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公开(公告)号：US5776666A
公开(公告)日：1998-07-07
申请号：US25474
申请日：1993-03-03
摘要： A method of accelerating black and white development comprising contacting a negative-type silver halide photographic element during processing with a developer prebath or a developer bath comprising an accelerator compound of the formula: ##STR1## is disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.3 may further combine with each other to form a 5-, 6-, or 7-membered ring; and wherein said developer prebath and developer bath do not contain any iron(III) ion complex salt having bleaching activity. A bath selected from the group consisting of developer prebaths and developer baths for black and white development of a negative-type silver halide photographic element comprising an aqueous solution of accelerator compound of the formula: ##STR2## is also disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.3 may further combine with each other to form a 5-, 6-, or 7-membered ring; with the proviso that said developer prebath and developer bath do not contain any iron(III) ion complex salt having bleaching activity or any nucleating agent capable of chemically fogging a negative-type silver halide emulsion; and said accelerator compound is present in an amount between 10.sup.-8 and 10.sup.-1 moles/L.
摘要翻译： 一种促进黑白发展的方法包括在加工过程中将负型卤化银照相元件与显影剂预浴液或包含下式的促进剂化合物的显色剂浴接触：其中R1，R2和R3为 取代基; 所述R 1，R 2和R 3可以进一步彼此结合形成5-，6-或7-元环; 并且其中所述显影剂预浴和显影剂浴不含有具有漂白活性的任何铁（III）离子络合物盐。 还公开了选自由显影剂前体和显色剂浴组成的组的浴，其用于黑色和白色显影的负型卤化银照相元件，其包含下式的促进剂化合物的水溶液：其中R1，R2， 和R3是取代基; 所述R 1，R 2和R 3可以进一步彼此结合形成5-，6-或7-元环; 条件是所述显影剂预浴和显影剂浴不含有具有漂白活性的任何铁（III）离子络合盐或能够化学起雾负型卤化银乳剂的任何成核剂; 并且所述加速剂化合物的存在量为10-8至10-1摩尔/ L。
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公开(公告)号：US5723255A
公开(公告)日：1998-03-03
申请号：US487373
申请日：1995-06-07
申请人： John Texter , David Alan Czekai
发明人： John Texter , David Alan Czekai
CPC分类号： G03C8/402
摘要： An aqueous solid particle dispersion of a thermal solvent, where said thermal solvent is a water-immiscible phenol derivative and has a melting point, T.sub.m, between 30.degree. C. and about 200.degree. C., wherein said dispersion contains a dispersing aid, and wherein the thermal solvent particles in said dispersion are essentially nanocrystalline is disclosed. Also disclosed is a process for forming a coating comprising the steps of:providing an aqueous solid particle dispersion of thermal solvent, where said thermal solvent is a water-immiscible phenol derivative and has a melting point, T.sub.m, between 30.degree. C. and about 200.degree. C., and where said dispersion contains a dispersing aid; combining said aqueous solid particle thermal solvent dispersion with a coating melt composition, where said coating melt composition is maintained at a temperature, T.sub.c, during the preparation and coating of said coating melt composition, and where T.sub.c
摘要翻译： 一种热溶剂的水性固体颗粒分散体，其中所述热溶剂是水不混溶性酚衍生物，并且具有在30℃至约200℃之间的熔点Tm，其中所述分散体含有分散助剂，和 其中所述分散体中的热溶剂颗粒基本上是纳米晶体。 还公开了一种形成涂层的方法，包括以下步骤：提供热溶剂的固体颗粒水分散体，其中所述热溶剂是水不混溶的苯酚衍生物，并且具有30℃至约30℃的熔点Tm 并且其中所述分散体含有分散助剂; 将所述水性固体颗粒热溶剂分散体与涂料熔融组合物组合，其中所述涂料熔融组合物在制备和涂覆所述涂料熔融组合物期间保持在Tc的温度，并且其中Tc
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43.发明授权Blocked photographically useful compounds for use with peroxide-containing processes 失效用于含过氧化物的工艺的封闭的有用的化合物
公开(公告)号：US5538834A
公开(公告)日：1996-07-23
申请号：US342983
申请日：1994-11-21
IPC分类号： G03C1/43 , C07C303/36 , C07C303/38 , C07C311/05 , G03C7/30 , G03C7/305 , G03C7/407
CPC分类号： C07C303/36 , C07C303/38 , G03C7/302 , G03C7/30511 , Y10S430/144 , Y10S430/156 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A method is disclosed for developing an image in a photographic element comprising a support, a silver halide emulsion containing an imagewise distribution of developable silver halide grains, and a blocked photographically useful compound comprising a photographically useful group and a blocking group capable of releasing the photographically useful group upon processing the photographic element in the presence of a peroxide, wherein the blocking group comprises an electrophilic group which is solely capable of undergoing a nucleophilic displacement reaction, the electrophilic group being bonded directly or through a releasable timing group to the photographically useful group, with the proviso that when the photographically useful group is a development inhibitor, the blocking group is bonded to the photographically useful group through at least one releasable timing group. The method comprises the step of contacting the photographic element with a processing solution comprising a peroxide.
