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50 条记录 (耗时 0.046 秒)

    Preparation of silicon-functional polyorganosiloxanes
    42.
    发明授权
    Preparation of silicon-functional polyorganosiloxanes 失效
    硅官能聚有机硅氧烷的制备

    公开(公告)号：US4177201A

    公开(公告)日：1979-12-04

    申请号：US974412

    申请日：1978-12-29

    申请人： Armand de Montigny ,  Hans-Heinrich Moretto

    发明人： Armand de Montigny ,  Hans-Heinrich Moretto

    IPC分类号： C08G77/00 ,  C08G77/06 ,  C08G77/08 ,  C08G77/10 ,  C08G77/14 ,  C08G77/22 ,  C08G77/42 ,  C07F7/08

    CPC分类号： C08G77/10 ,  C08G77/14

    摘要： A process for the preparation of an equilibrated acyloxy-containing organopolysiloxane comprising reacting at a temperature of up to 135.degree. C. a chlorosilane of the formulaR.sub.a R'.sub.b SiCl.sub.(4-a-b)whereina=0, 1, 2 or 3b=0, 1, 2 or 3, anda+b is at most 3,or a partial hydrolysis product thereof, with at least one organosiloxane containing the units[R.sub.2 R"--SiO.sub.178 ] [RR"--SiO] [R"--SiO.sub.3/2 ] [SiO.sub.2 ]whereinR and R' each independently is hydrogen or an optionally halogen or cyano-substituted monovalent hydrocarbon radical with up to 18 C atoms, andR" is hydrogen, chlorine, hydroxyl, or an optionally halogen or cyano-substituted monovalent hydrocarbon radical with up to 18 C atoms,in the presence of a proton acid siloxane-equilibration catalyst, and at least about 1.1 times the molar amount of a monobasic carboxylic acid based on the silicon-bonded chlorine atom, the number of all the Si--Cl groups in the reactants exceeding the number of all the Si--OH groups.

    摘要翻译： 一种用于制备平衡的含酰氧基的有机聚硅氧烷的方法，包括在高达135℃的温度下反应式为RaR'bSiCl（4-ab）的氯硅烷，其中a = 0,1,2或3b = 0 至少一个含有[R2R“ - SiO178] [RR” - SiO] [R“ - ]的单体的有机硅氧烷，其中a + b为3以下，或其部分水解产物， SiO 3/2] [SiO 2]其中R和R'各自独立地是氢或具有至多18个C原子的任选的卤素或氰基取代的一价烃基，R“是氢，氯，羟基或任选的卤素或 具有至多18个C原子的氰基取代的一价烃基，在质子酸硅氧烷平衡催化剂的存在下，和基于硅键合的氯原子的一元羧酸的摩尔量的至少约1.1倍， 的反应物中的所有Si-Cl基团超过所有Si-OH基团的数目。

    Flame-repellent polysiloxane molding compositions
    43.
    发明授权
    Flame-repellent polysiloxane molding compositions 失效
    阻燃聚硅氧烷成型组合物

    公开(公告)号：US4419474A

    公开(公告)日：1983-12-06

    申请号：US313112

    申请日：1981-10-20

    申请人： Jurgen Ackermann ,  Hans-Heinrich Moretto ,  Wilfried Kniege ,  Werner Rauer

    发明人： Jurgen Ackermann ,  Hans-Heinrich Moretto ,  Wilfried Kniege ,  Werner Rauer

    IPC分类号： C08K3/22 ,  C08K3/36 ,  C08K5/16 ,  C08K5/21 ,  C08K13/02 ,  C08L83/00 ,  C08L83/04 ,  C08L83/06

    CPC分类号： C08K13/02

    摘要： In a polysiloxane molding composition which can be cured to give flame-repellent products, comprising(a) a diorganopolysiloxane of the formula ##EQU1## in which n is 1.9 to 2.05, andR.sup.1 is an alkyl, alkenyl and/or or aryl radical with 1-8 C-atoms,(b) finely divided TiO.sub.2 with a surface area, measured by the BET method, greater than 20 m.sup.2 /g and a particle size less than 0.5 .mu.m,(d) platinum and/or one of its sulphur-free compounds, and(e) a curing agent,the improvement which comprises about 0.05 to 10% by weight of (a) to (e) of nitrogen compound of the formula ##STR1## in which R is H, phenyl, alkyl with 1-6 C-atoms, tolyl, nitrile, --NHR.sup.2, --CH.sub.2 OR.sup.2, --CH.sub.2 COOR.sup.2, --C(.dbd.NH)NHR.sup.2, --CO--NH--R.sup.2 or (R.sup.1).sub.2 C--,R.sub.2.sup.1 is H, alkyl with 1-6 C-atoms, Si(CH.sub.3).sub.3 -- or R,R.sup.2 is H or --CO--R, andZ is NH, O or NR,or a salt thereof. Articles molded therefrom and then cured are of enhanced flame-repellency.

