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公开(公告)号:US10072206B2
公开(公告)日:2018-09-11
申请号:US15197891
申请日:2016-06-30
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Fangming Du , Anant Achyut Setlur
IPC: C09K11/61
CPC classification number: C09K11/616
Abstract: Processes for preparing color stable red-emitting phosphors include contacting a complex fluoride phosphor of formula I with a first fluorine-containing oxidizing agent in gaseous form at a first temperature ranging from 200° C. to 700° C. to form a first product phosphor, contacting the first product phosphor in particulate form with a solution of a compound of formula II in aqueous hydrofluoric acid to form a treated phosphor, and contacting the treated phosphor with a second fluorine-containing oxidizing agent in gaseous form at a second temperature
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公开(公告)号:US09698314B2
公开(公告)日:2017-07-04
申请号:US14208592
申请日:2014-03-13
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ I wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
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43.
公开(公告)号:US20160312114A1
公开(公告)日:2016-10-27
申请号:US15197897
申请日:2016-06-30
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Fangming Du , Anant Achyut Setlur
IPC: C09K11/61
CPC classification number: C09K11/616 , C09K2211/181 , C09K2211/188 , H01L24/48 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2924/00014 , H01L2924/181 , H01L2924/00012 , H01L2224/45099 , H01L2224/45015 , H01L2924/207
Abstract: Processes for preparing color stable Mn4+ doped phosphors include contacting a phosphor of formula I with a fluorine-containing oxidizing agent in gaseous form at temperature ≦225° C. to form the color stable Mn4+ doped phosphor A x MF y : Mn 4 + I wherein A is independently at each occurrence Li, Na, K, Rb, Cs, or a combination thereof; M is independently at each occurrence Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the MFy ion; and y is 5, 6 or 7. In another aspect, the processes include contacting a phosphor of formula I at an elevated temperature with an oxidizing agent comprising a C1-C4 fluorocarbon, to form the color stable Mn4+ doped phosphor.
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公开(公告)号:US20150364659A1
公开(公告)日:2015-12-17
申请号:US14304098
申请日:2014-06-13
Applicant: General Electric Company
Inventor: Anant Achyut Setlur , Stanton Earl Weaver , Thomas Bert Gorczyca , Ashfaqul Islam Chowdhury , James Edward Murphy , Florencio Garcia
CPC classification number: H01L33/504 , C09K11/617 , C09K11/7774 , H01L33/005 , H01L33/502 , H01L2224/48247 , H01L2224/48257 , H01L2924/181 , H01L2933/0041 , H01L2924/00012
Abstract: A process for fabricating a LED lighting apparatus includes disposing a composite coating on a surface of a LED chip. The composite coating comprises a first composite layer having a manganese doped phosphor of formula I and a first binder, and a second composite layer comprising a second phosphor composition and a second binder. The first binder, the second binder or both include a poly(meth)acrylate. Ax[MFy]:Mn4+ (I) wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7.
Abstract translation: 制造LED照明装置的方法包括在LED芯片的表面上设置复合涂层。 复合涂层包括具有式I的锰掺杂磷光体和第一粘合剂的第一复合层和包含第二磷光体组合物和第二粘合剂的第二复合层。 第一粘合剂,第二粘合剂或两者包括聚(甲基)丙烯酸酯。 Ax [MFy]:Mn4 +(I)其中A是Li,Na,K,Rb,Cs或它们的组合; M是Si,Ge,Sn,Ti,Zr,Al,Ga,In,Sc,Hf,Y,La,Nb,Ta,Bi,Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y是5,6或7。
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公开(公告)号:US20150361337A1
公开(公告)日:2015-12-17
申请号:US14549847
申请日:2014-11-21
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Florencio Garcia , Ashfaqul Islam Chowdhury , Srinivas Prasad Sista , Anant Achyut Setlur
CPC classification number: C09K11/617 , C09K11/7774 , H01L33/502 , H01L33/507 , H01L33/54 , H01L2224/48247 , H01L2224/48257 , H01L2924/181 , H01L2924/00012
Abstract: A process for synthesizing a Mn4+ doped phosphor includes contacting a precursor of formula I, at an elevated temperature with a fluorine-containing oxidizing agent in gaseous form to form the color stable Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and amount of Mn ranges from about 0.9 wt % to about 4 wt %, based on total weight.
Abstract translation: 合成Mn4 +掺杂荧光体的方法包括使式I的前体在升高的温度下与气态的含氟氧化剂接触以形成颜色稳定的Mn4 +掺杂荧光体; 其中A为Li,Na,K,Rb,Cs或其组合; M是Si,Ge,Sn,Ti,Zr,Al,Ga,In,Sc,Hf,Y,La,Nb,Ta,Bi,Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7; 并且Mn的量基于总重量为约0.9重量%至约4重量%。
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公开(公告)号:US09210775B2
公开(公告)日:2015-12-08
申请号:US13665514
申请日:2012-10-31
Applicant: General Electric Company
Inventor: James Edward Murphy , Anant Achyut Setlur
CPC classification number: H05B37/0227 , F25D17/042 , F25D2317/0417
Abstract: A method and system for storage of perishable items is provided. The system includes at least one enclosed compartment to store the perishable items. At least one of the walls of the enclosed compartment is detachable to allow movement of the perishable items in and out of the compartment. The system further includes a plurality of light emitting diodes (LEDs) that are disposed on one of the walls of the compartment. The LEDs include one or more blue LEDs that are coated with a layer of phosphor material. The LEDs are electrically coupled with a power source. The system further includes a control unit that is configured to control power supplied by the power source to the LEDs based on presence of the perishable items in the compartment.