摘要翻译： 公开了一种用于在照相元件中显影图像的方法，该照相元件包括载体，含有可显影卤化银颗粒的成像分布的卤化银乳剂，以及包含摄影有用的基团和能够照相地释放的封闭基团的封闭照相用化合物 在过氧化物存在下处理照相元件的有用基团，其中所述封闭基团包括仅能够进行亲核置换反应的亲电子基团，所述亲电子基团直接键合或通过可释放定时基团键合至照相用的基团 条件是当照相有用的基团是显影抑制剂时，封闭基团通过至少一个可释放定时基团与照相用组合键合。 该方法包括使照相元件与包含过氧化物的处理溶液接触的步骤。
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44.发明授权
公开(公告)号：US5494775A
公开(公告)日：1996-02-27
申请号：US331426
申请日：1994-10-31
申请人： John Texter
发明人： John Texter
IPC分类号： G03C8/40
CPC分类号： G03C8/402 , Y10S430/156
摘要： A diffusion transfer process is disclosed for forming a color photographic image comprising the steps of:providing an aqueous-developable photographic color diffusion transfer element of two or more layers comprising a single dimensionally stable support, radiation sensitive silver halide, an aqueous solid particle thermal solvent dispersion for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing or dye-forming coupler compound, and hydrophilic binder, wherein said dye is heat transferable in said binder and said thermal solvent, said thermal solvent has a melting point between 50.degree. C. and about 200.degree. C., said dispersion contains a dispersing aid, and said thermal solvent is incorporated at 5 to 200% by weight of said hydrophilic binder;exposing said element to actinic radiation;processing said element by contacting said element to an external aqueous bath containing compounds selected from the group consisting of conventional color developer compounds of the primary amine type, compounds which activate the release of incorporated color developers, and compounds which activate development by incorporated dye developers;washing said element;drying said clement to remove imbibed water; andheating said element to effect dye diffusion transfer to an image receiving layer, wherein bleaching and fixing steps are absent in said diffusion transfer process.
摘要翻译： 公开了用于形成彩色摄影图像的扩散转移方法，其包括以下步骤：提供包含单维稳定载体，辐射敏感卤化银，水性固体颗粒热溶剂的两层或多层的水性可显影照相色彩扩散转移元件 用于促进染料通过亲水性粘合剂，染料释放或染料形成成色剂化合物和亲水性粘合剂的热扩散的分散体，其中所述染料在所述粘合剂和所述热溶剂中是可热转移的，所述热溶剂的熔点在 50℃和约200℃，所述分散体含有分散助剂，所述热溶剂加入所述亲水性粘合剂的5至200重量％; 将所述元件暴露于光化辐射; 通过使所述元件与包含选自常规的伯胺型常规彩色显影剂化合物，激活合并的显色剂的释放的化合物和通过引入的染料显影剂激活显影的化合物的化合物接触所述元件来处理所述元件; 洗涤元素; 干燥所述清洁剂以除去吸入的水; 并加热所述元件以进行染料扩散转移到图像接收层，其中在所述扩散转移过程中不存在漂白和固定步骤。
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45.发明授权
公开(公告)号：US5470688A
公开(公告)日：1995-11-28
申请号：US250146
申请日：1994-05-27
CPC分类号： G03C8/10 , G03C8/4013 , Y10S430/159
摘要： In accordance with this invention a heat-developable photographic color diffusion transfer element is provided, where this element comprises a dimensionally stable support and one or more layers comprising radiation sensitive silver halide, an organic silver salt oxidizing agent, a reducing agent, a methine-dye releasing compound, and a binder, wherein said methine-dye is heat diffusible in said element, and wherein said methine-dye releasing compound is of the structureCp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.