    摘要翻译： 在可以固化得到阻燃产品的聚硅氧烷模塑组合物中，其包含（a）式“IMAGE”的二有机聚硅氧烷，其中n为1.9至2.05，并且R 1为烷基，烯基和/或或芳基， 1-8个碳原子，（b）通过BET法测量的具有大于20m 2 / g和小于0的粒度的表面积的细碎TiO 2。

    Organopolysiloxane-urethane-vinyl graft copolymers
    46.
    发明授权
    Organopolysiloxane-urethane-vinyl graft copolymers 失效
    有机聚硅氧烷 - 氨基甲酸酯 - 乙烯基接枝共聚物

    公开(公告)号：US4336358A

    公开(公告)日：1982-06-22

    申请号：US207093

    申请日：1980-11-14

    申请人： Heinrich Alberts ,  Hans Friemann ,  Hans Sattlegger ,  Hans-Heinrich Moretto

    发明人： Heinrich Alberts ,  Hans Friemann ,  Hans Sattlegger ,  Hans-Heinrich Moretto

    IPC分类号： C08L51/08 ,  C08F281/00 ,  C08F283/00 ,  C08F283/12 ,  C08F289/00 ,  C08L51/00 ,  C08L51/02 ,  C08L83/04 ,  C08F283/02

    CPC分类号： C08F283/00

    摘要： A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyester-urethane and, (III) units of vinyl monomers, units of the first and second polymeric moieties being linked via vinyl polymer bridges, all these units having been polymerized in the presence of mixtures of the first and second polymeric moieties, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.

    摘要翻译： 一种接枝共聚物，其包含作为第一聚合物部分的具有OH官能团的有机聚硅氧烷，（II）作为第二聚合物部分的聚酯 - 氨基甲酸酯和（III）乙烯基单体单元，所述第一和第二聚合物部分的单元为 通过乙烯基聚合物桥连接，所有这些在第一和第二聚合物部分的混合物存在下聚合的单元通过聚合合适的单体分散体来制备。 该产品适用于替换含有机聚硅氧烷，硅烷交联剂和固化催化剂的室温可固化组合物中的全部或一些有机聚硅氧烷组分。

    Conversion of low-boiling constituents from alkyl-chlorosilane synthesis
    47.
    发明授权
    Conversion of low-boiling constituents from alkyl-chlorosilane synthesis 失效
    低沸点成分从烷基氯硅烷合成转化

    公开(公告)号：US4297500A

    公开(公告)日：1981-10-27

    申请号：US209932

    申请日：1980-11-24

    申请人： Ulrich Finke ,  Hans-Heinrich Moretto

    发明人： Ulrich Finke ,  Hans-Heinrich Moretto

    IPC分类号： C07F7/12 ,  C07F7/08

    CPC分类号： C07F7/123 ,  C07F7/122

    摘要： A process for converting the low-boiling constituents formed in the preparation of methylchlorosilane to the Muller-Rochow process and which consist essentially of tetramethylsilane, dimethylmonochlorosilane and 2-methylbut-2-ene into a product mixture consisting essentially of trimethylchlorosilane, dimethylchlorosilane and C.sub.2 -.sub.20 alkyldimethylchlorosilanes or C.sub.6-10 -aryldimethylchlorosilanes, comprising contacting the low-boiling product mixture with AlCl.sub.3, AlOCl and/or AlBr.sub.3, together with hydrogen chloride, in the liquid phase at about 40.degree. to +25.degree. C. The mixture prior to conversion may be contacted with HCl and either ZnCl.sub.2 or active charcoal and/or an olefin may be added thereto.

    摘要翻译： 将在甲基氯硅烷制备中形成的低沸点组分转化为Müller-Rochow工艺的方法，其基本上由四甲基硅烷，二甲基一氯甲硅烷和2-甲基丁-2-烯组成基本上由三甲基氯硅烷，二甲基氯硅烷和C2- 20烷基二甲基氯硅烷或C6-10-芳基二甲基氯硅烷，其包括在约40℃至+ 25℃下将液体相中的低沸点产物混合物与AlCl 3，AlOCl和/或AlBr 3一起与氯化氢接触。转化前的混合物 可以与HCl接触，并且可以向其中加入ZnCl 2或活性炭和/或烯烃。

    Addition of dialkylhalogeno-hydridosilanes to unsaturated hydrocarbon compounds
    48.
    发明授权
    Addition of dialkylhalogeno-hydridosilanes to unsaturated hydrocarbon compounds 失效
    向不饱和烃化合物中加入二烷基卤代羟基硅烷

    公开(公告)号：US4254271A

    公开(公告)日：1981-03-03

    申请号：US2930

    申请日：1979-01-12

    申请人： Ulrich Finke ,  Hans-Heinrich Moretto

    发明人： Ulrich Finke ,  Hans-Heinrich Moretto

    IPC分类号： C07F7/14 ,  C07F7/08

    CPC分类号： C07F7/14

    摘要： In the addition of an unsaturated compound into a silane of the formulaR.sub.1 R.sub.2 SiXHwhereinX is Cl or Br, andR.sub.1 and R.sub.2 each independently is an alkyl, aryl or aralkyl radical with up to 20 C atoms, or an alkenyl or alkinyl radical with up to 12 C atoms,the improvement which comprises effecting the addition reaction in the presence of at least one of aluminum chloride, aluminum bromide, aluminum oxychloride and aluminum oxybromide.

