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公开(公告)号：US20220176366A1
公开(公告)日：2022-06-09
申请号：US17442843
申请日：2020-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Joshua J. Willis , Jeffrey C, Bunquin , Stephanie M Westbrook , Antonie Jan Bons , Joseph A. Thnockmorton , Javier Guzman , Renyuan Yu
Abstract: The present disclosure relates to nanoparticle compositions, catalyst compositions, processes for making nanoparticle compositions and processes for making catalyst compositions. In at least one embodiment, a composition includes a plurality of nanoparticles, where each nanoparticle includes a kernel, the kernels include at least one metal element and oxygen, and the kernels have an average particle size from 4 to 100 nanometers, and a particle size distribution of less than 20%.
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公开(公告)号：US11970573B2
公开(公告)日：2024-04-30
申请号：US17227662
申请日：2019-11-13
Inventor： Monica Lotz , S. Richard Turner , Hans Eliot Edling , Kapil Kandel , Michael Salciccioli , Stephen Cohn , Alan A. Galuska , Javier Guzman , Edward E. Paschke
IPC: C08G63/193 , C08G63/80 , C08G63/85
CPC classification number: C08G63/193 , C08G63/80 , C08G63/85 , C08G2120/00
Abstract: Bifuran-modified polyester, polyethylene-terephthalate-co (2,2′-bifuran-5,5′-dicarboxylate), prepared by esterifying or transesterifying a diacid component comprising from 2 to 10 mole percent 2,2′-bifuran-5,5′-dicarboxylate and a diol component with a catalyst compound comprising metal present in an amount of from about 10 to about 450 ppm and polycondensation to form the polyester wherein the polyester has an inherent viscosity of at least 0.5 g/dL, a glass transition temperature (Tg) of 82° C. or more, a semicrystalline melting peak (Tm) with ΔHf equal to or greater than 5 J/g on the second heating ramp, and melting temperature (Tm) between 229° C. and 246° C. Reinforced compositions and shaped articles comprising bifuran-modified polyethylene terephthalate and methods of their production are also disclosed.
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公开(公告)号：US11891517B2
公开(公告)日：2024-02-06
申请号：US17908769
申请日：2021-03-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Anatoly I. Kramer , Alexander V. Zabula , Elizabeth A. Turner , Raf de Meester , Helge Jaensch , Jeffrey C. Bunquin , Javier Guzman , Emiel de Smit , John S. Coleman , Madelyn Bekker , Roxana Perez Velez
CPC classification number: C08L91/06 , C07C6/04 , C07C7/163 , C07C2531/22
Abstract: Wax compositions may be obtained by providing an olefinic feed comprising a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, wherein m and n are independently selected integers each ranging from about 12 to about 100, and the olefinic feed optionally comprises one or more internal olefins and/or one or more branched olefins; contacting the olefinic feed with a metal carbene catalyst in a reactor; forming ethylene and a hydrocarbon substance comprising a linear olefin dimer comprising two carbon atoms less than a sum of m and n; removing the ethylene from the reactor while forming the linear olefin dimer; and isolating a wax composition comprising the linear olefin dimer, a hydrogenated reaction product thereof, or any combination thereof.
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公开(公告)号：US09302971B2
公开(公告)日：2016-04-05
申请号：US14515823
申请日：2014-10-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Guang Cao , James R. Lattner , Javier Guzman , Shifang L. Luo
IPC: C07C51/265 , C07D493/08 , C07C45/66 , C07C29/20 , C07C29/19 , C07C67/08 , C07D307/46 , C07C29/00 , C08K5/00 , C07C51/255
CPC classification number: C07C51/265 , C07C29/00 , C07C29/19 , C07C29/20 , C07C45/66 , C07C51/255 , C07C67/08 , C07C2601/14 , C07D307/46 , C07D493/08 , C08K5/0016 , C07C33/26 , C07C33/14 , C07C47/56 , C07C63/26
Abstract: This invention relates to the production of terephthalic acid by 1) cycloaddition of 2,5 substituted furan (such as 2,5-bis hydroxymethylfuran or 5-hydroxymethylfurfural) and ethylene, and 2) the subsequent oxidation of the dehydrated cycloaddition product to terephthalic acid. The invention relates more particularly to overall biobased pathways for making terephthalic acid from carbohydrates such as hexoses (e.g., glucose or fructose).
Abstract translation: 本发明涉及通过1）2,5-取代的呋喃（例如2,5-双羟甲基呋喃或5-羟甲基糠醛）和乙烯的环加成制备对苯二甲酸，和2）随后将脱水环加成产物氧化成对苯二甲酸 。 本发明更具体地涉及从碳水化合物如己糖（例如葡萄糖或果糖）制备对苯二甲酸的总体生物基通路。
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公开(公告)号：US11912819B2
公开(公告)日：2024-02-27
申请号：US17284717
申请日：2019-11-13
Inventor： Monica Lotz , Kapil Kandel , Michael Salciccioli , Stephen Cohn , Alan A. Galuska , Javier Guzman , S. Richard Turner , Hans Eliot Edling , Edward E. Paschke
IPC: C08G63/185 , C08G63/199 , C08G63/80 , C08G63/85
CPC classification number: C08G63/185 , C08G63/199 , C08G63/80 , C08G63/85 , C08G2120/00 , C08G2250/00
Abstract: Semicrystalline polyethylene-2,2′-bifuran-5,5′-dicarboxylate (PEBF) homopolyester or copolyester with up to 5 mole percent isophthalate or up to 2.7 mole percent terephthalate, based on the diacid component, or up to 2.5 mole percent 1,4-cyclohexanedimethanol (CHDM), based on the diol component, prepared by esterifying or transesterifying the diacid and the diol components with a catalyst including about 10 to about 50 ppm wt metal, and polycondensation, wherein the bifuran polyester has an intrinsic viscosity of at least 0.4 g/dL and a semicrystalline melting peak (Tm) with ΔHf equal to or greater than 5 J/g on the second heating ramp.
