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公开(公告)号：US06562937B2
公开(公告)日：2003-05-13
申请号：US09795180
申请日：2001-03-01
IPC分类号： C08H6368
CPC分类号： C08G64/24
摘要： In a continuous flow reactor one or more bisphenols is converted by the action of phosgene and aqueous base into a mixture of mono- and bisphenol chloroformates which are then treated with a catalyst, additional aqueous caustic and a monophenol to afford endcapped polycarbonates. At relatively high levels of added monophenol endcapped polycarbonate oligomers are obtained. The method is especially suited for the continuous preparation of endcapped oligomers of tetrabromobisphenol A polycarbonate. The method is characterized by efficient use of phosgene, and conversion of chloroformate groups to carbonate linkages aided by trialkylamine catalysts bearing at least one methyl group on nitrogen, such as N,N-dimethylbutylamine (DMBA).
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42.发明授权Aqueous hexasubstituted guanidinium chlorides and methods for their preparation and use 失效六取代氯化胍水溶液及其制备和使用方法公开(公告)号：US06235934B1
公开(公告)日：2001-05-22
申请号：US09216252
申请日：1998-12-17
申请人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
发明人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
IPC分类号： C07C27902
CPC分类号： C08G73/1021 , C07C277/00
摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts for the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.
摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作六取代胍盐的源，其可用作用于使二羟基芳族化合物与取代酰亚胺的碱金属盐反应形成聚醚酰亚胺或其中间体的相转移催化剂。
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公开(公告)号：US6020456A
公开(公告)日：2000-02-01
申请号：US186705
申请日：1998-11-06
CPC分类号： C08G73/1064 , C08G73/1042 , C08G73/105 , C08G73/106
摘要： Copolyetherimides are prepared by conventional means from hindered diamines such as the isomeric methyl-4,6-diethyl-1,3-phenylenediamines and bis(2-chloro-4-amino-3,5-diethylphenyl)methane. They have unusually high glass transition temperatures.
摘要翻译： 共聚醚酰亚胺通过常规方法由受阻二胺如异构甲基-4,6-二乙基-1,3-苯二胺和双（2-氯-4-氨基-3,5-二乙基苯基）甲烷制备。 它们具有非常高的玻璃化转变温度。
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44.发明授权Diaminoalkyl quaternary ammonium salts and method for their preparation and use 失效二氨基烷基季铵盐及其制备和使用方法
公开(公告)号：US5821322A
公开(公告)日：1998-10-13
申请号：US851260
申请日：1997-05-05
申请人： Daniel Joseph Brunelle , Peter David Phelps , Eugene Pauling Boden , Mark Erik Nelson , Larry Ivis Flowers , Paul Dean Sybert , Erik Hendrick Adriaan Capelle
发明人： Daniel Joseph Brunelle , Peter David Phelps , Eugene Pauling Boden , Mark Erik Nelson , Larry Ivis Flowers , Paul Dean Sybert , Erik Hendrick Adriaan Capelle
IPC分类号： C07D295/02 , B01J31/02 , C07B61/00 , C07C68/02 , C07C69/96 , C07C209/12 , C07C211/63 , C07D295/13 , C08G64/22 , C08G64/24 , C08G64/00
CPC分类号： C07D295/13 , C07C211/63 , C08G64/24
摘要： Diaminoalkyl quaternary ammonium salts are prepared by the reaction of alkyl halides with tertiary diamines having C.sub.2-20 primary alkyl radicals attached to nitrogen and an alkyl radical between the two nitrogen atoms in which at least three carbon atoms separate said nitrogen atoms. Said salts are preferably substantially free from corresponding diamines. They are useful as catalysts for interfacial polycarbonate preparation by the reaction of phosgene with at least one dihydroxyaromatic compound. Polycarbonate preparation using such catalysts is economical in phosgene consumption, is accompanied by a rapid conversion of chloroformate groups to desirable species and affords a product with a very low proportion of unreacted dihydroxyaromatic compound.
摘要翻译： 二氨基烷基季铵盐通过烷基卤与与氮连接的具有C2-20伯烷基的叔二胺和两个氮原子之间的烷基与其中至少三个碳原子分开所述氮原子的烷基反应来制备。 所述盐优选基本上不含相应的二胺。 它们可用作通过光气与至少一种二羟基芳族化合物反应的界面聚碳酸酯制备的催化剂。 使用这种催化剂的聚碳酸酯制备在光气消耗中是经济的，伴随着氯甲酸酯基团快速转化为所需物质并提供具有非常低比例的未反应的二羟基芳族化合物的产物。
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公开(公告)号：US5710086A
公开(公告)日：1998-01-20
申请号：US618738
申请日：1996-03-20
CPC分类号： C08G63/85 , B01J31/1805 , B01J31/223 , B01J31/2239 , C07F7/006 , B01J2531/0216 , B01J2531/0247 , B01J2531/46 , B01J31/0212
摘要： Reaction mixtures prepared from tetraalkyl titanates and mixtures of glycols, said reaction mixtures comprising titanium bisglycoxide oligomers, may be used as depolymerization catalysts for conversion of linear polyesters to macrocyclic polyester oligomers.
摘要翻译： 由四烷基钛酸盐和二醇的混合物制备的反应混合物，所述反应混合物包括双羟基碳酸二烷基酯低聚物，可用作用于将线性聚酯转化为大环聚酯低聚物的解聚催化剂。
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46.发明申请公开(公告)号：US20120130042A1
公开(公告)日：2012-05-24
申请号：US13361679
申请日：2012-01-30
IPC分类号： C08G75/23
摘要： Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12 aliphatic radical, C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical.
摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2和R 3在每次出现时独立地为卤素原子，硝基，氰基，C 1 -C 12脂族基，C 3 -C 12脂环族基团或C 3 -C 12芳族基团; n，m，q各自独立地为0至4的整数; 且Q为C 3 -C 20脂环族基团或C 3 -C 20芳族基团。
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47.发明授权公开(公告)号：US08106135B2
公开(公告)日：2012-01-31
申请号：US11552276
申请日：2006-10-24
IPC分类号： C08G75/23 , C08F283/06 , C08L81/00
摘要： Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12 aliphatic radical, C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical.
摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2和R 3在每次出现时独立地为卤素原子，硝基，氰基，C 1 -C 12脂族基，C 3 -C 12脂环族基团或C 3 -C 12芳族基团; n，m，q各自独立地为0至4的整数; 且Q为C 3 -C 20脂环族基团或C 3 -C 20芳族基团。
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公开(公告)号：US20110240550A1
公开(公告)日：2011-10-06
申请号：US12751824
申请日：2010-03-31
申请人： David Roger Moore , Hongyi Zhou , Matthew Jeremiah Misner , Xiaohui Chen , Lifeng Zhang , Daniel Joseph Brunelle , Minglin Ma
发明人： David Roger Moore , Hongyi Zhou , Matthew Jeremiah Misner , Xiaohui Chen , Lifeng Zhang , Daniel Joseph Brunelle , Minglin Ma
CPC分类号： B01D71/80 , B01D67/0006 , B01D67/0011 , B01D69/10 , B01D71/68 , B01D2323/22 , B01D2325/28 , B01D2325/36 , C08L81/06
摘要： A separation matrix comprises a porous surface layer; and a bulk porous support, wherein both the porous surface layer and the bulk porous support comprising a block copolymer. The block copolymer comprises A-B or A-B-A repeating units, wherein A and B at each occurrence are two different blocks of oligomer, or polymer. A structural unit of block A is derived from one or more atom transfer radical polymerization (ATRP)-active monomer or oligomer and a structural unit of block B is derived from a thermoplastic ATRP-active macro initiator. A poly dispersity index of the block copolymer is at least about 2.
摘要翻译： 分离基质包括多孔表面层; 和多孔支撑体，其中多孔表面层和本体多孔载体均包含嵌段共聚物。 嵌段共聚物包含A-B或A-B-A重复单元，其中A和B每次出现时是两个不同的低聚物或聚合物嵌段。 嵌段A的结构单元衍生自一种或多种原子转移自由基聚合（ATRP）活性单体或低聚物，并且嵌段B的结构单元衍生自热塑性ATRP活性的大分子引发剂。 嵌段共聚物的聚分散指数为至少约2。
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公开(公告)号：US07605222B2
公开(公告)日：2009-10-20
申请号：US11210164
申请日：2005-08-22
申请人： Qing Ye , David Bruce Hall , William David Richards , Daniel Joseph Brunelle , Havva Yagci Acar
发明人： Qing Ye , David Bruce Hall , William David Richards , Daniel Joseph Brunelle , Havva Yagci Acar
IPC分类号： C08G73/00
CPC分类号： C08G73/1046 , C08G73/124
摘要： Copolyetherimides compositions having high glass transition temperatures and outstanding ductility are presented. The copolyetherimides having Mw of at least 40,000 comprising isomeric bis(phthalimide) structural units within a relatively narrow range of isomer proportions exhibited Tgs of at least 240° C. and outstanding Notched Izod values. The copolyetherimides comprise oxydianiline residues and structural units of the formulas (I) and (II) (III). The copolyetherimides are characterized by a mole percentage of structural units derived from 4,4′-biphenol in a range from about 55% to about 85% of all bisphenol-derived structural units present in the copolyetherimide composition; a mole percentage of structural units derived from bisphenol A in a range from about 45% to about 15% of all bisphenol-derived structural units present in the copolyetherimide composition; and a total mole percentage of structural units derived from bisphenol A or 4,4′-biphenol of at least 95% of all bisphenol-derived structural units present in the copolyetherimide composition.
摘要翻译： 提出了具有高玻璃化转变温度和优异延展性的共聚酰亚胺组合物。 具有至少40,000的Mw的共聚醚酰亚胺，其包含在相对窄的异构体比例范围内的异构双（邻苯二甲酰亚胺）结构单元，其Tg至少为240℃，并且具有优异的缺口伊佐德值。 共聚醚酰亚胺包括氧化二苯胺残基和式（I）和（II）（III）的结构单元。 共聚醚酰亚胺的特征在于衍生自4,4'-联苯酚的结构单元的百分比在共聚醚酰亚胺组合物中存在的所有双酚衍生的结构单元的约55％至约85％的范围内; 来自双酚A的结构单元的摩尔百分比在存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的约45％至约15％的范围内; 并且衍生自双酚A或4,4'-联苯酚的结构单元的总摩尔百分比为存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的至少95％。
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50.发明授权公开(公告)号：US07557174B2
公开(公告)日：2009-07-07
申请号：US11528206
申请日：2006-09-27
CPC分类号： C08G63/85 , C08G63/191 , C08G63/64
摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of at least some phenoxy end groups.
摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。
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