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公开(公告)号：US4412039A
公开(公告)日：1983-10-25
申请号：US284295
申请日：1981-07-17
IPC分类号： C08F291/00 , C08F255/02 , C08F283/12 , C08L83/10
CPC分类号： C08F283/122 , C08F255/026
摘要： A co-grafted polymer dispersion comprising blocks of an organopolysiloxane with OH functional groups, blocks of an ethylene/vinyl ester copolymer containing about 5 to 99% by weight of incorporated vinyl ester, and blocks of vinyl monomer units polymerized in the presence of mixtures of the organopolysiloxane and ethylene/vinyl ester copolymer, the organopolysiloxane and ethylene/vinyl ester copolymer blocks being linked via vinyl polymer bridges. The dispersions mixed with suitable catalysts, can cure under the influence of atmospheric moisture to elastic tack-free rubbers suitable as sealants.
摘要翻译： 包含具有OH官能团的有机聚硅氧烷嵌段的共接枝聚合物分散体，含有约5至99重量％的所加入的乙烯基酯的乙烯/乙烯基酯共聚物嵌段和在下列混合物存在下聚合的乙烯基单体单元嵌段 有机聚硅氧烷和乙烯/乙烯基酯共聚物，有机聚硅氧烷和乙烯/乙烯基酯共聚物嵌段通过乙烯基聚合物桥连接。 与合适的催化剂混合的分散体可以在大气湿度的影响下固化成适合作为密封剂的弹性无粘性橡胶。
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公开(公告)号：US4368290A
公开(公告)日：1983-01-11
申请号：US207043
申请日：1980-11-14
IPC分类号： C08L51/08 , C08F281/00 , C08F283/00 , C08F283/06 , C08F283/12 , C08F289/00 , C08L51/00 , C08L51/02 , C08L83/04 , C08L83/10
CPC分类号： C08F283/122 , C08F283/06
摘要： A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyether, and (III) units of vinyl monomer which have been polymerized in the presence of mixtures of the first and second polymeric moieties which moieties are linked via vinyl polymer bridges, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.
摘要翻译： 一种接枝共聚物，其包含作为第一聚合物部分的（I）具有OH官能团的有机聚硅氧烷，（II）作为第二聚合物部分的聚醚，和（III）乙烯基单体的单元，其在第一聚合物部分的混合物存在下聚合 和通过乙烯基聚合物桥连接部分的第二聚合物部分通过聚合合适的单体分散体而制备。 该产品适用于替换含有机聚硅氧烷，硅烷交联剂和固化催化剂的室温可固化组合物中的全部或一些有机聚硅氧烷组分。
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公开(公告)号：US4444946A
公开(公告)日：1984-04-24
申请号：US344083
申请日：1982-01-29
IPC分类号： C08F283/00 , C08F283/12 , C08F291/00 , C08G18/40 , C08G18/61 , C08G18/63 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/08 , C08L67/00 , C08L77/00 , C08L83/00 , C08L83/04 , C08L83/10 , C08L101/00 , C08L83/06
CPC分类号： C08L51/085 , C08G18/4072 , C08G18/61 , C08G18/63 , C08L83/04 , C08L83/10 , C08G77/16 , C08G77/20
摘要： The invention relates to special stable dispersions which crosslink at room temperature upon exposure to moisture in the atmosphere. The dispersions comprise polysiloxanes, vinyl-grafted polysiloxanes and condensation products, e.g. by weight approximately comprisingI. 20-90% of at least one diorganopolysiloxane optionally terminated by OH,II. 5-85% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C. and/or a vinyl monomer-grafted derivative thereof, andIII. 5-85% of at least one organopolysiloxane modified by grafting with at least one vinyl monomer and comprising(A) 10-90% of a diorganopolysiloxane optionally terminated by OH,(B) 10-90% of polymerized units of at least one vinyl compound, and(C) 0-80% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C.
摘要翻译： 本发明涉及在暴露于大气中的水分时在室温下交联的特殊的稳定分散体。 分散体包括聚硅氧烷，乙烯基接枝的聚硅氧烷和缩合产物，例如 约20-90％的至少一种二羟基硅氧烷，任选被OH，II终止。 5-85％至少一种脂族或混合的脂族/芳族缩聚产物或加聚产物，玻璃温度TG高达40℃的聚醚或乙烯基聚合物和/或其乙烯基单体接枝衍生物和III 。 通过与至少一种乙烯基单体接枝改性的至少一种有机聚硅氧烷的5-85％，并且包含（A）10-90％的任选被OH封端的二有机聚硅氧烷，（B）10-90％的至少一种乙烯基的聚合单元 化合物，和（C）0-80％的至少一种脂族或混合的脂族/芳族缩聚产物或加聚产物，聚醚或乙烯基聚合物，玻璃温度TG高达40℃。
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公开(公告)号：US4376185A
公开(公告)日：1983-03-08
申请号：US207033
申请日：1980-11-14
IPC分类号： C08F283/00 , C08F281/00 , C08F283/12 , C08F289/00 , C08G77/442 , C08G77/445 , C08L51/08 , C08L83/04 , C08L83/10 , C08L67/02 , C08L83/06
CPC分类号： C08F283/122 , C08F283/124 , C08G77/442 , C08G77/445 , C08L51/085 , C08L83/10
摘要： A co-grafted polymer comprising units of organopolysiloxanes with OH functional groups, polyesters and vinyl monomers, polymeric units of the vinyl monomers being linked to the organopolysiloxane and polyester units, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.
