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    Process of producing cyclohexylbenzene
    43.
    发明授权
    Process of producing cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号：US09382172B2

    公开(公告)日：2016-07-05

    申请号：US14375996

    申请日：2012-12-05

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Christopher L. Becker ,  James R. Lattner ,  Keith H. Kuechler ,  Hari Nair

    IPC: C07C2/74 ,  C07C2/54 ,  C07C7/04 ,  C07C5/367

    CPC classification number: C07C2/74 ,  C07C5/367 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  C07C2529/89 ,  C07C13/28 ,  C07C15/04

    Abstract: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen in the presence of a hydroalkylation catalyst under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, and benzene. At least a portion of the cyclohexane from the first effluent stream is then contacted with hydrogen in the presence of a dehydrogenation catalyst under dehydrogenation conditions effective to convert at least some of the cyclohexane into benzene contained in a second effluent stream. At least some of the hydrogen is supplied to the process so as to contact the dehydrogenation zone (e.g., the dehydrogenation catalyst) before contacting the hydroalkylation catalyst.

    Abstract translation: 在生产环己基苯的方法中，苯在氢化烷基化催化剂存在下，在有效形成包含环己基苯，环己烷和苯的第一流出物流的加氢烷基化条件下与氢气接触。 然后，在脱氢催化剂存在下，将有效将至少一些环己烷转化为第二流出物流中所含的苯的脱氢催化剂存在下，将来自第一流出物流的至少一部分环己烷与氢气接触。 在与加氢烷基化催化剂接触之前，将至少一些氢气供给到该方法中以与脱氢区（例如，脱氢催化剂）接触。

    Conversion of Lignin to Fuels and Aromatics
    44.
    发明申请
    Conversion of Lignin to Fuels and Aromatics 审中-公开
    木质素转化为燃料和芳烃

    公开(公告)号：US20160145497A1

    公开(公告)日：2016-05-26

    申请号：US14876940

    申请日：2015-10-07

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： James R. Lattner ,  Teng Xu ,  Paul F. Keusenkothen

    IPC: C10G1/02 ,  C07C4/14 ,  C07C2/86 ,  C10G1/00 ,  C10G3/00

    CPC classification number: C10G1/02 ,  C07C2/864 ,  C07C4/14 ,  C10B49/22 ,  C10B53/02 ,  C10G1/002 ,  C10G3/42 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/44 ,  C10K1/16 ,  C10K1/18 ,  Y02P30/20

    Abstract: Methods are provided for converting lignin-containing biomass into compounds that are more readily processed to form fuel and/or chemical products. The methods can allow for removal of at least a portion of the oxygen in lignin, either during or after depolymerization of lignin to single ring aromatic compounds, while optionally reducing or minimizing aromatic saturation performed on the aromatic compounds. The methods can include use of quench solvent to control reactions within the product stream from a pyrolysis process and/or use of a solvent to assist with hydroprocessing of lignin, lignin-containing biomass, or a pyrolysis oil.

    Abstract translation: 提供了用于将含木质素的生物质转化成更容易加工以形成燃料和/或化学产品的化合物的方法。 在木质素解聚成单环芳族化合物期间或之后，在任选地还原或最小化对芳族化合物进行的芳族饱和的同时，这些方法可以允许在木质素中除去至少一部分氧。 所述方法可以包括使用骤冷溶剂来控制来自热解过程的产物流中的反应和/或使用溶剂来辅助木质素，含木质素的生物质或热解油的加氢处理。

    Cyclohexane Dehydrogenation
    46.
    发明申请
    Cyclohexane Dehydrogenation 有权
    环己烷脱氢

    公开(公告)号：US20150284304A1

    公开(公告)日：2015-10-08

    申请号：US14438638

    申请日：2013-12-02

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： James R. Lattner ,  Christopher L. Becker ,  Tan-Jen Chen

    IPC: C07C5/367 ,  C07C37/58 ,  C07C45/28 ,  C07C2/74

    CPC classification number: C07C5/367 ,  C07C2/74 ,  C07C5/31 ,  C07C13/28 ,  C07C15/04 ,  C07C37/58 ,  C07C45/28 ,  C07C2601/14

    Abstract: A cyclohexane dehydrogenation process comprising a step of providing, as a benzene-containing stream, a vapor phase in equilibrium with a liquid phase at a condensation separation system; supplying benzene, hydrogen, and cyclohexane into a dehydrogenation reactor where at least part of the benzene supplied is from the benzene-containing stream. The use of a condensation separation system enables the control of the partial pressure of benzene in the material fed into the dehydrogenation reactor by controlling the temperature of the vapor phase, and hence the control of hydrogen to benzene molar ratio in the dehydrogenation reactor. The process results in a long life of the dehydrogenation catalyst due to reduced coking.

