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公开(公告)号：US5280074A
公开(公告)日：1994-01-18
申请号：US960248
申请日：1992-10-13
IPC分类号： C08F210/06 , C08F297/08 , C08L23/08 , C08L23/10 , C08L23/16 , C08L53/00 , C08L23/06
CPC分类号： C08F210/06 , C08F297/083 , C08L23/10 , C08L53/00 , C08L23/0815 , C08L23/16 , C08L2308/00 , C08L2314/06 , Y02P20/52 , Y10S526/943
摘要： A propylene block copolymer having good flow properties and a very good low temperature impact strength is obtained in a high yield if a catalyst which consists of a chiral metallocene, containing a bridge, of the formula I ##STR1## and an aluminoxane is used for the polymerization of propylene and the comonomers.The polymerization is carried out in two stages, a crystalline propylene polymer in liquid monomers being prepared in the first stage and a copolymer in the gas phase being prepared in the second stage.
摘要翻译： 如果由式I（* CHEMICAL STRUCTURE *）（I）的手性茂金属（桥梁）组成的催化剂和（I）化合物的组成的催化剂，以高产率获得具有良好流动性和非常好的低温冲击强度的丙烯嵌段共聚物 铝氧烷用于丙烯和共聚单体的聚合。 聚合分两个阶段进行，在第一阶段制备液态单体中的结晶丙烯聚合物，在第二阶段制备气相共聚物。
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公开(公告)号：US5278264A
公开(公告)日：1994-01-11
申请号：US934573
申请日：1992-08-24
申请人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
发明人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
IPC分类号： C07C13/465 , C07C1/24 , C07C45/28 , C07C45/46 , C07C49/67 , C07F7/00 , C07F17/00 , C08F2/06 , C08F4/60 , C08F4/625 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F4/82 , C08F10/00 , C08F110/06 , C08F4/64
CPC分类号： C07C45/46 , C07C13/465 , C07C45/28 , C07C49/67 , C07F17/00 , C08F10/00 , C07C2102/08 , C08F110/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very effective catalyst system for olefin polymerization consists of a cocatalyst, preferably an aluminoxane, and a metallocene of the formula (I) ##STR1## in which, preferably, M.sup.1 is Zr, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 to R.sup.6 are alkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a chain having one or more members, in which R.sup.7 can also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system leads to polymers of variable molecular weight and stereotacticity, depending on the substituents R.sup.3 to R.sup.6 chosen, at polymerization temperatures which are relevant in industry.
摘要翻译： 用于烯烃聚合的非常有效的催化剂体系由助催化剂，优选铝氧烷和式（I）的金属茂（*化学结构*）（I）组成，其中优选M1是Zr，R1和R2是烷基或 卤素，R3至R6是烷基， - （CR8R9）m-R7-（CR8R9）n - 是具有一个或多个成员的链，其中R7也可以是（取代的）杂原子，并且m + n为零或 根据与工业相关的聚合温度，催化剂体系导致可变分子量和立体定向性的聚合物，这取决于所选择的取代基R 3至R 6。
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公开(公告)号：US5243001A
公开(公告)日：1993-09-07
申请号：US960249
申请日：1992-10-13
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06
CPC分类号： C08F110/06 , C08F10/00 , C08F10/06 , C08F110/02 , C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization is composed of an aluminoxane and a metallocene of the formula I ##STR1## wherein preferably M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen, R.sup.5 and R.sup.6 are alkyl or haloalkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.m --is a single-membered or multimembered chain in which R.sup.7 may also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system gives polymers having a high molecular weight and high stereospecificity.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系由铝氧烷和式I的茂金属组成（I），其中优选M1是Zr或Hf，R1和R2是烷基或卤素，R3和R4是氢，R5和 R6是烷基或卤代烷基， - （CR8R9）m-R7-（CR8R9）m-是单元或多元链，其中R7也可以是（取代的）杂原子，并且m + n为零或1. 催化剂体系提供具有高分子量和高立体定向性的聚合物。
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公开(公告)号：US5132381A
公开(公告)日：1992-07-21
申请号：US490833
申请日：1990-03-08
IPC分类号： C07F17/00 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F110/06
CPC分类号： C08F110/06 , C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A syndiotactic polyolefin is obtained in a high yield by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst consisting of a metallocene of the formula I ##STR1## and an aluminoxane. This polyolefin has a very high syndiotactic index. At a low polymerization temperature, a polyolefin having a low average molecular weight and narrow molecular weight distribution is obtained, and at a high polymerization temperature a polymer having a high average molecular weight and a wide molecular weight distribution is obtained.Shaped articles produced from the polymers are distinguished by a high transparency, flexibility, tear strength and excellent surface gloss.
