公开(公告)号：US10253048B2

公开(公告)日：2019-04-09

申请号：US15926511

申请日：2018-03-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Dong-Xu Xue ,  Amy J. Cairns ,  Youssef Belmabkhout

IPC: C07F5/00 ,  B01J31/16 ,  C07C51/41 ,  B01J20/22

Abstract: Metal organic framework compositions can have a face centered cubic structure.

公开(公告)号：US09920076B2

公开(公告)日：2018-03-20

申请号：US14919238

申请日：2015-10-21

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Dong-Xu Xue ,  Amy J. Cairns ,  Youssef Belmabkhout

IPC: C07C29/151 ,  C07C51/41 ,  C07F5/00 ,  B01J31/16 ,  B01J20/22

CPC classification number: C07F5/00 ,  B01J20/226 ,  B01J31/1691 ,  C07C51/418

Abstract: Metal organic framework compositions can have a face centered cubic structure.

公开(公告)号：US11905246B2

公开(公告)日：2024-02-20

申请号：US17171127

申请日：2021-02-09

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

IPC: C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

CPC classification number: C07D209/88 ,  B01J20/226 ,  B01J31/1691 ,  B01J37/04 ,  B01J37/06 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  C07D317/36 ,  B01J2231/34 ,  B01J2531/0211 ,  B01J2531/36 ,  B01J2531/38 ,  B01J2531/845 ,  Y02C20/40

Abstract: A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

公开(公告)号：US11607665B2

公开(公告)日：2023-03-21

申请号：US17001286

申请日：2020-08-24

Applicant: King Abdullah University of Science and Technology

Inventor： Youssef Belmabkhout ,  Mohamed Eddaoudi ,  Dalal A. Alezi

IPC: B01J20/22 ,  B01J20/28 ,  B01J31/16 ,  C07F5/00 ,  C07F5/06 ,  C07F15/02 ,  C10L3/10

Abstract: Embodiments of the present disclose provide a method of sorbing one or more compounds from a fluid, wherein the method may include contacting a M-soc-MOF composition with a fluid containing at least H2S and one or more of CO2 and CH4; and sorbing at least H2S from the fluid. Embodiments of the present disclosure provide a membrane that may include a metal-organic framework (MOF) composition, wherein the MOF composition includes a M-soc-MOF composition, where M is a metal and soc is a square-octahedral topology, and wherein the M-soc-MOF composition is a continuous thin film on a support.

公开(公告)号：US11344870B2

公开(公告)日：2022-05-31

申请号：US17078618

申请日：2020-10-23

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC: B01J31/16 ,  B01J20/22 ,  B01D53/02

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US11066435B2

公开(公告)日：2021-07-20

申请号：US16458833

申请日：2019-07-01

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Osama Shekhah ,  Youssef Belmabkhout

IPC: C07F15/04 ,  B01J20/22 ,  B01J20/30 ,  B01J31/16 ,  B01J37/00 ,  B01J37/04 ,  C07F7/02

Abstract: A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand.

公开(公告)号：US10926242B2

公开(公告)日：2021-02-23

申请号：US16599720

申请日：2019-10-11

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/02 ,  C07C7/13 ,  B01D53/02 ,  C01B3/40 ,  C10G25/00 ,  C10L1/06 ,  C10L1/08 ,  F02B1/14 ,  F02B5/02 ,  F02B47/04 ,  F02M25/12

Abstract: Systems and methods for separating hydrocarbons on an internal combustion powered vehicle via one or more metal organic frameworks are disclosed. Systems and methods can further include utilizing separated hydrocarbons and exhaust to generate hydrogen gas for use as fuel.

公开(公告)号：US10765989B2

公开(公告)日：2020-09-08

申请号：US16280481

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Osama Shekhah

IPC: B01D53/02 ,  B01J20/28 ,  B01J20/22 ,  A61M16/22 ,  H01M8/0668

Abstract: Embodiments of the present disclosure describe a device for removing CO2 comprising a gas flow inlet, a housing including a SIFSIX-3-Cu metal-organic framework (MOF) composition for sorbing and/or desorbing CO2, and a gas flow outlet. Embodiments of the present disclosure describe an anesthetic system comprising one or more regeneratable cartridges for sorbing and/or desorbing CO2, wherein each of the one or more regeneratable cartridge includes a metal-organic framework composition, wherein at least one of the regeneratable cartridges includes a SIFSIX-3-Cu MOF. Embodiments of the present disclosure describe an alkaline fuel cell comprising a catalyst layer including a SIFSIX-3-Cu MOF composition for sorbing and/or desorbing CO2.

公开(公告)号：US10744482B2

公开(公告)日：2020-08-18

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10703767B2

公开(公告)日：2020-07-07

申请号：US16280504

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Dong-Xu Xue ,  Amy J. Cairns ,  Youssef Belmabkhout

IPC: C07F5/00 ,  B01J31/16 ,  C07C51/41 ,  B01J20/22

Abstract: Embodiments of the present disclosure describe compositions comprising a molecular building block (MBB) having the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion. Embodiments of the present disclosure further describe methods of making a metal-organic framework (MOF) composition comprising contacting one or more molecular building blocks (MBBs) with one or more bidentate ligands, wherein the MBBs have the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion.