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公开(公告)号：US4977236A
公开(公告)日：1990-12-11
申请号：US449289
申请日：1989-12-05
Applicant: David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence , Mark Rule
Inventor： David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence , Mark Rule
CPC classification number: C08G75/0227 , C08G75/0231 , C08G75/0263 , C08G75/0268
Abstract: A process for preparation of a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein A is a divalent substituted or unsubstituted aromatic radical, T is a monovalent aromatic radical, x is in the range of 0.5 to 0.001 and n is an integer from 1 to 100.
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42.发明授权
公开(公告)号：US4977224A
公开(公告)日：1990-12-11
申请号：US437701
申请日：1989-11-17
Applicant: Joseph J. Watkins , David R. Fagerburg , Paul B. Lawrence , Mark Rule
Inventor： Joseph J. Watkins , David R. Fagerburg , Paul B. Lawrence , Mark Rule
CPC classification number: C08G75/029 , C08G75/0263 , C08G75/14
Abstract: A process for preparation of a copoly(arylene sulfide) which has a decreased amount of disulfide radicals and corresponds to the structure ##STR1## wherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.45 to 0 and n is at least 50,comprising contacting a copoly(arylene sulfide) corresponding to the structure ##STR2## wherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.50 to 0.001 and n is at least 25,in the melt phase with a diiodoaromatic compound corresponding to the structureI-A-IwhereinA is a divalent substituted or unsubstituted aromatic radical.
Abstract translation: 一种制备二硫键数量少并且对应于[（-AS-）1-x（-ASS-）x] n结构的共聚（亚芳基硫醚）的方法，其中A是二价取代或未取代的芳族 基团，x在0.45至0的范围内，n至少为50，其中包括使对应于[（-AS-）1-x（-ASS-）x] n结构的共聚（亚芳基硫醚） 二价取代或未取代的芳族基团，x在0.50至0.001的范围内且n至少为25，在熔融相中与对应于其中A是二价取代或未取代的芳族基团的结构IAI的二碘代芳族化合物相结合。
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公开(公告)号：US4939236A
公开(公告)日：1990-07-03
申请号：US404811
申请日：1989-09-08
Applicant: David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence , Mark Rule
Inventor： David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence , Mark Rule
CPC classification number: C08G75/0263
Abstract: A process for preparing a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sbsb.nwherein x is in the range of 0.5 to 0.001 by reacting a mixture of a diiodoaromatic compound and elemental sulfur which contains less than 0.05 weight percent carbon.
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公开(公告)号：US4935559A
公开(公告)日：1990-06-19
申请号：US303347
申请日：1989-01-30
Applicant: Mark Rule , Eric J. Fugate
Inventor： Mark Rule , Eric J. Fugate
CPC classification number: C07C2/861 , C07C17/16 , C07C2531/04
Abstract: A method of preparing an aryl alkene compound comprising reacting an iodoaromatic compound an alkene and an alkanol in the presence of a palladium catalyst and the absence of a Bronsted base.
Abstract translation: 一种制备芳基烯烃化合物的方法，包括在钯催化剂存在下和不存在Bronsted碱的情况下使碘芳香族化合物与烯烃和链烷醇反应。
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45.发明授权
公开(公告)号：US4866200A
公开(公告)日：1989-09-12
申请号：US228779
申请日：1988-08-04
Applicant: Mark Rule , Thomas H. Larkins, Jr. , Donald W. Lane , Guy R. Steinmetz
Inventor： Mark Rule , Thomas H. Larkins, Jr. , Donald W. Lane , Guy R. Steinmetz
Abstract: Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an alkanol and a palladium catalyst.
Abstract translation: 公开了通过芳族碘化物在烷醇和钯催化剂存在下羰基化来共同生产芳族羧酸酯和烷基碘化物的方法。
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Patent Agency Ranking
公开(公告)号：US4863710A
公开(公告)日：1989-09-05
申请号：US220844
申请日：1988-07-15
Applicant: Mark Rule , Victor H. Agreda
Inventor： Mark Rule , Victor H. Agreda
IPC: C01B7/14 , C07C29/124 , C07C31/02
CPC classification number: C07C29/124 , C01B7/14
Abstract: A process comprising preparation of an alkanol and elemental iodine by contacting an iodoalkane containing 1 to 20 carbons, water and molecular oxygen at a temperature in the range of about 50.degree. to about 200.degree. C. and recovering the elemental iodine.
