公开(公告)号：US11976037B2

公开(公告)日：2024-05-07

申请号：US16410897

申请日：2019-05-13

Applicant: Hexion Inc.

Inventor： Fabrizio Marras ,  Leo Sliedregt ,  Alexander Kraynov

IPC: C07C67/055 ,  B01J23/44 ,  B01J23/89 ,  B01J31/02 ,  B01J31/22 ,  B01J35/00 ,  B01J37/04 ,  C07C67/58 ,  B01J27/13 ,  B01J29/072 ,  B01J35/12

CPC classification number: C07C67/055 ,  B01J23/44 ,  B01J23/8926 ,  B01J31/0201 ,  B01J31/0239 ,  B01J31/2234 ,  B01J31/2239 ,  B01J35/0006 ,  B01J37/04 ,  C07C67/58 ,  B01J27/13 ,  B01J29/072 ,  B01J35/12 ,  B01J2231/49 ,  B01J2531/16 ,  B01J2531/824 ,  Y02P20/582 ,  C07C67/055 ,  C07C69/01 ,  C07C67/055 ,  C07C69/24 ,  C07C67/58 ,  C07C69/24 ,  C07C67/58 ,  C07C69/01 ,  C07C67/055 ,  C07C69/78 ,  C07C67/055 ,  C07C69/44 ,  C07C67/055 ,  C07C69/56

Abstract: This invention concerns a process for the production of vinyl esters of carboxylic acids with 3 to 20 carbon atoms, via vinylation in the presence of palladium (Pd) catalyst in combination with copper (Cu) as co-catalyst stabilized by organic salts in the presence of ethylene and air or oxygen.

公开(公告)号：US20190185404A1

公开(公告)日：2019-06-20

申请号：US16323479

申请日：2017-08-24

Applicant: Nicolaas A. De Munck ,  Hans K. T. Goris ,  Eddy Van Driessche

Inventor： Nicolaas A. De Munck ,  Hans K. T. Goris ,  Eddy Van Driessche

IPC: C07C51/36 ,  C07C67/303

CPC classification number: C07C51/36 ,  B01J27/13 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/18 ,  C07C67/303 ,  C07C2601/14 ,  C07C69/75

Abstract: A process for ring hydrogenation of a benzenepolycarboxylic acid or derivative thereof, which process comprises contacting a feed stream comprising said acid or derivative thereof with a hydrogen-containing gas in the presence of a catalyst under hydrogenation conditions to produce a hydrogenated product, wherein said catalyst comprises a Group VIII metal, a support material and a halogen, and wherein the halogen is present in an amount of from 0.02 to 0.60% by weight, based on the total weight of the catalyst.

公开(公告)号：US20190184383A1

公开(公告)日：2019-06-20

申请号：US16285736

申请日：2019-02-26

Applicant: Liudmila Aleksandrovna TYURINA ,  Alexander Ivanovich TYURIN ,  Irina Gennadievna TARKHANOVA ,  Alexey Aleksandrovich TYURIN

Inventor： Liudmila Aleksandrovna TYURINA ,  Alexander Ivanovich TYURIN ,  Irina Gennadievna TARKHANOVA ,  Alexey Aleksandrovich TYURIN

IPC: B01J27/122 ,  B01J31/16 ,  B01D53/26 ,  B01J31/02 ,  B01D53/86 ,  B01J27/32 ,  C07C7/11 ,  C07C7/148 ,  B01J27/128

CPC classification number: B01J27/122 ,  B01D53/263 ,  B01D53/8603 ,  B01D53/8612 ,  B01D2251/90 ,  B01D2252/2023 ,  B01D2255/20761 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/306 ,  B01J27/128 ,  B01J27/13 ,  B01J27/32 ,  B01J31/02 ,  B01J31/16 ,  C07C7/11 ,  C07C7/1485

Abstract: This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc., including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.

公开(公告)号：US20180200699A1

公开(公告)日：2018-07-19

申请号：US15539882

申请日：2016-07-04

Applicant: START-CATALYST LLC

Inventor： Liudmila Aleksandrovna TYURINA ,  Alexander Ivanovich TYURIN ,  Irina Gennadievna TARKHANOVA ,  Alexey Aleksandrovich TYURIN

IPC: B01J27/122 ,  B01D53/86 ,  B01D53/26 ,  C07C7/148 ,  C07C7/11

CPC classification number: B01J27/122 ,  B01D53/263 ,  B01D53/8603 ,  B01D53/8612 ,  B01D2251/90 ,  B01D2252/2023 ,  B01D2255/20761 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/306 ,  B01J27/128 ,  B01J27/13 ,  B01J27/32 ,  B01J31/02 ,  B01J31/16 ,  C07C7/11 ,  C07C7/1485

Abstract: This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc, including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.

公开(公告)号：US09932361B2

公开(公告)日：2018-04-03

申请号：US15063966

申请日：2016-03-08

Applicant: F.I.S.—FABBRICA ITALIANA SINTETICI S.P.A.