摘要翻译： 包含具有OH官能团的有机聚硅氧烷单元，聚酯和乙烯基单体的共接枝聚合物，通过聚合合适的单体分散体制备的乙烯基单体的聚合单元与有机聚硅氧烷和聚酯单元连接。 该产品适用于替换含有机聚硅氧烷，硅烷交联剂和固化催化剂的室温可固化组合物中的全部或一些有机聚硅氧烷组分。
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公开(公告)号：US4336358A
公开(公告)日：1982-06-22
申请号：US207093
申请日：1980-11-14
IPC分类号： C08L51/08 , C08F281/00 , C08F283/00 , C08F283/12 , C08F289/00 , C08L51/00 , C08L51/02 , C08L83/04 , C08F283/02
CPC分类号： C08F283/00
摘要： A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyester-urethane and, (III) units of vinyl monomers, units of the first and second polymeric moieties being linked via vinyl polymer bridges, all these units having been polymerized in the presence of mixtures of the first and second polymeric moieties, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.
摘要翻译： 一种接枝共聚物，其包含作为第一聚合物部分的具有OH官能团的有机聚硅氧烷，（II）作为第二聚合物部分的聚酯 - 氨基甲酸酯和（III）乙烯基单体单元，所述第一和第二聚合物部分的单元为 通过乙烯基聚合物桥连接，所有这些在第一和第二聚合物部分的混合物存在下聚合的单元通过聚合合适的单体分散体来制备。 该产品适用于替换含有机聚硅氧烷，硅烷交联剂和固化催化剂的室温可固化组合物中的全部或一些有机聚硅氧烷组分。
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公开(公告)号：US4366286A
公开(公告)日：1982-12-28
申请号：US204680
申请日：1980-11-05
IPC分类号： C09J7/02 , C08F283/00 , C08L51/00 , C08L51/02 , C08L83/00 , C08L83/04 , C09D183/04 , D21H19/32 , C08L51/08
CPC分类号： D21H19/32 , C08L83/04 , C08G77/16 , C08G77/20 , C08G77/26 , C08G77/42 , C08G77/46 , C08G77/70
摘要： In a sheet coated on both surfaces with non-stick coatings, one of the coatings being more non-stick than the other, the improvement which comprises employing as the lesser non-stick coating a composition according to claim 1 by weight consisting essentially of(A) about 10 parts of a polyorganosiloxane with hydroxyl end groups and with a viscosity of 10.sup.2 to 5.10.sup.4 Pas,(B) 0.5-5 parts of at least one cross-linking agent of the formulaRSiX.sub.3whereinX is a hydrolyzable group andR is an alkyl, alkenyl, aryl or aminoalkyl group with 1-12 C atoms,(C) 0.1-2 parts of an organic tin compound as the catalyst and(D) 100-500 parts by weight of an organic solvent, the improvement which comprises additionally including, and(E) 0.1-20 parts of a graft copolymer comprising(i) 25-75% of an essentially linear polyorganosiloxane with hydroxyl end groups and with a viscosity of 100 to 500,000 mPas and(ii) 10-70% of at least one organic polymer with a molecular weight of 500 to 100,000, linked to (i) via bridges formed on polymerization of(iii) 10-60% of one or more monomers containing at least one aliphatic double bond.
摘要翻译： 在涂覆有具有不粘涂层的两个表面上的片材中，一个涂层比另一个涂层更粘不粘，其改进包括使用根据权利要求1所述的组合物作为较小不粘涂层，该组合物基本上由（ A）约10份具有羟基端基的聚有机硅氧烷，粘度为102〜5.104Pa·s，（B）0.5-5份至少一种式RSiX 3的交联剂，其中X为可水解基团，R为 具有1-12个碳原子的烷基，烯基，芳基或氨基烷基，（C）0.1-2份作为催化剂的有机锡化合物和（D）100-500重量份的有机溶剂，其改进包括 另外包括和（E）0.1-20份的接枝共聚物，其包括（i）25-75％的具有羟基端基的基本上线性的聚有机硅氧烷和粘度为100-500,000mPas，和（ii）10-70％ 至少一种分子量为500至100,000的有机聚合物，与（ i）通过在（iii）10-60％的一种或多种含有至少一个脂族双键的单体的聚合上形成的桥。
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7.发明授权Combinations of polyorganosiloxanes and fluororubbers containing double bonds by Si-H addition 失效通过Si-H添加，含有双键的聚有机硅氧烷和氟橡胶的组合
公开(公告)号：US5554689A
公开(公告)日：1996-09-10
申请号：US344780
申请日：1994-11-23
CPC分类号： C08G77/442 , C08F8/42 , C08L27/12
摘要： A chemically linkable mixture comprising(a) about 98 to 80% by weight of a fluoroelastomer bearing lateral olefinic double bonds,(b) about 2 to 20% by weight of at least one of a silicone oligomer, silicone elastomer and a fluorosilicone elastomer containing Si--H groups, and(c) a catalyst containing at least one of a noble metal and an organic peroxide.Fluororubbers made therefrom are distinguished by excellent physical properties.