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47.发明授权Process for the preparation of copoly(arylene sulfide) with aromatic nitro compound catalyst 失效用芳族硝基化合物催化剂制备共聚（亚芳基硫醚）的方法
公开(公告)号：US4792600A
公开(公告)日：1988-12-20
申请号：US118572
申请日：1987-11-09
Applicant: Mark Rule , David R. Fagerburg , Joseph J. Watkins
Inventor： Mark Rule , David R. Fagerburg , Joseph J. Watkins
CPC classification number: C08G75/14 , C08G75/0222 , C08G75/0263
Abstract: A process for preparing a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein x is in the range of 0.5 to 0.001 by reacting a mixture of a diiodoaromatic compound and elemental sulfur in the presence of a catalytic amount of an aromatic nitro compound.
Abstract translation: 制备对应于[（-AS-）1-x（-ASS-）x] n结构的共聚（亚芳基硫醚）的方法，其中x为0.5至0.001的范围内，通过使二碘代芳族化合物和 在催化量的芳族硝基化合物的存在下加入元素硫。
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48.发明授权
公开(公告)号：US4778917A
公开(公告)日：1988-10-18
申请号：US115294
申请日：1987-11-02
Applicant: Guy R. Steinmetz , Mark Rule , Victor H. Agreda , Lanney C. Treece
Inventor： Guy R. Steinmetz , Mark Rule , Victor H. Agreda , Lanney C. Treece
IPC: B01J27/13 , B01J31/22 , B01J31/24 , C07B61/00 , C07C17/093 , C07C17/16 , C07C17/18 , C07C19/07 , C07C67/00 , C07C67/36 , C07C69/76 , C07C17/00
CPC classification number: C07C17/093
Abstract: Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an ether and a ruthunium catalyst.
Abstract translation: 公开了通过在醚和钍催化剂存在下芳族碘化物的羰基化来共同生产芳族羧酸酯和烷基碘化物的方法。
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公开(公告)号：US08790543B2
公开(公告)日：2014-07-29
申请号：US13263820
申请日：2010-04-08
Applicant: Adrian John Carmichael , Andrew Stuart Overend , Mark Rule , Ronald James Valus , James Stuart Leeming
Inventor： Adrian John Carmichael , Andrew Stuart Overend , Mark Rule , Ronald James Valus , Christine Leeming
CPC classification number: C01B3/065 , A23L2/42 , A23L3/3436 , A23V2002/00 , C08K3/12 , Y02E60/362 , Y02E60/364 , A23V2200/10 , A23V2250/12
Abstract: A closure (40) for a container incorporates calcium hydride and a matrix material as a hydrogen-generating composition. In use, hydrogen is generated which reacts with oxygen permeating a container associated with the closure and a catalyst associated with the container catalyses reaction of the hydrogen and oxygen to produce water, thereby scavenging the oxygen. The composition of calcium hydride and matrix is also claimed.
Abstract translation: 用于容器的封闭件（40）包含氢化钙和作为产氢组合物的基质材料。 在使用中，产生氢气，其与渗透与封闭件相关联的容器的氧气反应，并且与容器相关联的催化剂催化氢气和氧气的反应以产生水，从而清除氧气。 还要求氢化钙和基质的组成。
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公开(公告)号：US08221533B2
公开(公告)日：2012-07-17
申请号：US13177035
申请日：2011-07-06
Applicant: Mark Rule , Harry Harshaw
Inventor： Mark Rule , Harry Harshaw
IPC: C04B41/46 , C04B41/47 , C04B103/65 , C09D5/00 , C09K3/18
CPC classification number: C04B41/46 , C04B2111/27 , C04B41/502 , C04B2103/0094
Abstract: A method to render stone, ceramic, or cementitious structures water repellent is disclosed. The method includes the step of contacting the stone, ceramic, or cementitious structures with an alkylphosphonic acid. The alkylphosphonic acid can be dispersed in an aqueous medium and can be at least partially neutralized with ammonia, an amine, or a basic alkali salt.
Abstract translation: 公开了一种提供石材，陶瓷或水泥结构防水剂的方法。 该方法包括使石头，陶瓷或水泥结构与烷基膦酸接触的步骤。 烷基膦酸可以分散在水性介质中，并且可以用氨，胺或碱性碱盐至少部分中和。
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