    摘要翻译： 在将不饱和化合物加入式R 1 R 2 SiXH的硅烷中，其中X是Cl或Br，并且R 1和R 2各自独立地是具有至多20个C原子的烷基，芳基或芳烷基，或具有上述的链烯基或炔基 至12 C原子，其改进包括在氯化铝，溴化铝，氯氧化铝和氧化铝铝中的至少一种的存在下进行加成反应。

    Preparation of catalytic copper and production of organochlorosilane using said copper
    49.
    发明授权
    Preparation of catalytic copper and production of organochlorosilane using said copper 失效
    使用所述铜制备催化铜和生产有机氯硅烷

    公开(公告)号：US4218387A

    公开(公告)日：1980-08-19

    申请号：US953047

    申请日：1978-10-19

    申请人： Joachim Maas ,  Rudolf Mundil ,  Bruno Degen ,  Hans-Heinrich Moretto

    发明人： Joachim Maas ,  Rudolf Mundil ,  Bruno Degen ,  Hans-Heinrich Moretto

    IPC分类号： B01J23/72 ,  B01J37/12 ,  C07B61/00 ,  C07F7/14 ,  C07F7/16

    CPC分类号： C07F7/16 ,  B01J23/72 ,  B01J37/12

    摘要： In the preparation of catalytic copper with an average particle size between about 0.1 and 100 microns and a copper-I oxide content of about 3 to 100% by oxidation of a Cu powder, the improvement which comprises carrying out the oxidation with oxygen at a reduced partial pressure compared with that of air, the resulting catalyst being of enhanced catalytic activity especially for the reaction of hydrocarbon chlorides with silicon for the production of organochlorosilanes (Rochow synthesis) wherein the desired material is produced in higher yield and greater selectivity.

    摘要翻译： 在通过Cu粉末的氧化制备平均粒径为约0.1至100微米的催化铜和约3至100％的铜-I氧化物含量的改进之处在于包括以减少的氧进行氧化 与空气相比，所得催化剂具有增强的催化活性，特别是用于烃氯化物与硅的反应用于生产有机氯硅烷（Rochow合成），其中所需材料以更高的产率和更高的选择性产生。

    Silyl esters of perfluoroalkanesulphonic acid esters and a process for their preparation
    50.
    发明授权
    Silyl esters of perfluoroalkanesulphonic acid esters and a process for their preparation 失效
    全氟烷基磺酸酯的甲硅烷基酯及其制备方法

    公开(公告)号：US4203914A

    公开(公告)日：1980-05-20

    申请号：US2112

    申请日：1979-01-08

    申请人： Ulrich Finke ,  Hans-Heinrich Moretto ,  Hans Niederprum ,  Helmut Vorbruggen

    发明人： Ulrich Finke ,  Hans-Heinrich Moretto ,  Hans Niederprum ,  Helmut Vorbruggen

    IPC分类号： C07F7/08

    CPC分类号： C07F7/0836

    摘要： A process for the preparation of a perfluoroalkanesulphonic acid ester of the formulaC.sub.n F.sub.2n+1 SO.sub.3 Si R.sup.1 R.sup.2 R.sup.3comprising reacting a silane of the formulaR.sup.1 R.sup.2 R.sup.3 R.sup.4 Siwith a perfluoroalkanesulphonic acid of the formulaC.sub.n F.sub.2n+1 SO.sub.3 HwhereinR.sup.1, R.sup.2 and R.sup.3 each independently is alkyl with 1 to 6 carbon atoms,R.sup.4 is methyl, andn is from 1 to 12.Compounds wherein the total number of carbon atoms in Cn, R.sup.1, R.sup.2 and R.sup.3 is at least 6 are new and especially useful as silylating agents in organic cyntheses.

    摘要翻译： 一种制备式C n F 2n + 1 SO 3 Si R 1 R 2 R 3的全氟烷基磺酸酯的方法，包括使式R 1 R 2 R 3 R 4 Si的硅烷与式C n F 2n + 1 SO 3 H的全氟烷基磺酸反应，其中R 1，R 2和R 3各自独立地为具有1至6个碳原子的烷基 原子，R 4为甲基，n为1至12. Cn，R 1，R 2和R 3中的碳原子总数至少为6的化合物是新的，并且特别用作有机核苷酸中的甲硅烷化剂。