摘要翻译： 一种可化学连接的混合物，其包含（a）约98至80重量％的带有侧面烯属双键的含氟弹性体，（b）约2至20重量％的至少一种硅氧烷低聚物，硅氧烷弹性体和含氟硅氧烷弹性体， Si-H基，和（c）含有贵金属和有机过氧化物中的至少一种的催化剂。 由其制备的氟橡胶的特征在于优异的物理性能。
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8.发明授权公开(公告)号：US06716916B1
公开(公告)日：2004-04-06
申请号：US10069862
申请日：2002-04-15
IPC分类号： C08F27900
CPC分类号： C08L51/04 , C08F279/04 , C08L25/12 , C08L55/02 , C08L67/02 , C08L69/00 , C08L69/005 , C08L77/00 , C08L2666/14 , C08L2666/24 , C08L2666/02 , C08L51/00
摘要： A molding composition containing a graft polymer is disclosed. The graft is a product of a free-radical emulsion polymerization of resin-forming vinyl monomers in the presence of rubber present in latex form having a glass transition temperature of ≦0° C. using an initiator combination comprising a persulfate compound and a redox initiator system. The process for preparing the graft polymer entails adding the persulfate compound at the beginning of the graft polymerization reaction and a later addition of the redox initiator. The composition that features good gloss and flowability is suitable for the preparation of molded articles.
摘要翻译： 公开了含有接枝聚合物的模塑组合物。 接枝物是在玻璃化转变温度为<= 0℃的胶乳形式的橡胶存在下，使用包含过硫酸盐化合物和氧化还原反应的引发剂组合的树脂形成乙烯基单体的自由基乳液聚合的产物 启动器系统。 制备接枝聚合物的方法需要在接枝聚合反应开始时加入过硫酸盐化合物，并且随后加入氧化还原引发剂。 具有良好光泽度和流动性的组合物适用于制备模制品。
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9.发明授权Thermoplastic molding compounds, provided with an antistatic agent which exhibit improved color stability during processing 失效具有抗静电剂的热塑性模塑料，其在加工过程中表现出改善的颜色稳定性公开(公告)号：US06639005B1
公开(公告)日：2003-10-28
申请号：US09958871
申请日：2001-10-12
IPC分类号： C08L3700
CPC分类号： C08L51/04 , C08K5/13 , C08K5/17 , C08K5/375 , C08L71/02 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic molding composition that exhibits antistatic properties and improved color stability is disclosed. The composition contains a major amount of resinous component that contains A) 0 to 100 % by weight of one or more graft polymers B) 100 to 0 % by weight of a thermoplastic vinyl (co)polymer, and a minor amount of a mixture of a) a modified or unmodified polyalkylene ethers and b) a phenolic oxidant wherein the weight ratio (a):(b) is 20:1 to 1:1.
摘要翻译： 公开了一种具有抗静电性和改善的颜色稳定性的热塑性模塑组合物。 该组合物含有主要量的含有A）0至100重量％的一种或多种接枝聚合物的树脂组分B）100至0重量％的热塑性乙烯基（共）聚合物和少量的 a）改性或未改性的聚亚烷基醚和b）酚类氧化剂，其中重量比（a）：（b）为20:1至1:1。
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公开(公告)号：US6057394A
公开(公告)日：2000-05-02
申请号：US754995
申请日：1996-11-22
申请人： Michael Bodiger , Herbert Eichenauer , Heinrich Alberts , Dieter Wittmann , Thomas Eckel , Peter Kruger
发明人： Michael Bodiger , Herbert Eichenauer , Heinrich Alberts , Dieter Wittmann , Thomas Eckel , Peter Kruger
CPC分类号： C08K3/0008 , C08L51/04
摘要： Thermoplastic moulding compositions containingA. a thermoplastic polymer andB. 0.1 to 50% by weight, with respect to A, of an inorganic substance with an average particle diameter of 0.1 to 100 nm,and the use of superfine inorganic substances as defined by B for increasing the X-ray contrast of thermoplastic moulding compositions comprising A and B.
摘要翻译： 含有A.热塑性聚合物的热塑性成型组合物和B.相对于A为0.1〜50重量％的平均粒径为0.1〜100nm的无机物质，以及由B定义的超细无机物质 用于增加包含A和B的热塑性模塑组合物的X射线对比度。
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