Abstract translation: 提供了用于存储易腐物品的方法和系统。 该系统包括至少一个封闭的隔间以存储易腐物品。 封闭隔间的至少一个墙壁是可拆卸的,以允许易腐物品进出隔室。 该系统还包括设置在隔室的一个壁上的多个发光二极管(LED)。 LED包括一层或多层涂有磷光体材料层的蓝色LED。 LED与电源电耦合。 该系统还包括控制单元,其被配置为基于存在隔室中的易腐物品来控制由电源向LED提供的电力。
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公开(公告)号:US20140327026A1
公开(公告)日:2014-11-06
申请号:US14311624
申请日:2014-06-23
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Abstract translation: 用于合成颜色稳定的Mn4 +掺杂荧光体的方法包括在升高的温度下以气态形式将式I的前体与含氟氧化剂接触以形成颜色稳定的Mn4 +掺杂荧光体Ax [MFy]:Mn4 +,其中A为Li ,Na,K,Rb,Cs或其组合; M是Si,Ge,Sn,Ti,Zr,Al,Ga,In,Sc,Hf,Y,La,Nb,Ta,Bi,Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7。
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公开(公告)号:US20140327023A1
公开(公告)日:2014-11-06
申请号:US13875534
申请日:2013-05-02
Applicant: General Electric Company
Inventor: Megan Marie Brewster , Anant Achyut Setlur , Robert Joseph Lyons , James Edward Murphy , Florencio Garcia
IPC: H01L33/50
CPC classification number: H01L33/504 , C09K11/617 , C09K11/7721 , C09K11/7734 , C09K11/7774 , H01L33/507 , H01L2224/48247 , H01L2224/48257 , H05B33/10
Abstract: A method for fabricating a light emitting device is disclosed. The light emitting device includes a light emitting diode (LED). The method includes disposing a layered phosphor composite or a thick phosphor composite radiationally coupled to the LED to form a light emitting device. The layered phosphor composite includes a first phosphor layer including a yellow-emitting phosphor over a second phosphor layer including manganese-doped potassium fluorosilicate (PFS). The second phosphor layer is disposed closer to the LED. The mass of the PFS of this light emitting device is at least 15% less than mass of the PFS in a reference light emitting device that has the same color temperature as the above mentioned light emitting device, but includes a blend of PFS and the yellow emitting phosphor instead of a layered configuration or has a decreased thickness.
Abstract translation: 公开了一种制造发光器件的方法。 发光器件包括发光二极管(LED)。 该方法包括设置辐射耦合到LED以形成发光器件的层状磷光体复合物或厚荧光粉复合物。 层状磷光体复合体包括在包含锰掺杂的氟硅酸钾(PFS)的第二磷光体层上包括黄色发射磷光体的第一荧光体层。 第二荧光体层设置得更靠近LED。 该发光器件的PFS质量比具有与上述发光器件相同色温的参考发光器件中的PFS质量小至少15%,但包括PFS与黄色 而不是层状构造,或者具有减小的厚度。
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公开(公告)号:US20140116079A1
公开(公告)日:2014-05-01
申请号:US13665514
申请日:2012-10-31
Applicant: GENERAL ELECTRIC COMPANY
Inventor: James Edward Murphy , Anant Achyut Setlur
CPC classification number: H05B37/0227 , F25D17/042 , F25D2317/0417
Abstract: A method and system for storage of perishable items is provided. The system includes at least one enclosed compartment to store the perishable items. At least one of the walls of the enclosed compartment is detachable to allow movement of the perishable items in and out of the compartment. The system further includes a plurality of light emitting diodes (LEDs) that are disposed on one of the walls of the compartment. The LEDs include one or more blue LEDs that are coated with a layer of phosphor material. The LEDs are electrically coupled with a power source. The system further includes a control unit that is configured to control power supplied by the power source to the LEDs based on presence of the perishable items in the compartment.
Abstract translation: 提供了用于存储易腐物品的方法和系统。 该系统包括至少一个封闭的隔间以存储易腐物品。 封闭隔间的至少一个墙壁是可拆卸的,以允许易腐物品进出隔室。 该系统还包括设置在隔室的一个壁上的多个发光二极管(LED)。 LED包括一层或多层涂有磷光体材料层的蓝色LED。 LED与电源电耦合。 该系统还包括控制单元,其被配置为基于存在隔室中的易腐物品来控制由电源向LED提供的电力。
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