有Si键合的氢原子的有机聚硅氧烷，（3）促进将Si键合的氢加成脂肪族双键的催化剂。

公开(公告)号：US5118772A

公开(公告)日：1992-06-02

申请号：US718688

申请日：1991-06-21

申请人： Christian Herzig ,  Doris Gilch

发明人： Christian Herzig ,  Doris Gilch

IPC分类号： C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C08G77/20 ,  C08G77/22 ,  C08G77/38

CPC分类号： C07F7/182 ,  C07F7/0852 ,  C07F7/12 ,  C07F7/1892 ,  C08G77/38

摘要： Novel, alkenyloxy-functional organosilicon compounds are described which contain at least one Si-bonded Y radical per molecule having the formula--(CH.sub.2).sub.2 --R.sup.2 --(A--R.sup.3).sub.z --O--CH.dbd.CH--CH.sub.2 --R.sup.4 (I),in whichA represents --O--, --S-- or ##STR1## R.sup.2 represents a linear or branched alkylene radical having from 1 to 7 carbon atom(s) per radical or a cycloalkylene radical having from 5 to 7 carbon atoms per radical, R.sup.3 represents a linear or branched alkylene radical having from 2 to 4 carbon atoms per radical, which may be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group, R.sup.4 represents a hydrogen atom or an alkyl radical having from 1 to 4 carbon atoms(s) per radical, and z is 0, 1 or 2.The alkenyloxy-functional organosilicon compounds are preferably silanes or organopolysiloxanes.The alkenyloxy-functional organopolysiloxanes can be crosslinked, for example, with ultraviolet light. These organopolysiloxanes can also be used for preparing coatings.

公开(公告)号：US5113006A

公开(公告)日：1992-05-12

申请号：US594791

申请日：1990-10-09

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08G77/20 ,  C08G77/38 ,  C08L83/06 ,  C08L83/07 ,  C09D183/04 ,  C09D183/07

CPC分类号： C08G77/38 ,  C07F7/0852 ,  C07F7/1836 ,  C08G77/20 ,  C08L83/06

摘要： Novel organosilicon compounds containing alkenyl groups and comprising units of the average formula ##STR1## in which R and R.sup.1 are hydrocarbon containing groups, and A is a radical of the formula ##STR2## in which R.sup.2, R.sup.3 and R.sup.4 are hydrocarbon containing groups; x is 0 or 1; y is 0 or 1, with the proviso that the sum x+y is 1 or 2; a is 0 or 1, with an average of 0.003 to 1.0; b is 0, 1, 2 or 3, with an average of 0.0 to 3.0; c is 0, 1, 2 or 3; with an average of 0.0 to 3.0; and the sum a+b+c.ltoreq.4, with an average of 1.5 to 4.0, with the proviso that each molecule contains at least one A radical and a method for preparation of the novel compounds are disclosed.

摘要翻译： 含有烯基的新型有机硅化合物，其包含平均结构式（I）的单元，其中R和R 1为含烃基团，A为下式的基团，其中R 2，R 3和R 4为含烃基 团体 x为0或1; y为0或1，条件是和x + y为1或2; a为0或1，平均为0.003〜1.0; b为0,1,2或3，平均为0.0〜3.0; c为0,1,2或3; 平均为0.0〜3.0; 并且总和a + b + c = 4，平均为1.5至4.0，条件是每个分子含有至少一个A基团和制备新化合物的方法。

公开(公告)号：US5041594A

公开(公告)日：1991-08-20

申请号：US555218

申请日：1990-07-20

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C07F7/08 ,  C08G77/06 ,  C08G77/10 ,  C08G77/20 ,  C08G77/22 ,  C08G77/38

CPC分类号： C08G77/38 ,  C08G77/20

摘要： Organo(poly)siloxanes having Si-linked, conjugated dienyl groups are prepared by adding a secondary or tertiary acetylenic alcohol (1) to an organo(poly)siloxane (2) having at least one Si-linked hydrogen atom in the presence of a catalyst (3) which promotes the addition of Si-linked hydrogen to an aliphatic multiple bond, and then eliminating water by an intramolecular reaction in the presence of an acid catalyst (4) from the alkenol groups of the organo(poly)siloxane thus obtained.

摘要翻译： 具有Si连接的共轭二烯基的有机（聚）硅氧烷通过在具有至少一个Si连接的氢原子的有机（多）硅氧烷（2）中，在 催化剂（3），其促进将Si连接的氢加成脂族多重键，然后在由这样得到的有机（聚）硅氧烷的烯醇基团的酸催化剂（4）存在下通过分子内反应除去水 。

公开(公告)号：US4795823A

公开(公告)日：1989-01-03

申请号：US20902

申请日：1987-03-02

申请人： Werner Schmitt ,  Peter Jochum ,  Wolf-Dietrich Zahler ,  Heijo Hubner ,  Manfred Holupirek ,  Oswald Gasser ,  Christian Herzig

发明人： Werner Schmitt ,  Peter Jochum ,  Wolf-Dietrich Zahler ,  Heijo Hubner ,  Manfred Holupirek ,  Oswald Gasser ,  Christian Herzig