摘要翻译： 根据本发明，提供了一种可热显影的照相彩色扩散转移元件，其中该元件包括尺寸稳定的支撑体和一个或多个包含辐射敏感卤化银，有机银盐氧化剂，还原剂，次甲基 - 染料释放化合物和粘合剂，其中所述次甲基染料在所述元件中是可热扩散的，并且其中所述次甲基染料释放化合物具有结构Cp-LM（I），其中Cp是在与 二价连接基团L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来 。
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46.发明授权Low volume processing for establishing boundary conditions to control developer diffusion in color photographic elements 失效用于建立边界条件以控制彩色照相元件中的显影剂扩散的低体积处理
公开(公告)号：US5411840A
公开(公告)日：1995-05-02
申请号：US992303
申请日：1992-12-21
申请人： John Texter , Roland G. Willis
发明人： John Texter , Roland G. Willis
CPC分类号： G03C7/407 , G03C1/42 , G03C7/30511 , Y10S430/144 , Y10S430/16 , Y10S430/164
摘要： A method of forming chromogenic photographic image comprising the steps of:providing an aqueous developable photographic element coated on a single dimensionally stable support, wherein said element comprises in reactive association (1) a developing agent, where said developing agent is a primary amine or a precursor of a primary amine, (2) radiation sensitive silver halide, (3) a color coupler compound that forms or releases a dye upon reaction with the oxidation product of a primary amine developing agent, and (4) a hydrophilic binder;exposing said element to actinic radiation; anddeveloping said image by contacting said element with an applied volume of an aqueous processing solution, wherein said applied volume is limited to less than 800% of the swell volume of said element in equilibrium-mechanical contact with said processing solution or the temporal duration of said contacting is limited to a time less than 500% of the time necessary for said element to swell to 90% of said swell volume.
摘要翻译： 一种形成生色摄影图像的方法，包括以下步骤：提供涂覆在单维稳定载体上的水性可显影照相元件，其中所述元件包括反应性缔合（1）显影剂，其中所述显影剂是伯胺或 伯胺的前体，（2）辐射敏感的卤化银，（3）与伯胺显影剂的氧化产物反应时形成或释放染料的着色成色剂化合物，和（4）亲水性粘合剂; 将所述元件暴露于光化辐射; 并且通过使所述元件与施加体积的水性处理溶液接触来显影所述图像，其中所述施加的体积被限制在与所述处理溶液平衡 - 机械接触的所述元件的溶胀体积的小于800％ 所述接触限制在所述元件膨胀至所述膨胀体积的90％所需时间的500％以下的时间。
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公开(公告)号：US5401623A
公开(公告)日：1995-03-28
申请号：US956140
申请日：1992-10-05
申请人： John Texter
发明人： John Texter
CPC分类号： G03C7/388 , Y10S430/136
摘要： A photographic coupler dispersion comprising colloidal microcrystalline particles of coupler, wherein said particles are wetted with an activating and water-immiscible organic solvent, and a color photographic element comprising a support bearing at least one photographic silver halide emulsion layer and a microcrystalline coupler dispersion in reactive association with said emulsion layer, wherein said coupler is wetted with an activating water-immiscible organic solvent are disclosed.
摘要翻译： 一种照相成色剂分散体，其包含成色剂的胶体微晶颗粒，其中所述颗粒用活化和水不混溶的有机溶剂润湿，以及彩色照相元件，其包含支持至少一种照相卤化银乳剂层的支持物和具有反应性的微晶成色剂分散体 与所述乳剂层结合，其中所述成色剂用活化水不混溶的有机溶剂润湿。
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公开(公告)号：US5354642A
公开(公告)日：1994-10-11
申请号：US927691
申请日：1992-08-10
申请人： John Texter , Tienteh Chen , Ronald H. White
发明人： John Texter , Tienteh Chen , Ronald H. White
CPC分类号： G03C8/4033 , G03C7/3275 , G03C8/4066
摘要： A process is disclosed for forming a dye image including the steps of:exposing a photographic element comprising a support bearing a light sensitive silver halide emulsion layer containing a polymeric color coupler compound capable of forming a heat transferable dye upon development, wherein the polymeric color coupler compound is of the formula:COUP-L-B wherein COUP represents a coupler moiety capable of forming a heat transferable dye upon reaction of the moiety with an oxidation product of a color developer; L is a divalent linking group which is separated from COUP upon reaction of the coupler moiety with said oxidation product of a color developer; and B represents the polymeric backbone;developing said exposed element with a color developer solution to form a heat transferable dye image;heating said exposed, developed element to thereby transfer the dye image from the emulsion layer to a dye receiving layer, where said receiving layer is part of the photographic element or part of a separate dye receiving element brought into contact with the photographic element; andseparating the emulsion layer from the dye receiving layer containing the transferred dye image.