摘要翻译： 在由式I（I）的茂金属和铝氧烷组成的催化剂的存在下，通过式R a -CH = CH-R b的烯烃的聚合或共聚，可以高产率获得间同立构聚烯烃。 该聚烯烃具有非常高的间同立构指数。 在低聚合温度下，获得具有低平均分子量和窄分子量分布的聚烯烃，并且在高聚合温度下获得具有高平均分子量和宽分子量分布的聚合物。 由聚合物制成的成型品通过高透明度，柔韧性，撕裂强度和优异的表面光泽来区分。
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公开(公告)号：US5087677A
公开(公告)日：1992-02-11
申请号：US548083
申请日：1990-07-05
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/6192 , C08F4/626 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F32/00 , C08F32/04 , C08F32/08 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F232/00 , C08F232/04
CPC分类号： C08F210/00 , C07F17/00 , C08F32/00 , C08F32/08 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： Polymers of polycyclic olefins of the formulae I to IV having a viscosity number greater than 20 cm.sup.3 /g and a glass transition temperature above 100.degree. C. are obtained without ring opening at a high polymerization rate and at polymerization temperatures advantageous from the technical point of view by means of a catalyst which is composed of a stereo-rigid, chiral metallocene compound of groups IVb to VIb of the Periodic Table of the Elements and an aluminoxane. ##STR1##
摘要翻译： 获得粘度大于20立方厘米/克，玻璃化转变温度高于100℃的式I至IV的多环烯烃聚合物，而不以高聚合速率开环，聚合温度优选为 通过由元素周期表IVb至VIb族的立体刚性手性茂金属化合物和铝氧烷组成的催化剂来观察。 （一）图像（二）<图像>（三）<图像>（四）
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公开(公告)号：US5086134A
公开(公告)日：1992-02-04
申请号：US424116
申请日：1989-10-19
IPC分类号： C08F4/642 , C07F17/00 , C08F2/02 , C08F4/58 , C08F4/60 , C08F4/602 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65922 , Y10S526/902 , Y10S526/909 , Y10S526/943
摘要： The invention relates to a process for the preparation of a predominantly crystalline ethylene/propylene copolymer having less than 15 mol % of propylene units, which can be carried out in liquid propylene as the suspending agent, if metallocene catalyst components of the formulae I, II or III are employed and the partial pressures of ethylene and propylene have a specific ratio. ##STR1## By means of this process, it is possible to increase the possible uses of polymerization plants which work with liquid propylene.
摘要翻译： 本发明涉及一种制备主要结晶的乙烯/丙烯共聚物的方法，其具有小于15mol％的丙烯单元，其可以在作为悬浮剂的液态丙烯中进行，如果式I，II的茂金属催化剂组分 或III，并且乙烯和丙烯的分压具有特定的比例。 （Ⅰ）<图像>（II）<图像>（III）通过该方法，可以增加与液体丙烯一起使用的聚合装置的可能用途。
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47.再颁专利Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts 失效含有2-取代茚基衍生物配体的金属茂，其制备方法及其作为催化剂的用途公开(公告)号：USRE39532E1
公开(公告)日：2007-03-27
申请号：US08895909
申请日：1997-07-17
IPC分类号： C07F7/28 , C07F9/00 , C07F11/00 , C07C13/465
CPC分类号： C07F17/00 , C07F7/0805 , C08F4/63912 , C08F4/63927 , C08F10/00 , C08F110/06 , C08F2500/03 , C08F2500/17 , C08F2500/15
摘要： The novel metallocenes of the formula I in which, preferably, M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, —(CR8R9)m—R7—(CR8R9)n— is a single- or multi-membered chain in which R7 may also be a (substituted) hetero atom, m+n is zero or 1, and R10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.