Inventor： Ottorino De Lucchi ,  Stefano Tartaggia ,  Clark Ferrari ,  Marco Galvagni ,  Marta Pontini ,  Stefano Fogal ,  Riccardo Motterle ,  Rosa Maria Moreno ,  Alex Comely

IPC: C07F7/18 ,  C07D239/42 ,  C07D317/30 ,  C07D215/14 ,  C07D209/24 ,  C07D413/12 ,  C07D419/12 ,  B01J27/13 ,  B01J31/12 ,  C07D209/12 ,  C07D213/30

CPC classification number: C07F7/1804 ,  B01J27/13 ,  B01J31/122 ,  B01J2231/543 ,  C07D209/12 ,  C07D209/24 ,  C07D213/30 ,  C07D215/14 ,  C07D239/42 ,  C07D317/30 ,  C07D413/12 ,  C07D419/12 ,  C07F7/188 ,  C07F7/1892

Abstract: Object of the present invention is an improved process for the preparation of key intermediates for the synthesis of statins.

公开(公告)号：US20180045884A1

公开(公告)日：2018-02-15

申请号：US15726725

申请日：2017-10-06

Applicant: ZDF LTD.

Inventor： Alexander Zilberman ,  Angelika Sokolowa ,  David Mizrahi

IPC: G02B6/036 ,  G02B6/02 ,  B01J27/10 ,  B01J27/135 ,  B01J27/13 ,  C23C18/18 ,  C03C25/10 ,  C23C18/36 ,  C23C18/30 ,  C23C18/28 ,  C23C18/16 ,  G02B6/44

CPC classification number: G02B6/036 ,  A61B2018/00547 ,  A61B2018/2222 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J31/0274 ,  C03C25/109 ,  C23C18/1639 ,  C23C18/165 ,  C23C18/1651 ,  C23C18/1844 ,  C23C18/1893 ,  C23C18/285 ,  C23C18/30 ,  C23C18/32 ,  C23C18/36 ,  C23C18/48 ,  C23C28/02 ,  G02B6/02 ,  G02B6/02033 ,  G02B6/02395 ,  G02B6/4478

Abstract: A waveguide for high efficiency transmission of high energy light useful in ablation procedures at predetermined bandwidths over predetermined distances comprising: an optical fiber core; a silanization agent; layered cladding surrounding the optical fiber core comprising: a first thin metal layer comprising at least two types of metals the first thin metal layer covalently bonded to the core and a second thin metal layer bonded to the second metal layer, and a catalyst component; wherein the silanization agent comprising organofunctional alkoxysilane molecule, such as 3-aminopropyltriethoxysilane (APTS), is a self supporting bridge between the surface of the optical fiber and the first metal layer; the first metal layer is uniformly chemisorbed onto the surface of the optical fiber by means of covalent Si—O—Si bonds with the optical fiber; further wherein the catalyst component derived from an activation solution for enhancing the layered cladding upon the optical fiber.

公开(公告)号：US09738589B2

公开(公告)日：2017-08-22

申请号：US15183163

申请日：2016-06-15

Applicant: DAIKIN INDUSTRIES, LTD.

Inventor： Tatsuya Ohtsuka ,  Akihiro Gotou ,  Sumi Ishihara ,  Yoshihiro Yamamoto ,  Akinori Yamamoto ,  Yoshichika Kuroki ,  Yuzo Komatsu ,  Yousuke Kishikawa

IPC: C07C67/36 ,  B01J27/13 ,  B01J31/24 ,  B01J23/44 ,  B01J31/02

CPC classification number: C07C67/36 ,  B01J23/44 ,  B01J27/13 ,  B01J31/0237 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/321 ,  B01J2231/49 ,  B01J2531/824 ,  C07C69/653

Abstract: The object of the present invention is to provide a process for producing α-fluoroacrylic acid ester at a high starting material conversion, high selectivity, and high yield. The present invention provides a process for producing the compound represented by the formula (1) wherein R represents alkyl optionally substituted with one or more fluorine atoms, the process comprising step A of reacting a compound represented by the formula (2) wherein X represents a bromine atom or a chlorine atom with an alcohol represented by the formula (3) wherein the symbol is as defined above, and carbon monoxide in the presence of a transition metal catalyst and a base to thereby obtain the compound represented by the formula (1).

