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    Substituted diphenyldiphosphines and a process for their preparation
    42.
    发明授权
    Substituted diphenyldiphosphines and a process for their preparation 失效
    取代的二苯基二膦及其制备方法

    公开(公告)号：US5972825A

    公开(公告)日：1999-10-26

    申请号：US95195

    申请日：1998-06-10

    申请人： Dieter Regnat ,  Hans-Jerg Kleiner ,  Helmut Bahrmann

    发明人： Dieter Regnat ,  Hans-Jerg Kleiner ,  Helmut Bahrmann

    IPC分类号： C07F9/50 ,  B01J21/18

    CPC分类号： C07F9/5027

    摘要： The present invention relates to compounds of the formula (I) ##STR1## where R.sup.1 is H or an alkyl radical having from 1 to 12 carbon atoms, R.sup.2 is a straight-chain alkylene radical having from 1 to 8 carbon atoms, an oxygen-containing alkylene radical having from 2 to 4 carbon atoms, a radical of the formula (II) or (III) ##STR2## or a cycloalkylene radical having from 3 to 10 carbon atoms, R.sup.3 is an alkyl radical having from 1 to 25 carbon atoms or an aryl radical having from 6 to 10 carbon atoms, A is a radical --COO.sup.- or --SO.sub.3 .sup.- and x=0, y=1, m=1 and n=1, or x=1, y=1, m=(1 or 2) and n=(1 or 2), or, if R.sup.2 is a radical of the formula (II) or (III), x=1, y=0, m=(0 or 1) and n=(0 or 1), and also a process for their preparation.

    摘要翻译： 本发明涉及式（I）化合物，其中R 1为H或具有1至12个碳原子的烷基，R 2为具有1至8个碳原子的直链亚烷基，含氧亚烷基 具有2至4个碳原子的式（II）或（III）的基团或具有3至10个碳原子的亚环烷基，R 3是具有1至25个碳原子的烷基或具有 6至10个碳原子，A是基团-COO-或-SO 3 - ，x = 0，y = 1，m = 1和n = 1，或x = 1，y = 1，m =（1或2） 或n =（1或2），或者如果R2是式（II）或（III）的基团，则x = 1，y = 0，m =（0或1）和n =（0或1） ，以及它们的制备过程。

    Process for the preparation of aldehydes
    44.
    发明授权
    Process for the preparation of aldehydes 失效
    醛的制备方法

    公开(公告)号：US4578523A

    公开(公告)日：1986-03-25

    申请号：US738822

    申请日：1985-05-29

    申请人： Helmut Bahrmann ,  Boy Cornils ,  Werner Konkol ,  Wolfgang Lipps

    发明人： Helmut Bahrmann ,  Boy Cornils ,  Werner Konkol ,  Wolfgang Lipps

    IPC分类号： C07C45/50

    CPC分类号： C07C45/50

    摘要： A novel process for the preparation of aldehydes by reacting olefins with carbon monoxide and hydrogen in the presence of a catalyst system comprised of rhodium in metallic form or as a compound and a water-soluble quaternary ammonium salt of a mono, di or trisulfonated arylphosphine.

    摘要翻译： 一种用于通过烯烃与一氧化碳和氢气在由金属形式的铑或作为化合物和单，二或三磺化芳基膦的水溶性季铵盐的催化剂体系存在下反应来制备醛的新方法。

    Process for the preparation of 3-(4-methyl-3-cyclohexen-1-yl) butyraldehyde
    45.
    发明授权
    Process for the preparation of 3-(4-methyl-3-cyclohexen-1-yl) butyraldehyde 失效
    3-（4-甲基-3-环己烯-1-基）丁醛的制备方法

    公开(公告)号：US4337363A

    公开(公告)日：1982-06-29

    申请号：US69659

    申请日：1979-08-24

    申请人： Helmut Bahrmann ,  Boy Cornils ,  Carl D. Frohning ,  Jurgen Weber

    发明人： Helmut Bahrmann ,  Boy Cornils ,  Carl D. Frohning ,  Jurgen Weber

    IPC分类号： B01J31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/225 ,  C07C67/00

    CPC分类号： C07C45/50

    摘要： In a process for the preparation of 3-(4-methyl-3-cyclohexen-1-yl) butyraldehyde by hydroformylation of limonene in the presence of a catalyst containing a metal of Group VIII of the Periodic Table, the improvement wherein a rhodium carbonyl complex containing additionally a triphenyl and/or trialkyl phosphine as ligands is used as catalyst and the reaction is conducted at a pressure of 100 to 350 bars and at a temperature of 110.degree. to 160.degree. C., the triphenyl or trialkyl phosphines or mixture thereof being present in an amount of 10 to 50 moles per gram atom of rhodium in the reaction mixture.