IPC分类号： C07C69/708 ,  A61K6/08 ,  A61K6/083 ,  C08F20/10 ,  C08F20/26 ,  C08F20/28 ,  C08F220/28 ,  C07C69/66

CPC分类号： A61K6/083 ,  Y10S522/908

摘要： (Methy)acrylic acid esters of the general formula(Mo).sub.n --[--A--O--CO--CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CO--O--].sub.x --A--(OM).sub.nare described whereinA is an alcohol radical having at least 4 chain atoms between two junction sites.M is CH.sub.2 .dbd.C(R.sup.1)--CO wherein R.sup.1 stands for hydrogen or methyl,n is 1 or 2, andx is 0.3 to 3.These esters are suited for the preparation of dental compositions.

摘要翻译： （Mo）n - [ - AO-CO-CH2-O-CH2-CH2-O-CH2-CO-O-] xA（OM）n的（甲基）丙烯酸酯，其中A是 在两个连接位点之间具有至少4个链原子的醇基。 M为CH 2 = C（R 1）-CO，其中R 1代表氢或甲基，n为1或2，x为0.3至3.这些酯适于制备牙科用组合物。

公开(公告)号：US08084566B2

公开(公告)日：2011-12-27

申请号：US13129159

申请日：2009-11-16

申请人： Holger Rautschek ,  Elisabeth Brehm ,  Christian Herzig

发明人： Holger Rautschek ,  Elisabeth Brehm ,  Christian Herzig

IPC分类号： C08G77/46 ,  C08G77/04 ,  C08G18/06 ,  C11D3/20

CPC分类号： B01D19/0404 ,  B01D19/0409 ,  C08G77/445 ,  C08G77/448 ,  C08G77/458 ,  C08G77/46 ,  C08L83/08 ,  C08L83/12 ,  C11D3/0026 ,  C11D3/373 ,  C11D3/3742 ,  C08L83/00

摘要： Mixtures of silicone resin with an organopolysiloxane copolymer prepared by hydrosilylating a substantially linear polymer containing an isocyanate reactive group with an Si—H containing organopolysiloxane, and reacting this intermediate with a diisocyanate, are useful as long lasting defoamers which are compatible with numerous media.

摘要翻译： 有机硅树脂与通过将含有异氰酸酯反应性基团的基本上线性的聚合物与含Si-H的有机聚硅氧烷氢化并使其与二异氰酸酯反应制备的有机聚硅氧烷共聚物的混合物可用作与多种介质相容的长效消泡剂。

公开(公告)号：US20110040036A1

公开(公告)日：2011-02-17

申请号：US12921044

申请日：2009-03-03

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C08F8/00

CPC分类号： C08G77/46 ,  C08G77/12

摘要： Silicone polyethers are prepared in a two stage process by reacting an unsaturated polyether with a first Si—H functional organopolysiloxane and then with a second organopolysiloxane, in which the weight ratio of silicon bonded hydrogen in the first and second organopolysiloxanes is at least 0.9. The reaction is more rapid than a single step process and produces a product with less unreacted Si—H content.

摘要翻译： 通过使不饱和聚醚与第一Si-H官能的有机聚硅氧烷，然后与第二有机聚硅氧烷反应制备硅氧烷聚醚，其中第一和第二有机聚硅氧烷中硅键合氢的重量比至少为0.9。 反应比单步法更快，并产生具有较少未反应的Si-H含量的产物。

公开(公告)号：US07868116B2

公开(公告)日：2011-01-11

申请号：US12305112

申请日：2007-06-19

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C08G77/06

CPC分类号： C08G77/38 ,  C08G77/06

摘要： High-molecular-weight siloxane polymers are prepared in a multi-step process wherein an Si—H functional linear siloxane containing silanol groups is reacted with a hydrosilylatable organic compound, and the product is then condensed.

摘要翻译： 高分子量硅氧烷聚合物以多步法制备，其中含有硅烷醇基的Si-H官能的直链硅氧烷与可氢化可硅烷化的有机化合物反应，然后将产物冷凝。

公开(公告)号：US20100305348A1

公开(公告)日：2010-12-02

申请号：US12599187

申请日：2008-05-19

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C07F7/10

CPC分类号： C08G77/388 ,  C07F7/0889 ,  C08G77/38

摘要： β-ketocarbonyl-functional organosilicon compounds are prepared by reacting an organosilicon compound containing at least one primary amino group with a compound which liberates a diketene, the reaction taking place in the presence of an organic compound which inhibits or prevents the reaction of diketenes with primary or secondary amino groups. The products are different from those produced merely by the reaction of a diketene with an amino-group-containing organosilicon compound.

摘要翻译： 通过使含有至少一个伯氨基的有机硅化合物与释放双烯酮的化合物反应来制备 - 羰基官能的有机硅化合物，该反应在有机化合物存在下进行，所述有机化合物抑制或防止双烯酮与 伯或仲氨基。 产物与仅由双烯酮与含氨基的有机硅化合物反应产生的产物不同。