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127 条记录 (耗时 0.022 秒)

    Granular flame-retardant composition
    41.
    发明授权
    Granular flame-retardant composition 有权
    颗粒阻燃组合物

    公开(公告)号：US07148276B2

    公开(公告)日：2006-12-12

    申请号：US10656398

    申请日：2003-09-05

    申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    IPC分类号： C08K5/53

    CPC分类号： C08K5/5313

    摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.

    摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。

    Method to improve the efficacy of therapeutic radiolabeled drugs
    42.
    发明申请
    Method to improve the efficacy of therapeutic radiolabeled drugs 审中-公开
    提高治疗放射性标记药物疗效的方法

    公开(公告)号：US20060127308A1

    公开(公告)日：2006-06-15

    申请号：US11009518

    申请日：2004-12-13

    申请人： Werner Krause

    发明人： Werner Krause

    IPC分类号： A61K51/00 ,  C07F5/00

    CPC分类号： A61K51/1093

    摘要： Disclosed are radiolabeled drugs and methods to improve their efficacy by using a radiosensitizer such that the radiosensitizer is either part of the radiolabeled drug by directly attaching the radiosensitizer to the radiolabeled drug or by producing a mixture of the radiolabeled drug and an analogue of the drug with the radiosensitizer attached to the drug instead of the radiolabel.

    摘要翻译： 公开了通过使用放射增敏剂来提高其功效的放射性标记药物和方法，使得放射增敏剂是放射性标记药物的一部分，通过将放射增敏剂直接附着到放射性标记的药物或通过产生放射性标记的药物和药物的类似物的混合物与 放射敏剂附着于药物而不是放射性标记物。

    Phosphorus-containing flame retardant agglomerates
    43.
    发明申请
    Phosphorus-containing flame retardant agglomerates 有权
    含磷阻燃剂

    公开(公告)号：US20050143503A1

    公开(公告)日：2005-06-30

    申请号：US10959515

    申请日：2004-10-06

    申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    IPC分类号： C09K21/12 ,  B01J2/28 ,  C08K5/00 ,  C08K5/5313 ,  C08K9/04 ,  C08L101/00 ,  C09K21/02 ,  C09K21/10 ,  C08K5/49

    CPC分类号： C08K5/0066 ,  C08J3/223 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2377/06 ,  C08K5/5313

    摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.

    摘要翻译： 本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基， 直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，b）为0.01至20重量％的助剂。 本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

    Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof
    47.
    发明授权
    Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof 有权
    用于制备单官能二烷基次膦酸，酯和盐的方法及其用途

    公开(公告)号：US09279085B2

    公开(公告)日：2016-03-08

    申请号：US13140555

    申请日：2009-10-06

    申请人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

    发明人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

    IPC分类号： C07F9/02 ,  C07F9/22 ,  C07F9/28 ,  C08K5/53 ,  C09K21/12 ,  C07F9/30 ,  C07F9/32 ,  C08K5/5313

    CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/3211 ,  C08K5/5313

    摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.

    摘要翻译： 本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或 酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数 至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。 还公开了所述二烷基膦酸，酯和盐的用途。

    Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether and the use thereof
    48.
    发明授权
    Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether and the use thereof 有权
    使用乙烯基醚制备单羧基官能化二烷基次膦酸，酯和盐的方法及其用途

    公开(公告)号：US08987489B2

    公开(公告)日：2015-03-24

    申请号：US13132196

    申请日：2009-10-06

    申请人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

    发明人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

    IPC分类号： C07F9/32 ,  C07F9/30 ,  C07F9/48 ,  C08K5/5313 ,  C09K21/12 ,  C08L21/00

    CPC分类号： C07F9/30 ,  C07F9/301 ,  C07F9/32 ,  C07F9/4816 ,  C07F9/4866 ,  C08K5/5313 ,  C08L21/00 ,  C09K21/12

    摘要： A method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ether of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting this derivative (VI) with an oxidant or in the presence of a catalyst C to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein the catalysts A and C are transition metals and/or transition metal compounds, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound.

    摘要翻译： 使用乙烯基醚制备单羧基官能化的二烷基次膦酸，酯和盐的方法。 该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使 所得的烷基亚磷酸，其盐或其酯（II）与式（V）的乙烯基醚在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（VI），和c）使该衍生物 VI）与氧化剂或催化剂C的存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III），其中催化剂A和C为过渡金属和/或过渡金属化合物，催化剂B为 过氧化物形成化合物和/或过氧化合物和/或偶氮化合物。

    Process for preparing mono-allyl-functionalized dialkylphosphinic acids, salts and esters thereof with allylic compounds, and the use thereof
    49.
    发明授权
    Process for preparing mono-allyl-functionalized dialkylphosphinic acids, salts and esters thereof with allylic compounds, and the use thereof 失效
    用烯丙基化合物制备单烯丙基官能化二烷基次膦酸，其盐和酯的方法及其用途

    公开(公告)号：US08772519B2

    公开(公告)日：2014-07-08

    申请号：US13127110

    申请日：2009-10-06

    申请人： Michael Hill ,  Werner Krause ,  Martin Sicken

    发明人： Michael Hill ,  Werner Krause ,  Martin Sicken

    IPC分类号： C07F9/30 ,  C07F9/32 ,  C07F5/06

    CPC分类号： C09K21/12 ,  C07F9/302 ,  C07F9/3217 ,  C08K5/5313

    摘要： The invention relates to a process for preparing mono-allyl-functionalized dialkylphosphinic acids, esters and salts with allylic compounds, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, or salt or ester thereof (II), b) the alkylphosphonous acid, or salt or ester thereof (II) thus formed is reacted with allylic compounds of the formula (V) in the presence of a catalyst B and of a base to give a mono-allyl-functionalized dialkylphosphinic acid derivative (III), where R1, R2, R3, R4, R5, R6, R7, R8, R9 are the same or different and are each independently, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, and X is H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base, and the catalysts A and B are transition metals and/or transition metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition metal compound and at least one ligand.

    摘要翻译： 本发明涉及用烯丙基化合物制备单烯丙基官能化二烷基次膦酸，酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应， 得到烷基亚磷酸或其盐或酯（II），b）将如此形成的烷基亚膦酸或其盐或酯（II）与式（Ⅴ）的烯丙基化合物在催化剂B的存在下反应，和 得到单烯丙基官能化的二烷基次膦酸衍生物（III）的碱，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9相同或不同，并且各自独立地为H， C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X是H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18 - 烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱， 催化剂A和B是过渡金属和/或过渡金属 nds和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。

    Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof
    50.
    发明授权
    Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof 有权
    使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸，酯和盐的方法及其用途

    公开(公告)号：US08735476B2

    公开(公告)日：2014-05-27

    申请号：US13132153

    申请日：2009-10-06

    申请人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

    发明人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

    IPC分类号： C08K5/5313

    CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/4816 ,  C07F9/4866 ,  C08K5/5313

    摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkylphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III).

    摘要翻译： 本发明涉及使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸，酯和盐的方法。 该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基次膦酸，其盐或其酯（II），b）使 如此获得的烷基次膦酸，其盐或其酯（II）与式（V）的羧酸的乙烯基酯在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（Ⅵ）和c） 使在催化剂C存在下得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单官能化二烷基次膦酸衍生物（Ⅶ），和d）使单官能化二烷基次膦酸衍生物（Ⅶ）反应; 与氧化剂或在催化剂D存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III）。