Tinctorial composition for keratinous fibres containing oxidation dye
precursors and aminoindole couplers, methods for dyeing using these
compositions and new compounds
    41.
    发明授权
    Tinctorial composition for keratinous fibres containing oxidation dye precursors and aminoindole couplers, methods for dyeing using these compositions and new compounds 失效
    含有氧化染料前体和氨基吲哚成色剂的角质纤维的着色组合物,使用这些组合物染色的方法和新化合物

    公开(公告)号:US5364414A

    公开(公告)日:1994-11-15

    申请号:US916706

    申请日:1992-07-22

    CPC分类号: A61Q5/10 A61K8/492

    摘要: Oxidation tinctorial composition intended to be used for dyeing keratinous fibres, in particular human keratinous fibres and especially hair, characterized in that it contains, in a solvent medium appropriate for dyeing these fibres, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor and at least one heterocyclic coupler corresponding to the formula (I): ##STR1## in which: R.sub.1 and R.sub.3, which may be identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, a carboxyl group or an alkoxycarbonyl group; at least one of the radicals R.sub.2 or R.sub.3 denotes hydrogen;R.sub.4 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl group;the group NHR.sub.4 occupying the positions 4, 6 or 7 of the benzene ring, as well as their salts.

    摘要翻译: 用于染色角质纤维,特别是人角质纤维,特别是毛发的氧化着色组合物,其特征在于,其在适于染色这些纤维的溶剂介质中含有至少一种对氧化染料前体或至少一种邻位氧化 染料前体和对应于式(I)的至少一种杂环成色剂:其中:R 1和R 3可以相同或不同,表示氢原子或C 1 -C 4烷基; R2表示氢原子,C1-C4烷基,羧基或烷氧基羰基; 基团R2或R3中的至少一个表示氢; R4表示氢原子或C1-C4烷基或C1-C4羟烷基或C2-C4多羟基烷基; 占据苯环位置4,6或7的NHR4基团以及它们的盐。

    Tinctorial compositions for keratin fibres containing precursors of
oxidation colorants and indole couplers, and dyeing processes using
these compositions
    42.
    发明授权
    Tinctorial compositions for keratin fibres containing precursors of oxidation colorants and indole couplers, and dyeing processes using these compositions 失效
    含有氧化着色剂和吲哚偶联剂前体的角蛋白纤维的着色组合物和使用这些组合物的染色方法

    公开(公告)号:US5279620A

    公开(公告)日:1994-01-18

    申请号:US871116

    申请日:1992-04-20

    IPC分类号: A61K8/49 A61Q5/10 A61K7/13

    CPC分类号: A61Q5/10 A61K8/492

    摘要: Tinctorial composition for keratin fibers, containing a para-type precursor of an oxidation colorant associated with a heterocyclic coupler of formula: ##STR1## where R.sub.1 .dbd.H, or C.sub.1 -C.sub.4 alkyl; R.sub.2 and R.sub.3, which may be identical or different, denote H, C.sub.1 -C.sub.4 alkyl, carboxyl or alkoxycarbonyl; OH is in position 6 or 7;and/or a salt of such a coupler.This composition allows the hair to be dyed with a color having a good resistance to light, washing, bad weather and perspiration.

    摘要翻译: 角蛋白纤维的着色组合物,其包含与下式的杂环成色剂相关的氧化着色剂的对位型前体:(*化学结构*),其中R 1 = H或C 1 -C 4烷基; R2和R3可以相同或不同,表示H,C1-C4烷基,羧基或烷氧基羰基; OH位于6或7位; 和/或这种成色剂的盐。 这种组合物允许用具有良好耐光性,洗涤性,恶劣天气和汗水的颜色染发头发。

    Meta-phenylenediamines, process for preparation thereof, intermediate
compounds and use of these meta-phenylenediamines as couplers for the
oxidation dyeing of keratinous fibres and especially human hair
    45.
    发明授权
    Meta-phenylenediamines, process for preparation thereof, intermediate compounds and use of these meta-phenylenediamines as couplers for the oxidation dyeing of keratinous fibres and especially human hair 失效
    间苯二胺,其制备方法,中间体化合物和这些间苯二胺作为角质纤维,特别是人发的氧化染色的成色剂的用途

    公开(公告)号:US4960432A

    公开(公告)日:1990-10-02

    申请号:US200170

    申请日:1988-05-31

    CPC分类号: A61K8/411 A61Q5/10

    摘要: New meta-phenylenediamines, process for preparation thereof, intermediate compounds and use of these metaphenylenediamines as couplers for the oxidation dyeing of keratinous fibres and especially human hair.The invention relates to the compounds of the formula: ##STR1## in which R.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical or a C.sub.2 -C.sub.3 mono- or polyhydroxyalkyl radical,Z and Z' denote, independently of one another, a C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 hydroxyalkyl radical, with the proviso that, when R.sub.1 and R.sub.2 simultaneously denote a hydrogen atom, Z and Z' do not simultaneously denote a methyl radical, and to their addition salts with an acid, to a process for preparation thereof and also to their use, by way of couplers, in an aqueous vehicle, in combination with at least one oxidation dye percursor of the para type, for the dyeing of human hair.The invention also relates to the intermediate compounds of the formula: ##STR2## in which R' denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a C.sub.2 or C.sub.3 mono- or polyhydroxyalkyl radical, or an acetyl or .beta.-chloethoxycarbonyl radical, and z and z' denote, independently of one another, a C.sub.1 -C.sub.4 alkyl radical.

