公开(公告)号：US07259200B2

公开(公告)日：2007-08-21

申请号：US10959515

申请日：2004-10-06

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/5313

CPC分类号： C08K5/0066 ,  C08J3/223 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2377/06 ,  C08K5/5313

摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.

摘要翻译： 本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基， 直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，和b）0.01至20重量％的助剂。 本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

公开(公告)号：US20130190432A1

公开(公告)日：2013-07-25

申请号：US13878145

申请日：2011-09-30

申请人： Werner Krause ,  Harald Bauer ,  Martin Sicken ,  Sebastian Hoerold ,  Wolfgang Wanzke ,  Elke Schlosser

发明人： Werner Krause ,  Harald Bauer ,  Martin Sicken ,  Sebastian Hoerold ,  Wolfgang Wanzke ,  Elke Schlosser

IPC分类号： C08K5/5313 ,  C08K5/3492 ,  C08K5/10 ,  C08K3/22 ,  C08K5/5317 ,  C08K5/56 ,  C08K5/52 ,  C08K3/38

CPC分类号： C08K5/5313 ,  C08K3/22 ,  C08K3/38 ,  C08K5/0008 ,  C08K5/10 ,  C08K5/34922 ,  C08K5/34924 ,  C08K5/52 ,  C08K5/5317 ,  C08K5/56

摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.

摘要翻译： 一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物 其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％ 含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物 氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

公开(公告)号：US20060208239A1

公开(公告)日：2006-09-21

申请号：US11438594

申请日：2006-05-22

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C09K21/00

CPC分类号： C08K5/5313

摘要： The invention relates to a compacted flame-retardant composition comprising an organophosphorus flame-retardant component, prepared by compacting an organophosphorus flame-retardant component with or without a compacting auxiliary, and to a process for preparing these flame-retardant compositions, and to polymer molding compositions which comprise these flame-retardant compositions.

摘要翻译： 本发明涉及一种压实的阻燃组合物，其包含通过压实有或无压实助剂的有机磷阻燃组分制备的有机磷阻燃组分，以及制备这些阻燃组合物的方法和聚合物成型 包含这些阻燃组合物的组合物。

公开(公告)号：US20060020064A1

公开(公告)日：2006-01-26

申请号：US11182693

申请日：2005-07-15

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/49

CPC分类号： B82Y30/00 ,  C08K5/5313 ,  C08K2201/011 ,  C08L21/00

摘要： The invention relates to a flame-retardant polymer molding composition which comprises a nanoparticulate phosphorus-containing flame retardant system which comprises at least one phosphinic salt of the formula (I) and/or diphosphinic salt of the formula (II) and/or their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4.

摘要翻译： 本发明涉及一种阻燃聚合物模塑组合物，其包含纳米颗粒含磷阻燃体系，其包含至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物 其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，线性 或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4。

公开(公告)号：US20050101707A1

公开(公告)日：2005-05-12

申请号：US10656406

申请日：2003-09-05

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C09K21/12 ,  C08K5/49 ,  C08K5/5313 ,  C08L101/00 ,  C09K21/02 ,  C09K21/04 ,  C09K21/10 ,  C09K21/14 ,  C09K21/00

CPC分类号： C08K5/5313

摘要： The invention related to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where F1 and R2 are identical or different and are C1-C8-alcyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C8-10-arylene, -alkylarylene or -arylakylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with malamine, melam and/or melem.

摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其中F 1和/ R 2相同或不同，为C 1 -C 8 - 烷硫基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 8 - 10 亚芳基， - 烷基亚芳基或 - 芳基亚芳基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含组分B1，B2和/或B3，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与malamine的复合盐，蜜胺 和/或马力。

公开(公告)号：US20050032958A1

公开(公告)日：2005-02-10

申请号：US10656313

申请日：2003-09-05

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C08L101/00 ,  C08K5/5313 ,  C08K9/04 ,  C08L1/00

CPC分类号： C08K5/5313

摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C5-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.

摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其中R 1和R 2的聚合物为 是C 1 -C 5烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。

公开(公告)号：US20050101706A1

公开(公告)日：2005-05-12

申请号：US10656398

申请日：2003-09-05

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C09K21/12 ,  C08K5/3467 ,  C08K5/5313 ,  C08K5/5317 ,  C08L101/00 ,  C09K21/02 ,  C09K21/04 ,  C09K21/10 ,  C09K21/14 ,  C08K5/49

CPC分类号： C08K5/5313

摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.

摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。

公开(公告)号：US07220791B2

公开(公告)日：2007-05-22

申请号：US10854606

申请日：2004-05-26

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken ,  Peter Staniek

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken ,  Peter Staniek

IPC分类号： C08K5/51

CPC分类号： C07F9/4816 ,  C09K21/14

摘要： The invention relates to a styrene-hypophosphite adduct of the formula (I) {R9[C(Ph(R1, R2, R3, R4, R5))R6—CR7R8]n}mP(O)(O 1/x Mx+)(R10)2-m where R1, R2, R3, R4, R5, R6, R7 and R8 are identical or different and are hydrogen, alkyl, linear or branched, aryl, aralkyl, oxoalkyl, oxoaryl, aminoalkyl, and/or aminoaryl, R9 is H or a free-radical-initiator radical, R10 is H, Mx+ is Li, Na, K, Mg, Ca, Sr, Ba, Al, Ge, Sn, Bi, Sb, Pb, Ti, TiO, Zr, ZrO, Zn, Fe, Ce, Mn, and/or a protonated nitrogen base having the valency x, m=1 or 2, and n=from 1 to 100, and is the number of styrene units C(Ph(R1, R2, R3, R4, R5))R6—CR7R8 inserted into the P—H bond.

摘要翻译： 本发明涉及式（I）的苯乙烯 - 次磷酸盐加合物<？in-line-formula description =“In-line Formulas”end =“lead”→> {R 9 Ph（R 1，R 2，R 2，R 3，R 4，R 5） >））R 6 -CR 7 R 8 N 3 N 2 N （O）（O 1 / x M×x +）（R 10）2-m < - in-line-formula description =“In 其中R 1，R 2，R 3，R 4，R 3，R 3，R 3，R 3， R 5，R 6，R 7和R 8是相同或不同的，是氢，烷基 直链或支链的芳基，芳烷基，氧代烷基，氧代芳基，氨基烷基和/或氨基芳基，R 9是H或自由基引发剂基，R 10是 H，M x +是Li，Na，K，Mg，Ca，Sr，Ba，Al，Ge，Sn，Bi，Sb，Pb，Ti，TiO，Zr，ZrO，Zn，Fe， Ce，Mn和/或具有化合价x，m = 1或2，n = 1至100的质子化氮碱，并且是苯乙烯单元C（Ph（R 1） UB 2，R 2，R 3，R 4，R 5））R 6， 插入到PH键中的一个或多个R 7 R 8。

公开(公告)号：US07148276B2

公开(公告)日：2006-12-12

申请号：US10656398

申请日：2003-09-05

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/53

CPC分类号： C08K5/5313

摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.

摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。

公开(公告)号：US20050143503A1

公开(公告)日：2005-06-30

申请号：US10959515

申请日：2004-10-06

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

IPC分类号： C09K21/12 ,  B01J2/28 ,  C08K5/00 ,  C08K5/5313 ,  C08K9/04 ,  C08L101/00 ,  C09K21/02 ,  C09K21/10 ,  C08K5/49

CPC分类号： C08K5/0066 ,  C08J3/223 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2377/06 ,  C08K5/5313

摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.

摘要翻译： 本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基， 直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，b）为0.01至20重量％的助剂。 本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。