公开(公告)号：US09718763B2

公开(公告)日：2017-08-01

申请号：US14990308

申请日：2016-01-07

Applicant: Regents of the University of Minnesota

Inventor： William Baker Tolman ,  Marc A. Hillmyer ,  Alex John ,  Levi Thomas Hogan

IPC: C07C253/30 ,  C07C67/32 ,  B01J27/13 ,  C07C67/317 ,  C07C201/12 ,  C07C1/207 ,  C07C17/361

CPC classification number: C07C253/30 ,  B01J23/44 ,  B01J23/755 ,  B01J27/128 ,  B01J27/13 ,  B01J2531/824 ,  C07C1/207 ,  C07C17/361 ,  C07C67/317 ,  C07C67/32 ,  C07C201/12 ,  C07C2527/13 ,  C07C2531/24 ,  Y02P20/52 ,  C07C69/54 ,  C07C255/08 ,  C07C15/46 ,  C07C15/44 ,  C07C11/167 ,  C07C11/02 ,  C07C11/12 ,  C07C15/52 ,  C07C205/06 ,  C07C15/50 ,  C07C15/58 ,  C07C25/28

Abstract: A process of preparing olefins of the formula (I) is described herein: with R1 being a substituted or unsubstituted (C1-C30)hydrocarbyl, and R2 being a substituted or unsubstituted (C1-C20)hydrocarbyl. The process includes reacting a compound of formula (II) wherein Ar is chosen from in the presence of a palladium-based catalyst and an organic solvent. A process of preparing olefins of the formula (III) is also described: with R3 being a substituted or unsubstituted (C1-C30)hydrocarbyl, R4 being a substituted or unsubstituted (C1-C20)hydrocarbyl, and R5 being a substituted or unsubstituted (C1-C30) hydrocarbyl. The process includes reacting a compound of formula (IV) wherein Ar is chosen from with a compound of formula (V) wherein Ar is chosen from in the presence of a palladium-based catalyst and an organic solvent.

公开(公告)号：US09694356B2

公开(公告)日：2017-07-04

申请号：US15081234

申请日：2016-03-25

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC

Inventor： Daqing Zhang ,  Gaoshan Zang ,  Yuhong Zhang ,  Jiaxin Wang ,  Tao Wang

IPC: B01J20/34 ,  B01J38/44 ,  B01J27/32 ,  B01J38/10 ,  B01J38/60 ,  B01J38/04 ,  B01J38/14 ,  B01J38/18 ,  B01J38/62 ,  B01J27/13 ,  C10G35/09 ,  C10G35/06 ,  B01J37/20

CPC classification number: B01J38/44 ,  B01J27/13 ,  B01J27/32 ,  B01J37/20 ,  B01J38/04 ,  B01J38/10 ,  B01J38/14 ,  B01J38/18 ,  B01J38/60 ,  B01J38/62 ,  C10G35/06 ,  C10G35/09

Abstract: This disclosure describes a method for regenerating a semi-regenerated reforming catalyst. The method comprises adjusting the reaction temperature to 250-480° C., introducing a sulfur-containing naphtha into the reforming reactor, or stopping introducing a feedstock into the reforming reactor, and introducing a sulfur-containing hydrogen into a recycle gas, until the sulfur content in the catalyst is 0.32-0.8 mass %, then the catalyst is subject to coke-burning, oxychlorination and reduction. Alternatively, the method first subjects the spent catalyst to coke-burning followed by introducing sulfate ions thereinto; and then performing oxychlorination and reduction. Disclosed is still another method for regenerating a platinum-rhenium reforming catalyst, which comprises coke-burning the spent catalyst; introducing sulfur and chlorine in the catalyst by impregnation; and then drying, calcinating and reducing.

公开(公告)号：US09580770B2

公开(公告)日：2017-02-28

申请号：US14521195

申请日：2014-10-22

Applicant: Rahul Shankar Bhaduri ,  Hye Kyung Cho Timken ,  Philip Ian Cuspard

Inventor： Rahul Shankar Bhaduri ,  Hye Kyung Cho Timken ,  Philip Ian Cuspard

IPC: C22B11/00 ,  C22B3/00 ,  B01J38/64 ,  B01J38/68 ,  B01J23/96 ,  B01J19/18 ,  C22B7/00 ,  B01J38/10 ,  B01J27/13 ,  B01J27/32

CPC classification number: C22B11/048 ,  B01J19/18 ,  B01J23/96 ,  B01J27/13 ,  B01J27/32 ,  B01J38/10 ,  B01J38/64 ,  B01J38/68 ,  B01J2219/00177 ,  C22B7/009 ,  Y02P10/214

Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.

Abstract translation: 提供了一种制备用于贵金属回收的废贵金属固定床催化剂的方法，包括：a）将催化剂加入苛性碱溶液中以洗涤废催化剂并制备具有碱性pH的洗涤浆液，其中废催化剂 已经与氯铝酸盐离子液体催化剂接触，并且其中废催化剂包含5至35重量％的氯化物; 和b）过滤洗涤浆液并收集：i）从除去的废催化剂中除去至少70重量％的氯化物并且保留贵金属的滤饼，和ii）洗涤滤液。 还提供了一种滤饼，其包括洗涤的固结滤饼，其具有40至75重量％的固体，饼状水分含量为25至小于60重量％，总贵金属为0.1至1.5重量％，残留氯含量为0至 小于4重量％。