    摘要翻译: 新的间苯二胺,其制备方法,中间体化合物以及这些间苯二胺作为角质纤维,特别是人类头发氧化染色的成色剂的用途。 本发明涉及下式的化合物:其中R 1和R 2彼此独立地表示氢原子,C 1 -C 4烷基或C 2 -C 3单 - 或多羟基烷基,Z 和Z'彼此独立地表示C1-C4烷基或C2-C4羟烷基,条件是当R1和R2同时表示氢原子时,Z和Z'不同时表示甲基,并且 与它们与酸的加成盐,涉及其制备方法,以及它们通过成色剂在水性载体中与至少一种对位型氧化染料组合物的组合用于人发染色 。 本发明还涉及下式的中间体化合物:其中R'表示氢原子,C 1 -C 4烷基,C 2或C 3单烷基或多羟基烷基,或乙酰基或β- 氯乙氧基羰基,z和z'彼此独立地表示C1-C4烷基。

    Dyeing compositions for keratinic fibres, based on halogenated
meta-phenylenediamines
    48.
    发明授权
    Dyeing compositions for keratinic fibres, based on halogenated meta-phenylenediamines 失效
    基于卤代间苯二胺的角质纤维染色组合物

    公开(公告)号:US4725283A

    公开(公告)日:1988-02-16

    申请号:US872387

    申请日:1986-06-10

    CPC分类号: A61K8/418 A61Q5/065

    摘要: The invention relates to dyeing compositions for direct dyeing of keratinic fibres, containing, in a cosmetically acceptable medium:(a) at least one yellow or green-yellow dye corresponding to the formula (I): ##STR1## in which X=Cl, Br, F, and R.sub.1 and R.sub.2 denote, independently of each other, hydrogen, alkyl, hydroxyalkyl, or alkylaminoalkyl in which the aminoalkyl group may be mono- or disubstituted provided that R.sub.1 and R.sub.2 do not simultaneously denote a hydrogen atom, and(b) at least one blue or violet dye corresponding to the formula: ##STR2## in which R.sub.3 denotes a hydrogen atom or an alkyl, monohydroxyalkyl, polyhydroxyalkyl or alkoxyalkyl radical and R.sub.4 and R.sub.5 have separately the same meanings as R.sub.3 but cannot denote a hydrogen atom.

    摘要翻译: 本发明涉及用于直接染色角蛋白纤维的染色组合物,其包含在化妆品可接受的介质中:(a)至少一种对应于式(I)的黄色或绿黄色染料:其中X = Cl,Br,F和R 1和R 2彼此独立地表示氢,烷基,羟基烷基或烷基氨基烷基,其中氨基烷基可以被单或二取代,条件是R 1和R 2不同时表示氢原子, 和(b)对应于下式的至少一种蓝色或紫色染料:其中R 3表示氢原子或烷基,单羟基烷基,多羟基烷基或烷氧基烷基,R 4和R 5分别具有与R 3 但不能表示氢原子。

    Tinctorial composition for keratinous fibers containing oxidation dye
precursors and couplers derived from 4-hydroxyindole, and dyeing method
using them
    50.
    发明授权
    Tinctorial composition for keratinous fibers containing oxidation dye precursors and couplers derived from 4-hydroxyindole, and dyeing method using them 失效
    含有氧化染料前体和衍生自4-羟基吲哚的成色剂的角质纤维的着色组合物和使用它们的染色方法

    公开(公告)号:US5609649A

    公开(公告)日:1997-03-11

    申请号:US262444

    申请日:1994-06-20

    CPC分类号: A61Q5/10 A61K8/492

    摘要: Tinctorial composition for keratinous fibers, in particular for human hair, characterized in that it contains, in a medium appropriate for dyeing these fibers, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor in combination with at least one heterocyclic coupler, corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; R.sub.3 denotes a hydrogen or halogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical, an alkoxycarbonyl radical or a formyl radical; X denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a halogen atom, a C.sub.1 -C.sub.4 alkoxy radical, an acetylamino group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group; at least one of the groups X, R.sub.1, R.sub.2 and R.sub.3 differing from hydrogen; as well as their salts.

    摘要翻译: 用于角质纤维,特别是人类头发的着色组合物,其特征在于,在适于对这些纤维进行染色的介质中含有至少一种对氧化染料前体或至少一种邻位氧化染料前体与至少一种杂环成色剂 对应于下式:其中R 1表示氢原子或C 1 -C 4烷基; R2表示氢原子,C1-C4低级烷基,羧基或烷氧基羰基; R3表示氢或卤素原子,C1-C4低级烷基,羧基,烷氧基羰基或甲酰基; X表示氢原子,C1-C4烷基,卤素原子,C1-C4烷氧基,乙酰氨基或二烷基(C1-C4)氨基甲基; X,R1,R2和R3中的至少一个不同于氢; 以及它们的盐。