Hydrogenation method for unsaturated block copolymers and hydrogenated unsaturated block copolymers
    1.
    发明授权
    Hydrogenation method for unsaturated block copolymers and hydrogenated unsaturated block copolymers 失效
    不饱和嵌段共聚物和氢化不饱和嵌段共聚物的氢化方法

    公开(公告)号:US07202308B2

    公开(公告)日:2007-04-10

    申请号:US10466170

    申请日:2001-11-23

    IPC分类号: C08F8/02

    摘要: Use is made, for selectively hydrogenating the olefinic double bonds of block copolymers, at least one block of which comprises olefinic double bonds, using a catalyst based on a metal from Group VIII in a medium comprising an organic solvent for the copolymer and an ionic liquid as solvent for the catalyst, of a water-immiscible ionic liquid, preferably an ionic liquid for which the anion is the hexafluorophosphate anion and the cation is the 1-butyl-3-methylimidazolium (bmim+) or 1-ethyl-3-methylimidazolium (emim+) cation.Applied to poly(styrene)-b-poly(butadiene)-b-poly(methyl methacrylate) block copolymers, the poly(butadiene) block of which predominantly possesses a 1,4-microstructure, this process results in copolymers for which the degree of hydrogenation is at least equal to 50% and which exhibit a melting point of greater than 30 °C.

    摘要翻译: 使用在包含共聚物的有机溶剂的介质中使用基于VIII族金属的催化剂和至少一个嵌段共聚物的烯属双键来选择性氢化嵌段共聚物的烯属双键,并且使用离子液体 作为催化剂的溶剂,与水不混溶的离子液体,优选阴离子是六氟磷酸盐阴离子的离子液体,阳离子是1-丁基-3-甲基咪唑鎓(bmim +)或 1-乙基-3-甲基咪唑鎓(emim + +)阳离子。

    Process for the manufacture of pentafluoroethane
    2.
    发明授权
    Process for the manufacture of pentafluoroethane 有权
    五氟乙烷生产工艺

    公开(公告)号:US08058487B2

    公开(公告)日:2011-11-15

    申请号:US11606753

    申请日:2006-11-30

    IPC分类号: C07C17/08

    CPC分类号: C07C17/21 C07C19/08

    摘要: The present invention relates to a continuous process for the fluorination of perchloroethylene (PER) in the gas phase in a single stage with hydrofluoric acid (HF) in the presence of a catalyst to give, as major product, pentafluoroethane. The process is characterized in that it is carried out at a temperature of between 280 and 430° C. and with an HF/PER molar ratio of greater than or equal to 20.

    摘要翻译: 本发明涉及在催化剂存在下,用氢氟酸(HF)在单相中在气相中氟化全氯乙烯(PER)的连续方法,得到作为主要产物的五氟乙烷。 该方法的特征在于其在280至430℃之间的温度下进行,HF / PER摩尔比大于或等于20。

    Process for the manufacture of pentafluoroethane
    3.
    发明申请
    Process for the manufacture of pentafluoroethane 有权
    五氟乙烷生产工艺

    公开(公告)号:US20070129581A1

    公开(公告)日:2007-06-07

    申请号:US11606753

    申请日:2006-11-30

    IPC分类号: C07C19/08 C07C21/18

    CPC分类号: C07C17/21 C07C19/08

    摘要: The present invention relates to a continuous process for the fluorination of perchloroethylene (PER) in the gas phase in a single stage with hydrofluoric acid (HF) in the presence of a catalyst to give, as major product, pentafluoroethane. The process is characterized in that it is carried out at a temperature of between 280 and 430° C. and with an HF/PER molar ratio of greater than or equal to 20.

    摘要翻译: 本发明涉及在催化剂存在下,用氢氟酸(HF)在单相中在气相中氟化全氯乙烯(PER)的连续方法,得到作为主要产物的五氟乙烷。 该方法的特征在于其在280至430℃之间的温度下进行,HF / PER摩尔比大于或等于20。

    COMPOSITION COMPRISING 2,3,3,3-TETRAFLUOROPROPENE
    5.
    发明申请
    COMPOSITION COMPRISING 2,3,3,3-TETRAFLUOROPROPENE 有权
    包含2,3,3,3-四氯丙烯的组合物

    公开(公告)号:US20130092869A1

    公开(公告)日:2013-04-18

    申请号:US13704272

    申请日:2011-06-07

    申请人: Beatrice Boussand

    发明人: Beatrice Boussand

    IPC分类号: C09K5/04

    摘要: The invention relates to a composition comprising a lubricant based on polyol esters (POE) and a refrigerant F including at least 99.8 wt % 2,3,3,3-tetrafluoropropene, between 0.5 and 500 ppm 1,1,1,2,3-pentafluoropropene, between 0.5 and 500 ppm trifluoropropyne and between 1 and 500 ppm compounds based on or carbon atoms optionally including an olefinic bond.

    摘要翻译: 本发明涉及一种组合物,其包含基于多元醇酯(POE)的润滑剂和包含至少99.8重量%的2,3,3,3-四氟丙烯的制冷剂F,0.5至500ppm之间的1,1,1,2,3 0.5至500ppm的三氟丙炔和1至500ppm的基于或任选包括烯键的碳原子的化合物。

    COMPOSITION BASED ON 1,3,3,3-TETRAFLUOROPROPENE
    6.
    发明申请
    COMPOSITION BASED ON 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
    基于1,3,3,3-四氯丙烯的组合物

    公开(公告)号:US20120068104A1

    公开(公告)日:2012-03-22

    申请号:US13232106

    申请日:2011-09-14

    IPC分类号: C09K5/04

    摘要: The subject of the present application is a composition comprising a lubricant based on polyol esters (POEs) or PVE and a refrigerant F comprising from 1 to 99% by weight of trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze) and from 1 to 99% by weight of 1,1,1,3-tetrafluoroethane. The subject of the present application is also the use of said composition in refrigeration, air conditioning and heat pumps.

    摘要翻译: 本申请的主题是包含基于多元醇酯(POE)或PVE的润滑剂和包含1至99重量%的反式-1,3,3,3-四氟丙烯(反式HFO- 1234ze)和1至99重量%的1,1,1,3-四氟乙烷。 本申请的主题也是在制冷,空调和热泵中使用所述组合物。

    Heat-transfer fluids having reduced flammability

    公开(公告)号:US10308853B2

    公开(公告)日:2019-06-04

    申请号:US13516796

    申请日:2010-12-16

    IPC分类号: C09K5/04

    摘要: The invention relates to a method for cooling or heating a fluid or a body by means of a vapour compression circuit containing a heat transfer fluid, said circuit being at least partially contained in an enclosure, and the relative humidity of the air in the enclosure being less than or equal to a threshold value H1 which is less than 50%, the flammability of the heat transfer fluid at relative humidity H1 being less than the flammability of the heat transfer fluid at 50% relative humidity.The invention also relates to a cooling or heating installation suited to the implementation of this method. The invention also relates to a method of protection against the risks of fire or explosion in an enclosure containing at least partially a vapour compression circuit containing a heat transfer fluid, as well as a method for reducing the GWP of a transfer fluid. The invention also relates to heat transfer fluids suited to the implementation of the above methods.