Phosphorus esters of 1-cyanoethyl-1,2,4-triazol-3-ols
    41.
    发明授权
    Phosphorus esters of 1-cyanoethyl-1,2,4-triazol-3-ols 失效
    1-氰基乙基-1,2,4-三唑-3-醇的磷酸酯

    公开(公告)号:US4172080A

    公开(公告)日:1979-10-23

    申请号:US527330

    申请日:1974-11-26

    CPC分类号: A01N57/08 C07F9/65183

    摘要: New 1,2,4-triazoles, their manufacture and use as active ingredient on pest control is disclosed. The triazoles correspond to the formula ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio,R.sub.2 represents C.sub.1 -C.sub.6 -alkyl,R.sub.3 represents hydrogen, chlorine, bromine, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.3 -C.sub.5 -alkenylthio or C.sub.3 -C.sub.5 -alkynylthio, andX represents oxygen or sulphur.

    摘要翻译: 新的1,2,4-三唑,其制造和用作有害生物控制的有效成分。 三唑对应于下式:其中R1代表C1-C6-烷基,C1-C6-烷氧基或C1-C6-烷硫基,R2代表C1-C6-烷基,R3代表氢,氯,溴,C1-C6- 烷基,C 1 -C 6 - 烷硫基,C 3 -C 5 - 烯硫基或C 3 -C 5 - 炔硫基,X表示氧或硫。

    Triaza compounds
    44.
    发明授权
    Triaza compounds 失效
    三氮唑化合物

    公开(公告)号:US4515620A

    公开(公告)日:1985-05-07

    申请号:US454950

    申请日:1983-01-03

    申请人: Beat Bohner

    发明人: Beat Bohner

    摘要: Triaza compounds of the general formula I ##STR1## and their basic addition salts have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence. In the formula, each of A.sub.1 and A.sub.2 is a homocyclic or heterocyclic aromatic radical such as phenyl, naphthyl, indanyl, imidazolyl, pyridinyl, pyrimidinyl, pyrazolyl or triazolyl, each of which is unsubstituted or mono- to trisubstituted, while only one of A.sub.1 and A.sub.2 may be a phenyl, naphthyl or indanyl radical, and each of R.sub.1 and R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.2 is hydrogen or a cation.

    摘要翻译: 通式I(I)的三氮杂化合物及其碱式加成盐在出芽前和芽后施用时具有良好的选择性除草和植物生长调节特性。 在该式中,A 1和A 2各自为苯环,萘基,茚满基,咪唑基,吡啶基,嘧啶基,吡唑基或三唑基等杂环或杂环芳族基团,各自为未取代或单取代或三取代, 并且A 2可以是苯基,萘基或茚满基,R 1和R 3各自为氢或C 1 -C 4烷基,R 2为氢或阳离子。

    Process for preparing 1,2,4-triazole derivatives
    45.
    发明授权
    Process for preparing 1,2,4-triazole derivatives 失效
    制备1,2,4-三唑衍生物的方法