    Abstract translation: 环己烷脱氢方法包括在冷凝分离系统下提供与液相平衡的气相作为含苯物流的步骤; 将苯，氢和环己烷供应到脱氢反应器中，其中供应的至少一部分苯来自含苯物流。 通过使用冷凝分离系统，能够通过控制蒸发相的温度来控制进入脱氢反应器的材料中的苯分压，从而控制脱氢反应器中氢与苯的摩尔比。 该方法由于焦化减少导致脱氢催化剂的长寿命。

    Process for Producing Phenol and/or Cyclohexanone from Cyclohexylbenzene
    47.
    发明申请
    Process for Producing Phenol and/or Cyclohexanone from Cyclohexylbenzene 有权
    从环己基苯生产苯酚和/或环己酮的方法

    公开(公告)号：US20150218075A1

    公开(公告)日：2015-08-06

    申请号：US14422444

    申请日：2013-09-12

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Keith H. Kuechler ,  Jihad M. Dakka ,  James R. Lattner ,  Christopher L. Becker ,  Edmund J. Mozeleski

    IPC: C07C45/53 ,  C07C1/24 ,  C07C37/08 ,  C07C407/00 ,  C07C29/60

    CPC classification number: C07C45/53 ,  C07C1/24 ,  C07C2/66 ,  C07C2/74 ,  C07C5/03 ,  C07C29/60 ,  C07C29/80 ,  C07C37/08 ,  C07C407/00 ,  C07C2529/70 ,  C07C2601/14 ,  C07C409/14 ,  C07C39/04 ,  C07C49/403 ,  C07C35/21 ,  C07C13/28

    Abstract: In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas to produce an oxidation effluent containing cyclohexylbenzene hydroperoxide. At least a portion of the cyclohexylbenzene hydroperoxide is then contacted with a cleavage catalyst to produce a cleavage effluent containing phenol and cyclohexanone and by-products including phenylcyclohexanol. The cleavage effluent or a neutralized product thereof also comprises at least one compound comprising an atom not being carbon, hydrogen or oxygen, which is separated from the cleavage effluent and/or the neutralized product thereof to leave a cleavage fraction lean in the compound comprising an atom not being carbon, hydrogen or oxygen and containing at least a portion of the phenylcyclohexanol. At least a portion of the phenylcyclohexanol is then contacted with a dehydration catalyst comprising a molecular sieve of the MCM-22 type to convert at least a portion of the phenylcyclohexanol to phenyl cyclohexene.

    Abstract translation: 在生产苯酚和/或环己酮的方法中，使环己基苯与含氧气体接触以产生含有环己基苯氢过氧化物的氧化流出物。 然后将至少一部分环己基苯氢过氧化物与裂解催化剂接触，以产生包含苯酚和环己酮的裂解流出物以及包括苯基环己醇在内的副产物。 裂解流出物或其中和产物还包含至少一种包含不是碳，氢或氧的原子的化合物，其从裂解流出物和/或其中和产物中分离出来，以在含有 原子不是碳，氢或氧并且含有至少一部分苯基环己醇。 然后至少一部分苯基环己醇与包含MCM-22型分子筛的脱水催化剂接触，以将至少一部分苯基环己醇转化成苯基环己烯。

    Process for Producing Phenol
    49.
    发明申请
    Process for Producing Phenol 有权
    生产苯酚的方法

    公开(公告)号：US20150018583A1

    公开(公告)日：2015-01-15

    申请号：US14375983

    申请日：2012-12-04

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Christopher L. Becker ,  James R. Lattner ,  Keith H. Kuechler ,  Hari Nair

    IPC: C07C37/08 ,  C07C2/66 ,  C07C407/00

    CPC classification number: C07C37/08 ,  C07C2/66 ,  C07C2/74 ,  C07C5/03 ,  C07C7/11 ,  C07C37/80 ,  C07C45/53 ,  C07C407/00 ,  C07C2601/14 ,  C07C409/14 ,  C07C39/04 ,  C07C49/403 ,  C07C13/28

    Abstract: In a process for producing phenol, benzene is reacted with a source of hydrogen containing methane in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction effluent comprising cyclohexylbenzene, benzene, hydrogen, and methane. A first stream comprising hydrogen, methane, and benzene is removed from the hydroalkylation reaction effluent and the first stream is washed with a second stream containing cyclohexylbenzene to produce a benzene-depleted hydrogen stream containing hydrogen and methane and a wash stream containing cyclohexylbenzene and benzene.

    Abstract translation: 在生产苯酚的方法中，在有效产生包含环己基苯，苯，氢和甲烷的加氢烷基化反应流出物的条件下，在加氢烷基化催化剂存在下，使苯与含氢甲烷源反应。 从加氢烷基化反应流出物中除去包含氢气，甲烷和苯的第一流，并将第一流用含有环己基苯的第二料流洗涤以产生含有氢和甲烷的贫苯氢气流，以及含有环己基苯和苯的洗涤流。

    Processes and systems for quenching pyrolysis effluents
    50.
    发明授权
    Processes and systems for quenching pyrolysis effluents 有权

    公开(公告)号：US12187967B2

    公开(公告)日：2025-01-07

    申请号：US17768663

    申请日：2020-09-16

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Reyyan Koc-Karabocek ,  James R. Lattner ,  William A. Aslaner ,  David Spicer ,  Mark A. Rooney

    IPC: C10G70/04 ,  C10G69/06

    Abstract: Processes and systems for quenching an effluent. In certain embodiments, the process can include contacting a pyrolysis effluent and a first quench medium to produce a first quenched effluent. A bottoms stream that can include tar and an overhead stream that can include ethylene and propylene can be obtained from the first quenched effluent. The first quench medium can include a first portion of the bottoms stream that can include a first portion of the tar. In certain embodiments, the process can also include hydroprocessing a second portion of the bottoms stream that can include a second portion of the tar to produce a hydroprocessed product. A hydroprocessed bottoms stream can be obtained from the hydroprocessed product. In certain embodiments, the process can also include contacting at least a portion of the hydroprocessed bottoms stream and the first portion of the bottoms stream to produce the first quench medium.

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