摘要翻译： 公开了一种用于形成染料图像的方法，包括以下步骤：将包含载体的载体的照相元件曝光，所述载体含有能够显影后能够形成可热转移染料的聚合物着色偶合剂化合物的感光卤化银乳剂层，其中聚合物颜色成色剂 化合物具有下式：COUP-LB，其中COUP表示当该部分与彩色显影剂的氧化产物反应时能够形成可传热染料的成色剂部分; L是当成色剂部分与显色剂的氧化产物反应时与COUP分离的二价连接基团; B代表聚合物骨架; 用显色剂溶液显影所述暴露的元件以形成可传热的染料图像; 加热所述暴露的显影元件，从而将染料图像从乳剂层转移到染料接收层，其中所述接收层是照相元件的一部分或与照相元件接触的分离的染料接收元件的一部分; 并将乳剂层与含有转印的染料图像的染料接收层分离。
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公开(公告)号：US5274109A
公开(公告)日：1993-12-28
申请号：US812519
申请日：1991-12-20
申请人： John Texter
发明人： John Texter
IPC分类号： C09B23/00 , C09B23/02 , C09B67/46 , G03C1/825 , G03C1/83 , C07D231/20 , C07D231/22 , C07D231/26
CPC分类号： C09B23/02 , C09B67/0084 , G03C1/832
摘要： A microprecipitated dispersion comprising a methine oxonol filter dye is provided which has the formula ##STR1## wherein n is 0, 1, or 2; R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different substituted or unsubstituted alkyl or aryl groups, one or more of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 contains carboxy substituent --CO.sub.2 Z, wherein Z.sup.+ is a statistical mixture of hydrogen (H.sup.+) and alkali or tetraalkylammonium cations (M.sup.+) such that Z.sup.+ =xH.sup.+ +(1-x)M.sup.+, where x is a decimal ranging from about 0.33 to about 0.95, and photographic elements containing them.
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50.发明授权Microemulsion polymerization - processes for dispersing photographically useful components 失效微乳液聚合 - 分散照相有用组分的方法
公开(公告)号：US5234807A
公开(公告)日：1993-08-10
申请号：US796107
申请日：1991-11-21
申请人： John Texter , Tienteh Chen , Edward Schofield
发明人： John Texter , Tienteh Chen , Edward Schofield
摘要： The polymerization and copolymerization of photographically useful vinyl monomers can be effected by dissolving such monomers in an isotropic oil-in-water microemulsion or in an isotropic water-in-oil microemulsion, each comprising monomers or comonomers, surfactants and/or cosurfactants, water, and optionally electrolytes. The microemulsion may be characterized as transparent or nearly transparent to the eye at 1% (w/w) or greater monomer, ultrafine in particle (droplet) size (typically in the range of 30 to 900 .ANG. in diameter), and spontaneously formed upon combining all the components with moderate stirring. The polymerization process is subsequently initiated with free radical initiators or with ultraviolet light. The components are chosen so that photographically useful polymers or photographically useful latexes are obtained, and said polymers or latexes may be coated in a photographic element.
摘要翻译： 照相用乙烯基单体的聚合和共聚可以通过将这些单体溶解在各向同性的水包油微乳液或各向同性的油包水微乳液中来实现，每种包括单体或共聚单体，表面活性剂和/或辅助表面活性剂，水， 和任选的电解质。 微乳液可以在1％（w / w）或更高的单体，特别是颗粒（液滴）尺寸的超细（通常在30至900安氏直径）范围内对眼睛透明或几乎透明，并自发形成 将所有组分合并搅拌均匀。 聚合过程随后用自由基引发剂或紫外光引发。 选择组分以便获得照相用的聚合物或照相用的胶乳，并且所述聚合物或胶乳可以涂覆在照相元件中。
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