    公开(公告)号:US4123437A

    公开(公告)日:1978-10-31

    申请号:US773026

    申请日:1977-02-28

    CPC分类号: C07F9/65183 C07D249/12

    摘要: 1,2,4-TRIAZOLE DERIVATIVES WHICH HAVE PARTICULAR IMPORTANCE AS INTERMEDIATES FOR, E.G., THE PREPARATION OF ACTIVE SUBSTANCES FOR PEST CONTROL, CORRESPONDING TO THE FORMULA ##STR1## wherein R.sup.1 represents an unsubstituted or substituted alkyl, alkenyl, or alkynyl, naphthyl, benzyl, phenylethyl, ##STR2## or phenylpropyl radical, or a mono or polycyclic cycloalkyl radical which can be bound by way of an alkylene bridge member, or a substituted phenyl radical,And new processes for the preparation of compounds of the formula ##STR3## wherein R represents hydrogen, an optionally substituted alkyl, alkenyl or alkynyl radical, an optionally substituted phenyl, naphthyl, benzyl, phenylethyl or phenylpropyl radical, a mono- or polycyclic cycloalkyl radical which can be bound by way of an alkylene bridge member and/or be substituted by alkyl, or a partially hydrogenated naphthyl radical, which processes are performed by addition to a hydrazine of the formulaR -- NH--NH.sub.2or to a hydrazone of the formula ##STR4## wherein R has the above given meaning, R.sub.1 represents hydrogen or lower alkyl and R.sub.2 represents lower alkyl, of an alkoxy-carbonyl-isothiocyanate of the formulaalkyl--O--CO--NCSand subsequent closure of the triazole ring in the resulting thiosemicarbazide of the formula ##STR5## by the splitting-off of an alkanol (alkyl--OH), are disclosed.

    摘要翻译: 具有特异性重要性的1,2,4-三唑衍生物作为EG的中间体,用于制备用于病虫害控制的活性物质,对应于本发明的化合物,其中R 1表示未取代或取代的烷基,烯基或炔基,萘基, 苄基,苯基乙基,苯丙基或可以通过亚烷基桥基或取代的苯基结合的单环或多环环烷基,以及用于制备化合物的新方法 其中R表示氢,任选取代的烷基,烯基或炔基,任选取代的苯基,萘基,苄基,苯基乙基或苯基丙基,可以通过亚烷基桥连接体和/或 被烷基或部分氢化的萘基取代,该方法通过加入式R-NH-NH 2的肼或加成式的腙进行 其中R具有上述给定含义,R 1表示氢或低级烷基,R 2表示低级烷基,式ALKYL-O-CO-NCS的烷氧羰基 - 异硫氰酸酯,随后在三 公开了通过分解链烷醇(烷基-OH)得到的式“IMAGE”的氨基硫脲。

    O,S-dialkyl- and O-alkyl-S-alkoxyalkyl-S-1,2,4-oxa-diazolyl-3-methylene
dithiophosphates
    46.
    发明授权
    O,S-dialkyl- and O-alkyl-S-alkoxyalkyl-S-1,2,4-oxa-diazolyl-3-methylene dithiophosphates 失效
    O,S-二烷基 - 和O-烷基-S-烷氧基烷基-S-1,2,4-氧杂 - 二唑基-3-亚甲基二硫代磷酸酯

    公开(公告)号:US4028377A

    公开(公告)日:1977-06-07

    申请号:US517359

    申请日:1974-10-23

    IPC分类号: A01N57/16 C07F9/653 C07F9/165

    CPC分类号: A01N57/16 C07F9/65318

    摘要: 1,2,4-Oxadiazoles, their manufacture and use as active ingredients in pesticides especially insecticides and acaricides. The compounds correspond to the formula ##STR1## wherein R.sub.1 represents hydrogen, unsubstituted alkyl, benzyl or phenyl, R.sub.2 represents methyl or ethyl, and R.sub.3 represents unsubstituted C.sub.1 -C.sub.7 alkyl optionally interrupted by oxygen or represents C.sub.3 -C.sub.4 alkenyl.

    摘要翻译: 1,2,4-恶二唑,其制造和用作农药,特别是杀虫剂和杀螨剂中的有效成分。 该化合物对应于下式:其中R 1表示氢,未取代的烷基,苄基或苯基,R 2表示甲基或乙基,R 3表示任选被氧中断或表示C 3 -C 4烯基的未取代的C 1 -C 7烷基。

    1,2,4-Triazolyl-phosphoric and -phosphonic acid esters
    47.
    发明授权
    1,2,4-Triazolyl-phosphoric and -phosphonic acid esters 失效
    1,2,4-三唑基 - 磷酸和膦酸酯

    公开(公告)号:US3992399A

    公开(公告)日:1976-11-16

    申请号:US422038

    申请日:1973-12-05

    摘要: 1,2,4-Triazolylphosphoric and 1,2,4-triazolylphosphonic acid esters of the formula ##SPC1##Wherein R.sub.1 represents hydrogen, alkyl, cycloalkyl, phenyl, benzyl, or phenethyl, R.sub.2 represents substituted phenyl, benzyl, phenethyl, or unsubstituted diphenylmethyl, .beta.-naphthyl, or ##SPC2##R.sub.3 represents alkyl, alkoxy, alkylthio, amino, monoalkylamino or dialkylamino, R.sub.4 represents alkyl, and X represents oxygen or sulphur, a process for their manufacture and their use in pest control.

