公开(公告)号：US08680346B2

公开(公告)日：2014-03-25

申请号：US13063079

申请日：2009-09-11

Applicant: Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

Inventor： Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

IPC: C07C17/00

CPC classification number: C07C21/18 ,  C07C17/04 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  C07C51/12 ,  C07C19/10

Abstract: The subject of the invention is a process for the preparation of 2,3-dichloro-1,1,1-trifluoropropane by chlorination of 3,3,3-trifluoropropene at a pressure greater than 2 bar. Application in the synthesis of 1234yf.

Abstract translation: 本发明的主题是通过在大于2巴的压力下氯化3,3,3-三氟丙烯来制备2,3-二氯-1,1,1-三氟丙烷的方法。 应用于1234yf的合成。

公开(公告)号：US08536386B2

公开(公告)日：2013-09-17

申请号：US12602705

申请日：2009-08-18

Applicant: Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

Inventor： Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

IPC: C07C17/00

CPC classification number: C07C17/25 ,  C07C21/18

Abstract: A subject-matter of the invention is a process for the preparation of fluoroolefin compounds. It relates more particularly to a process for the manufacture of a compound of formula (I) CF3—CF═CHX in which X represents a hydrogen or fluorine atom, comprising at least one stage of dehydrofluorination of a compound of formula (II) CF3—CHF—CHFX during which the compound of formula (II) is brought into contact with a mixture composed of water and of potassium hydroxide in which the potassium hydroxide is present in an amount of between 58 and 86% by weight.

Abstract translation: 本发明的主题是制备氟烯烃化合物的方法。 更具体地涉及制备式（I）化合物的方法，其中X表示氢或氟原子，包括式（II）化合物的至少一个脱氟化氢阶段CF 3 - CHF-CHFX，其中使式（II）化合物与由氢和氢氧化钾组成的混合物接触，其中氢氧化钾的存在量为58至86重量％。

公开(公告)号：US08058487B2

公开(公告)日：2011-11-15

申请号：US11606753

申请日：2006-11-30

Applicant: Beatrice Boussand ,  Michel Devic

Inventor： Beatrice Boussand ,  Michel Devic

IPC: C07C17/08

CPC classification number: C07C17/21 ,  C07C19/08

Abstract: The present invention relates to a continuous process for the fluorination of perchloroethylene (PER) in the gas phase in a single stage with hydrofluoric acid (HF) in the presence of a catalyst to give, as major product, pentafluoroethane. The process is characterized in that it is carried out at a temperature of between 280 and 430° C. and with an HF/PER molar ratio of greater than or equal to 20.

Abstract translation: 本发明涉及在催化剂存在下，用氢氟酸（HF）在单相中在气相中氟化全氯乙烯（PER）的连续方法，得到作为主要产物的五氟乙烷。 该方法的特征在于其在280至430℃之间的温度下进行，HF / PER摩尔比大于或等于20。

公开(公告)号：US20110190554A1

公开(公告)日：2011-08-04

申请号：US12602707

申请日：2009-08-19

Applicant: Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

Inventor： Anne Pigamo ,  Michel Devic ,  Laurent Wendlinger

IPC: C07C17/23

CPC classification number: C07C17/25 ,  C07C17/354 ,  C07C21/18 ,  Y02P20/582 ,  C07C19/08

Abstract: A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene which comprises the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; and (iv) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene. Stages (ii) and (iv) are carried out using a water and potassium hydroxide mixture with the potassium hydroxide representing between 58 and 86% by weight of the mixture and at a temperature of between 110 and 180° C.

Abstract translation: 本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，其包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3 ，3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; 和（iv）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯。 阶段（ii）和（iv）使用氢氧化钾与氢氧化钾混合物的比例为混合物的58-86％（重量）和在110和180℃之间的温度下进行。

公开(公告)号：US20100305370A1

公开(公告)日：2010-12-02

申请号：US12665140

申请日：2009-03-27

Applicant: Michel Devic ,  Dominique Guillet ,  Emmanuel Guiraud ,  Laurent Wendlinger

Inventor： Michel Devic ,  Dominique Guillet ,  Emmanuel Guiraud ,  Laurent Wendlinger

IPC: C07C17/25

CPC classification number: C07C21/18 ,  B01J21/04 ,  B01J23/866 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/26 ,  C07C17/25 ,  C07C17/354 ,  C07C19/08

Abstract: The invention relates to a gas-phase continuous method for preparing 2,3,3,3-tetrafluoro-1-propene, said method comprising the following steps: (i) hydrogenation of hexafluoropropylene to form 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the previous step to 1,2,3,3,3-pentafluoropropene-1; (iii) hydrogenation of the 1,2,3,3,3-pentafluoropropene-1 obtained in the previous step to form 1,1,1,2,3-pentafluoropropane; and (iv) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the previous step to form 2,3,3,3-tetrafluoro-1-propene.