摘要翻译： 配方的新金属茂
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48.发明授权Metallocenes containing aryl-substituted indenyl ligands and their use as catalysts 失效含有芳基取代的茚基配体的金属茂及其作为催化剂的用途公开(公告)号：US06242544B1
公开(公告)日：2001-06-05
申请号：US09001152
申请日：1997-12-30
申请人： Frank Küber , Bernd Bachmann , Walter Spaleck , Andreas Winter , Jürgen Rohrmann
发明人： Frank Küber , Bernd Bachmann , Walter Spaleck , Andreas Winter , Jürgen Rohrmann
IPC分类号： C08F452
CPC分类号： C08F297/08 , B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/40 , B01J2531/48 , B01J2531/50 , B01J2531/60 , C07C17/14 , C07C45/46 , C07C49/67 , C07F17/00 , C08F4/63912 , C08F4/63916 , C08F4/63927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F297/083 , Y10S526/904 , Y10S526/905 , Y10S526/943 , C07C22/04 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/01 , C08F2500/15 , C08F2500/18
摘要： A very effective catalyst system for the polymerization or copolymerization of olefins comprises a cocatalyst, preferably an aluminoxane or a supported aluminoxane, and a metallocene of the formula I in which, in the preferred form, M1 is Zr or Hf, R1 and R2 are halogen or alkyl, R3 is alkyl, R4 to R12 are alkyl or hydrogen and R13 is a (substituted) alkylene or heteroatom bridge. The metallocenes, in particular the zirconocenes, produce polymers of very high molecular weight, in the case of prochiral monomers polymers of very high molecular weight, very high stereotacticity and very high melting point, at high catalyst activities in the industrially interesting temperature range between 50 and 80° C.
摘要翻译： 用于烯烃聚合或共聚的非常有效的催化剂体系包括助催化剂，优选铝氧烷或负载的铝氧烷，以及优选形式的M1为Zr或Hf的式Iin的茂金属，R 1和R 2为卤素或 烷基，R 3是烷基，R 4至R 12是烷基或氢，R 13是（取代的）亚烷基或杂原子桥。 茂金属，特别是锆茂，产生非常高分子量的聚合物，在前分子量高，立体定向性非常高，熔点非常高的前手性单体聚合物的情况下，在高催化剂活性的工业感兴趣的温度范围为50 和80℃
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49.发明授权Metallocene catalysts comprising indenyl ligands substituted with electronegative groups 失效茂金属催化剂包括用电负性基团取代的茚基配位体
公开(公告)号：US6087292A
公开(公告)日：2000-07-11
申请号：US46741
申请日：1998-03-24
申请人： Andreas Winter , Juergen Rohrmann , Martin Antberg , Walter Spaleck , Wolfgang Anton Herrmann , Herbert Riepl
发明人： Andreas Winter , Juergen Rohrmann , Martin Antberg , Walter Spaleck , Wolfgang Anton Herrmann , Herbert Riepl
IPC分类号： C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/6592 , C08F10/00 , C08F110/06 , B01J31/00
CPC分类号： C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63927 , C08F4/65912 , Y10S526/943
摘要： A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## where M.sup.1 =Zr or Hf, R.sup.1 and R.sup.2 =(C.sub.1 -C.sub.3)-alkyl or chlorine, R.sup.3, with the proviso that at least one of the radicals R.sup.3 is not hydrogen, is hydrogen, F, Cl, --OR.sup.7, --NR.sup.7 R.sup.8, --P(O)R.sup.7 R.sup.8, --P(OR.sup.7).sub.2 or SR.sup.7, R.sup.4 is a ##STR2## radical, and m plus n are zero or 1.
摘要翻译： 用于烯烃聚合的高效催化剂体系包括助催化剂，优选铝氧烷和式I的茂金属，其中M1 = Zr或Hf，R1和R2 =（C1-C3） - 烷基或氯，R3与 条件是基团R3中的至少一个不是氢，是氢，F，Cl，-OR7，-NR7R8，-P（O）R7R8，-P（OR7）2或SR7，R4是基团，m + n为零或1。
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公开(公告)号：US6017841A
公开(公告)日：2000-01-25
申请号：US846667
申请日：1997-05-01
申请人： Andreas Winter , Walter Spaleck
发明人： Andreas Winter , Walter Spaleck
IPC分类号： C08F4/58 , C07F17/00 , C08F4/60 , C08F4/6192 , C08F4/62 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F297/06
CPC分类号： C08F110/06 , C07F17/00 , C08F10/00 , C08F10/06 , C08F4/61927 , C08F4/63912 , C08F4/63922 , C08F4/63927 , C08F4/65912 , C08F4/65927 , Y10S526/902 , Y10S526/943
摘要： In the case of Ziegler catalysts based on a metallocene as the transition metal component and an aluminoxane as the activator, preactivation of the metallocene with the aluminoxane results in a considerable increase in the activity of the catalyst system. Furthermore, 1-olefin polymers of a high degree of isotacticity and having compact, spherical particles, a very narrow particle size distribution and a high bulk density are obtained by means of a catalyst system of this type.
摘要翻译： 在基于茂金属作为过渡金属组分的齐格勒催化剂和铝氧烷作为活化剂的情况下，用铝氧烷预活化茂金属导致催化剂体系的活性显着增加。 此外，通过这种催化剂体系可获得具有高度全同立构规整度并具有致密球形颗粒，非常窄的粒度分布和高堆积密度的1-烯烃聚合物。
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