    摘要翻译: 1,2,4-三唑基磷酸和式+ q,10的1,2,4-三唑基膦酸酯,其中R1表示氢,烷基,环烷基,苯基,苄基或苯乙基,R2表示取代的苯基,苄基,苯乙基或 未取代的二苯基甲基,β-萘基或+ q,11 R 3表示烷基,烷氧基,烷硫基,氨基,单烷基氨基或二烷基氨基,R 4表示烷基,X表示氧或硫,其制备方法及其在害虫防治中的应用。

    1,5-diphenylpyrazole-3-carboxylic acid derivatives for the protection of
cultivated plants
    50.
    发明授权
    1,5-diphenylpyrazole-3-carboxylic acid derivatives for the protection of cultivated plants 失效
    1,5-二苯基吡唑-3-羧酸衍生物,用于保护栽培植物

    公开(公告)号:US4944790A

    公开(公告)日:1990-07-31

    申请号:US325833

    申请日:1989-03-20

    摘要: 1,5-diphenylpyrazole-3-carboxylic acid derivatives of the formula ##STR1## in which each of R.sub.a and R.sub.b, independently of the other represents halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl or cyano, n represents zero or an integer from 1 to 3, and OR.sub.1 represents hydroxy, a plant-physiologically tolerable salt radical or any desired ester radical, are capable of antagonizing specifically the phytotoxic action of phenoxypropionic acid ester herbicides of the formula II ##STR2## in which G represents ##STR3## in which Hal.sub.1 represents fluorine, chlorine, bromine, iodine or trifluoromethyl, Hal.sub.2 represents hydrogen, fluorine, chlorine, bromine or trifluoromethyl, Z represents nitrogen or methine (--CH.dbd.), X represents an oxygen or sulphur atom, R.sub.1 ' represents halogen, trifluoromethyl, nitro, cyano, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and n represents 0, 1, 2 or 3 and T represents an ester, amide, cyanamide or oxime radical.Compositions, containing those components, as selective herbicides and the use of those two active ingredients for controlling weeds in crops of useful plants are described, as are also novel 1,5-diphenylpyrazole-3-carboxylic acid derivatives corresponding to the formula I and the preparation thereof.

    摘要翻译: 其中R a和R b各自独立地表示卤素,C 1 -C 5 - 烷基,C 1 -C 5 - 卤代烷基,C 2 -C 5 - 烯基的1,5-二苯基吡唑-3-羧酸衍生物 ,C 2 -C 5炔基或氰基,n表示0或1至3的整数,OR 1表示羟基,植物 - 生理上可耐受的盐基或任何所需的酯基,能够特异性地拮抗苯氧基丙酸酯的植物毒性作用 其中G代表其中Hal1代表氟,氯,溴,碘或三氟甲基的式Ⅱ的除草剂,其中G代表氢,氯,溴,碘或三氟甲基,Hal2代表氢,氟,氯,溴或三氟甲基,Z 表示氮或次甲基(-CH =),X表示氧或硫原子,R1'表示卤素,三氟甲基,硝基,氰基,C1-C4-烷基或C1-C4-烷氧基,n表示0,1,2或3 T代表酯,酰胺,氰胺或肟基。 描述了含有这些成分的作为选择性除草剂的组合物以及这两种活性成分用于控制有用植物作物中的杂草的用途,以及对应于式I的新的1,5-二苯基吡唑-3-羧酸衍生物和 的制备。