Abstract translation: 本发明涉及一种制备2,3,3,3-四氟-1-丙烯的气相连续方法，所述方法包括以下步骤：（i）六氟丙烯的氢化形成1,1,1,2,3 ，3-六氟丙烷; （ii）将上一步获得的1,1,1,2,3,3-六氟丙烷的脱氟化氢化为1,2,3,3,3-五氟丙烯-1; （iii）在前一步骤中获得的1,2,3,3,3-五氟丙烯-1的氢化形成1,1,1,2,3-五氟丙烷; 和（iv）前一步骤中获得的1,1,1,2,3-五氟丙烷的脱氟化氢，形成2,3,3,3-四氟-1-丙烯。

公开(公告)号：US20100068108A1

公开(公告)日：2010-03-18

申请号：US12513412

申请日：2007-11-06

Applicant: Michel Devic

Inventor： Michel Devic

IPC: B01J19/02

CPC classification number: B01J19/02 ,  B01J2219/0245 ,  B82Y30/00 ,  C07B39/00 ,  C07C17/21 ,  C07C19/12

Abstract: The present invention relates to a process for the preparation of primary di- and/or triamines of high purity from nitriles which can themselves originate from dimer and/or trimer acids.This process comprises a stage of ammoniation of the acid functional groups and a stage of hydrogenation of the nitrile functional groups to give primary amine functional groups and does not require additional purification stage(s).

Abstract translation: 本发明涉及一种由腈制备高纯度的主要二 - 和/或三胺的方法，其本身可以源于二聚体和/或三聚酸。 该方法包括酸官能团的氨化阶段和腈官能团的氢化阶段以产生伯胺官能团，并且不需要额外的纯化阶段。

公开(公告)号：US20070129581A1

公开(公告)日：2007-06-07

申请号：US11606753

申请日：2006-11-30

Applicant: Beatrice Boussand ,  Michel Devic

Inventor： Beatrice Boussand ,  Michel Devic

IPC: C07C19/08 ,  C07C21/18

CPC classification number: C07C17/21 ,  C07C19/08

Abstract: The present invention relates to a continuous process for the fluorination of perchloroethylene (PER) in the gas phase in a single stage with hydrofluoric acid (HF) in the presence of a catalyst to give, as major product, pentafluoroethane. The process is characterized in that it is carried out at a temperature of between 280 and 430° C. and with an HF/PER molar ratio of greater than or equal to 20.

Abstract translation: 本发明涉及在催化剂存在下，用氢氟酸（HF）在单相中在气相中氟化全氯乙烯（PER）的连续方法，得到作为主要产物的五氟乙烷。 该方法的特征在于其在280至430℃之间的温度下进行，HF / PER摩尔比大于或等于20。

公开(公告)号：US07202308B2

公开(公告)日：2007-04-10

申请号：US10466170

申请日：2001-11-23

Applicant: Beatrice Boussand ,  Philippe Bonnet ,  Francois Court ,  Michel Devic ,  Manuel Hidalgo ,  Christophe Navarro

Inventor： Beatrice Boussand ,  Philippe Bonnet ,  Francois Court ,  Michel Devic ,  Manuel Hidalgo ,  Christophe Navarro

IPC: C08F8/02

CPC classification number: C08F8/04 ,  Y02P20/542 ,  C08F297/00

Abstract: Use is made, for selectively hydrogenating the olefinic double bonds of block copolymers, at least one block of which comprises olefinic double bonds, using a catalyst based on a metal from Group VIII in a medium comprising an organic solvent for the copolymer and an ionic liquid as solvent for the catalyst, of a water-immiscible ionic liquid, preferably an ionic liquid for which the anion is the hexafluorophosphate anion and the cation is the 1-butyl-3-methylimidazolium (bmim+) or 1-ethyl-3-methylimidazolium (emim+) cation.Applied to poly(styrene)-b-poly(butadiene)-b-poly(methyl methacrylate) block copolymers, the poly(butadiene) block of which predominantly possesses a 1,4-microstructure, this process results in copolymers for which the degree of hydrogenation is at least equal to 50% and which exhibit a melting point of greater than 30 °C.