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Patent Agency Ranking
公开(公告)号：US20220176365A1
公开(公告)日：2022-06-09
申请号：US17442710
申请日：2020-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jeffrey C. Bunquin , Joshua J. Willis , Paul F. Keusenkothen , Javier Guzman , Jennifer R. Pena
IPC: B01J35/00 , B01J23/889 , B01J35/08 , B01J6/00 , B01J37/02 , B01J37/00 , C07C1/04 , C07C29/156
Abstract: Disclosed are novel supported nanoparticle compositions, precursors, processes for making supported nanoparticle compositions, processes for making catalyst compositions, and processes for converting syngas. The catalyst composition can comprise nanoparticles comprising metal oxide(s), such as manganese cobalt oxide. This disclosure is particularly useful for converting syngas via the Fischer-Tropsch reactions to make olefins and/or alcohols.
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公开(公告)号：US20220033573A1
公开(公告)日：2022-02-03
申请号：US17227662
申请日：2019-11-13
Inventor： Monica Lotz , S. Richard Turner , Hans Eliot Edling , Kapil Kandel , Michael Salciccioli , Stephen Cohn , Alan A. Galuska , Javier Guzman , Edward E. Paschke
IPC: C08G63/193 , C08G63/80 , C08G63/85
Abstract: Copolyesters such as polyethylene terephthalate (PET) or polyethylene furanoate (PEF) modified with bifuran polyacids such as dimethyl-2,2′-bifuran-5,5′-dicarboxylate (BFE), 2,2′-bifuran-5,5′-dicarboxylic acid (BDA), or bis(2-hydroxyethyl)-2,2′-bifuran-5,5′-dicarboxylate (BHEB), and/or bifuran polyhydroxyls, may have improved properties such as glass transition temperature (Tg), tensile modulus, barrier properties, crystallinity, and/or impact strength. Polyethylene terephthalate-co-bifuranoate (PETBF) has an improved Tg. Also described are polyethylene furanoate-co-bifuranoates (PEFBF).
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公开(公告)号：US11091419B2
公开(公告)日：2021-08-17
申请号：US16652894
申请日：2018-05-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Etienne Mazoyer , Monica D. Lotz , Constantinos P. Bokis , Javier Guzman
IPC: C07C51/43
Abstract: Processes are described for purifying a biphenyldicarboxylic acid product containing one or more impurities, particularly at least formylbiphenylcarboxylic acid. In the processes, a mixture comprising the biphenyldicarboxylic acid product is contacted with hydrogen in the presence of a hydrogenation catalyst under conditions to selectively reduce at least part of the formylbiphenylcarboxylic acid to produce a hydrogenation effluent comprising (i) hydroxymethylbiphenylcarboxylic acid and/or methylbiphenylcarboxylic acid, and (ii) biphenylcarboxylic acid. At least a portion of the biphenyldicarboxylic acid is then separated from the hydrogenation effluent. Advantageously, a polyester product may be produced from the separated biphenyldicarboxylic acid.
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公开(公告)号：US20240010579A1
公开(公告)日：2024-01-11
申请号：US18042386
申请日：2021-08-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jeffrey C. Bunquin , Joshua J. Willis , Partha Nandi , Javier Guzman
CPC classification number: C07C1/044 , B01J23/83 , B01J23/8892 , B01J35/0013 , B01J35/006 , B01J37/18 , B01J37/082 , B01J37/0205 , B01J37/0236 , C07C2523/06 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/04 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/50 , C07C2523/10
Abstract: Fischer-Tropsch processes for converting syngas produces linear alpha olefins at high yield and selectivity in the presence of supported nano-particle catalyst compositions and/or metal carbide/nitride-containing catalyst compositions.
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10.发明公开公开(公告)号：US20230159759A1
公开(公告)日：2023-05-25
申请号：US17908746
申请日：2021-03-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Anatoly I. Kramer , Alexander V. Zabula , Elizabeth A. Turner , Roxana Perez Velez , Helge Jaensch , Jeffrey C. Bunquin , Javier Guzman , Emiel de Smit , John S. Coleman , Madelyn Bekker
IPC: C08L91/06 , C11C5/00 , C09J191/06
CPC classification number: C08L91/06 , C11C5/002 , C09J191/06
Abstract: Wax compositions may be obtained by subjecting one or more linear alpha olefins to olefin metathesis and optionally hydrogenating. The wax compositions comprise: a hydrocarbon substance comprising a linear olefin dimer formed from a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, a hydrogenated or partially hydrogenated reaction product of the linear olefin dimer, or any combination thereof, the first linear alpha olefin and the second linear alpha olefin being the same or different, and the linear olefin dimer comprising two carbon atoms less than a sum of m and n; wherein m and n are independently selected integers each ranging from 12 to 100; and wherein the wax composition has a melting point of 25° C. or greater.
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