    摘要翻译： 在通过在含有元素周期表第Ⅷ族金属的催化剂的存在下，通过柠檬烯的加氢甲酰化制备3-（4-甲基-3-环己烯-1-基）丁醛的方法，其中铑羰基 使用另外含有三苯基和/或三烷基膦作为配体的络合物用作催化剂，反应在100至350巴的压力和110至160℃的温度下进行，三苯基或三烷基膦或其混合物 在反应混合物中以每克原子的铑含量为10至50摩尔。

    Process for the preparation of aldehydes by means of a catalyst system comprising rhodium and substituted diphenyldiphospines
    47.
    发明授权
    Process for the preparation of aldehydes by means of a catalyst system comprising rhodium and substituted diphenyldiphospines 失效
    通过包含铑和取代的二苯基二磷的催化剂体系制备醛的方法

    公开(公告)号：US5801291A

    公开(公告)日：1998-09-01

    申请号：US813877

    申请日：1997-03-07

    申请人： Helmut Bahrmann ,  Hans-Jerg Kleiner ,  Dieter Regnat

    发明人： Helmut Bahrmann ,  Hans-Jerg Kleiner ,  Dieter Regnat

    IPC分类号： B01J31/24 ,  B01J31/28 ,  B01J31/40 ,  C07B61/00 ,  C07C45/50 ,  C07C45/78 ,  C07C47/02

    CPC分类号： B01J31/04 ,  B01J31/2409 ,  B01J31/2414 ,  B01J31/2452 ,  B01J31/4046 ,  B01J31/4061 ,  C07C45/50 ,  C07C45/786 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2540/40 ,  B01J2540/42 ,  Y02P20/584

    摘要： The present invention relates to a process for the preparation of aldehydes, which comprises reacting an olefinic compound having 2 to 20 carbon atoms with carbon monoxide and hydrogen, in the presence or absence of a solvent, in the presence of a catalyst comprising rhodium and a compound or a mixture of compounds of the formula (I) ##STR1## in which R.sup.1 is H or an alkyl radical having 1 to 12 carbon atoms, R.sup.2 is a straight-chain alkylene radical having 1 to 8 carbon atoms, an oxygen-containing alkylene radical having 2 to 4 carbon atoms, a radical of the formula (II) or (III) ##STR2## or a cycloalkylene radical having 3 to 10 carbon atoms, R.sup.3 is an alkyl radical having 1 to 25 carbon atoms or an aryl radical having 6 to 10 carbon atoms, A is a radical --COO.sup.- or --SO.sub.3.sup.- and x=0, y=1, m=1 and n=1, or x=0.1, y=1, m=(1 or 2) and n=(1 or 2), or, if R.sup.2 is a radical of the formula (II) or (III), x=1, y=0, m=(0 or 1) and n=(0 or 1), at a temperature from 50.degree. to 190.degree. C. and under a pressure from 0.1 to 45 MPa, and separating the reaction product off from the catalyst.

    摘要翻译： 本发明涉及醛的制备方法，其包括在存在或不存在溶剂的情况下，使含有2-20个碳原子的烯属化合物与一氧化碳和氢反应，在包含铑和 化合物或其中R 1为H或具有1至12个碳原子的烷基的式（I）化合物（I）的化合物，R 2为具有1至8个碳原子的直链亚烷基， 具有2至4个碳原子的含氧亚烷基，式（II）或（III）的基团（III）或具有3至10个碳原子的亚环烷基，R 3是 具有1至25个碳原子的烷基或具有6至10个碳原子的芳基，A是基团-COO-或-SO 3 - ，x = 0，y = 1，m = 1和n = 1，或x = 0.1，y = 1，m =（1或2）和n =（1或2），或者如果R2是式（II）或（III）的基团，x = 1，y = 0，m = （0或1）和n =（0或1），在50°至190℃的温度下 并在0.1至45MPa的压力下，将反应产物与催化剂分离。

    Reactivation of water-soluble hydroformylation catalysts
    48.
    发明授权
    Reactivation of water-soluble hydroformylation catalysts 失效
    水溶性加氢甲酰化催化剂的再活化

    公开(公告)号：US5466644A

    公开(公告)日：1995-11-14

    申请号：US378861

    申请日：1995-01-19

    申请人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    发明人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    IPC分类号： B01J27/185 ,  B01J27/28 ,  B01J31/24 ,  B01J31/40 ,  B01J38/48 ,  C07B61/00 ,  C07C27/20 ,  C07C27/22 ,  C07C45/50 ,  C07C45/85 ,  C07C47/02 ,  B01J38/62

    CPC分类号： B01J31/4046 ,  B01J31/20 ,  B01J31/2404 ,  B01J31/2447 ,  C07C45/50 ,  C07C45/85 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/96 ,  Y02P20/584

    摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.

    摘要翻译： 一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物， 由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯 （-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为 单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。

    Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom
    50.
    发明授权
    Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom 失效
    用铑催化剂加氢甲酰化和从中分离铑的方法

    公开(公告)号：US4731485A

    公开(公告)日：1988-03-15

    申请号：US9734

    申请日：1987-02-02

    申请人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

    发明人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

    IPC分类号： C07C45/50

    CPC分类号： C07C45/50

    摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.

    摘要翻译： 一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。 还阐述了在络合剂和增溶剂存在下制备醛的方法。 增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个 碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。