Abstract translation: 使用在包含共聚物的有机溶剂的介质中使用基于VIII族金属的催化剂和至少一个嵌段共聚物的烯属双键来选择性氢化嵌段共聚物的烯属双键，并且使用离子液体 作为催化剂的溶剂，与水不混溶的离子液体，优选阴离子是六氟磷酸盐阴离子的离子液体，阳离子是1-丁基-3-甲基咪唑鎓（bmim +）或 1-乙基-3-甲基咪唑鎓（emim + +）阳离子。

公开(公告)号：US07060244B2

公开(公告)日：2006-06-13

申请号：US10221339

申请日：2001-02-15

Applicant: Michel Devic

Inventor： Michel Devic

IPC: C01B15/029

CPC classification number: B01J8/228 ,  B01J8/222 ,  B01J19/1881 ,  B01J19/243 ,  B01J2208/00141 ,  B01J2208/00176 ,  B01J2208/00212 ,  B01J2208/00256 ,  B01J2208/003 ,  B01J2219/00031 ,  B01J2219/00083 ,  B01J2219/00099 ,  B01J2219/00103 ,  B01J2219/00114 ,  C01B15/013 ,  C01B15/029

Abstract: The invention concerns a method for making an aqueous solution of hydrogen peroxide. More particularly, it concerns a method for making hydrogen peroxide directly from hydrogen and oxygen, finely dispersed in an aqueous acid medium comprising a catalyst and at least a surfactant. The invention also concerns a device for implementing said method.

公开(公告)号：US06958138B1

公开(公告)日：2005-10-25

申请号：US10018868

申请日：2000-06-07

Applicant: Michel Devic

Inventor： Michel Devic

IPC: B01J8/00 ,  B01J8/22 ,  B01J19/18 ,  B01J23/10 ,  B01J23/38 ,  B01J23/40 ,  B01J23/44 ,  B01J27/185 ,  B01J35/10 ,  B01J37/02 ,  C01B15/029 ,  C01B15/01

CPC classification number: B01J27/13 ,  B01J8/006 ,  B01J8/222 ,  B01J8/228 ,  B01J19/1881 ,  B01J23/38 ,  B01J23/40 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/22 ,  B01J2208/00176 ,  B01J2208/00212 ,  B01J2219/185 ,  C01B15/029

Abstract: The invention concerns a supported metal catalyst based on at least one metal selected in the group M consisting of palladium, platinum, ruthenium, rhodium, iridium, holmium, osmium and gold, used for directly making hydrogen peroxide from hydrogen and oxygen. The invention also concerns a method for making said catalyst comprising successively an impregnating step with a solution based on one or several salt(s) of at least one metal of group M on a support, and a reduction step characterised in that at the end of the reduction step, the catalyst is treated with an aqueous acid solution comprising bromine and bromide ions. The catalyst is characterised by metal or crystallised metal aggregates with size ranging between 0.1 and 20 microns and preferably between 0.1 and 10 microns. The supported bimetal catalyst is preferred, for example Pd—Pt, Au—Pt, Pd—Ho and Pd—Au.

Abstract translation: 本发明涉及一种载体金属催化剂，其基于选自由钯，铂，钌，铑，铱，钬，锇和金组成的组M中的至少一种金属，用于从氢气和氧气直接制备过氧化氢。 本发明还涉及一种制备所述催化剂的方法，其包括基于载体上至少一种M族金属的一种或多种盐的溶液的浸渍步骤，以及还原步骤，其特征在于在末端 还原步骤，用包含溴和溴离子的酸性水溶液处理催化剂。 催化剂的特征在于金属或结晶的金属聚集体，其尺寸范围为0.1至20微米，优选为0.1至10微米。 优选负载的双金属催化剂，例如Pd-Pt，Au-Pt，Pd-Ho和Pd-Au。