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公开(公告)号：US07799210B2
公开(公告)日：2010-09-21
申请号：US11100309
申请日：2005-04-06
IPC分类号： C10G67/02
CPC分类号： C10G67/12 , C10G45/08 , C10G67/04 , C10G67/0418 , C10G67/06 , C10G67/14 , C10G2400/02
摘要： A three-step process of removing sulfur from naphtha feeds. The steps include a first hydrotreating step, a mercaptan removal agent and an adsorbent containing a reactive metal on an inorganic support. Step one removes at least 95 wt. % of the sulfur compounds while preserving at least 50 wt. % of the olefins. Treatment with the mercaptan removal agent lowers the sulfur content to 30 wppm total sulfur and final naphtha product contains leas than 10 wppm total sulfur.
摘要翻译： 从石脑油进料中除去硫的三个步骤。 所述步骤包括第一加氢处理步骤，硫醇去除剂和在无机载体上含有活性金属的吸附剂。 第一步除去至少95wt。 ％的硫化合物，同时保留至少50wt。 ％的烯烃。 用硫醇去除剂处理将硫含量降低到总硫含量为30wppm，最终石脑油产品含有超过10wppm的总硫。
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公开(公告)号：US06843905B2
公开(公告)日：2005-01-18
申请号：US10342731
申请日：2003-01-15
CPC分类号： C10G65/16
摘要： The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.
摘要翻译： 本发明涉及形成低硫汽油汽油的方法及其制成的产品。 在一个实施方案中，方法包括将催化裂化的石脑油分离成沸点低于约165°F的轻馏分和沸点高于约165°F的重馏分。通过非加氢处理方法处理轻馏分以除去硫， 并将重馏分加氢处理以将硫去除至低于约100ppm的水平。
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公开(公告)号：US06610197B2
公开(公告)日：2003-08-26
申请号：US09977000
申请日：2001-10-12
IPC分类号： C10G4500
CPC分类号： C10G65/16
摘要： The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.
摘要翻译： 本发明涉及形成低硫汽油汽油的方法及其制成的产品。 在一个实施方案中，方法包括将催化裂化的石脑油分离成沸点低于约165°F的轻馏分和沸点高于约165°F的重馏分。通过非加氢处理方法处理轻馏分以除去硫， 并将重馏分加氢处理以将硫去除至低于约100ppm的水平。
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公开(公告)号：US06489530B1
公开(公告)日：2002-12-03
申请号：US09574262
申请日：2000-05-19
申请人： Gordon F. Stuntz
发明人： Gordon F. Stuntz
IPC分类号： C07C406
摘要： A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha feedstream is contacted in the reaction zone with a catalyst under catalytic conversion concditions. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. A stream rich in C4 and/or C5 olefins is recycled to the stripping zone.
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公开(公告)号：US5198099A
公开(公告)日：1993-03-30
申请号：US743958
申请日：1991-08-12
IPC分类号： C10G65/12
CPC分类号： C10G65/12
摘要： A process for producing ultra clean distillate and naphtha products wherein a distillate boiling range stream which contains heteroatoms and aromatics to subjected to three stage processing. The first stage is conventional hydrotreating, wherein the resulting effluent is further hydrotreated, but with a noble metal zeolite catalyst which is typically used for hydrocracking. The effluent from this second stage, which is now substantially free of heteroatoms, is passed to a third stage. This third stage is a hydrocracking stage, the severity of which will determine if the ultimate product will be a distillate or a naphtha.
摘要翻译： 一种生产超清洁馏出物和石脑油产品的方法，其中含有杂原子和芳族化合物进行三段加工的馏出物沸程流。 第一阶段是常规加氢处理，其中所得流出物进一步加氢处理，但是使用通常用于加氢裂化的贵金属沸石催化剂。 现在基本上不含杂原子的来自该第二阶段的流出物被传送到第三阶段。 第三阶段是加氢裂化阶段，其严重程度将决定最终产品是馏出物还是石脑油。
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46.发明授权Fluid catalytic cracking using catalysts containing an alumina-on-silica component 失效使用含有氧化铝 - 二氧化硅组分的催化剂进行流化催化裂化
公开(公告)号：US5074990A
公开(公告)日：1991-12-24
申请号：US543503
申请日：1990-06-25
CPC分类号： B01J37/0018 , B01J21/12 , B01J37/02 , C10G11/04 , C10G11/05
摘要： Disclosed is a fluid catalytic cracking process using a catalyst composite comprised of an alumina-on-silica material, an inorganic refractory oxide, and optionally a zeolite material. The alumina-on-silica material is comprised of silica particles with surface bound aluminum groups chemically bonded to the silica surface through surface oxygen atoms, which material is dispersed in a matrix of a refractory oxide.
摘要翻译： 公开了使用由氧化铝 - 二氧化硅材料，无机耐火氧化物和任选的沸石材料组成的催化剂复合物的流化催化裂化方法。 氧化铝 - 二氧化硅材料由具有表面结合的铝基团的二氧化硅颗粒组成，其通过表面氧原子化学键合到二氧化硅表面，该材料分散在难熔氧化物的基质中。
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公开(公告)号：US5070053A
公开(公告)日：1991-12-03
申请号：US631561
申请日：1990-12-21
CPC分类号： C10G11/05 , B01J21/12 , B01J37/0018 , B01J37/02 , C10G11/04
摘要： Disclosed is a FCC catalyst composite, and a method of making said composite comprised of an alumina-on-silica additive, an inorganic refractory oxide, and optionally a zeolite material.
摘要翻译： 公开了一种FCC催化剂复合材料，以及由氧化铝 - 二氧化硅添加剂，无机难熔氧化物和任选的沸石材料制成所述复合材料的方法。
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公开(公告)号：US4504379A
公开(公告)日：1985-03-12
申请号：US525787
申请日：1983-08-23
CPC分类号： C10G11/04 , Y10S502/521
摘要： A method for passivating metal contaminants present in a hydrocarbon feedstock which become deposited on cracking catalyst is described. The method is directed at passing the cracking catalyst through a passivation zone having a reducing atmosphere maintained at an elevated temperature. The reducing atmosphere comprises a process reducing gas stream which has been passed through a guard bed adapted to selectively remove an unsaturated hydrocarbon prior to the process reducing gas being added to the passivation zone.
摘要翻译： 描述了一种钝化沉积在裂化催化剂上的烃原料中存在的金属污染物的方法。 该方法涉及使裂化催化剂通过具有保持在高温下的还原气氛的钝化区。 还原气氛包括一种工艺还原气流，其已经通过适合于选择性除去不饱和烃的保护床，在还原气体被加入钝化区之前。
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公开(公告)号：US4280896A
公开(公告)日：1981-07-28
申请号：US108396
申请日：1979-12-31
申请人： Roby Bearden , Gordon F. Stuntz
发明人： Roby Bearden , Gordon F. Stuntz
CPC分类号： B01J29/90 , B01J21/20 , C10G11/02 , C10G11/187 , Y10S502/521
摘要： A method for passivating a catalyst used to crack hydrocarbon feedstock to lower molecular weight products in a reaction zone is disclosed where the feedstock contains at least one metal contaminant selected from the class consisting of nickel, vanadium and iron and where the contaminant becomes deposited on the catalyst such that at least a major portion of the total of said metal contaminant deposited on the catalyst comprises only one of the metal contaminants. The method comprises monitoring the composition of said metal contaminant on the catalyst, adding a predetermined amount of at least one of said metal contaminants not present as the major contaminant on the catalyst, and passing the catalyst from the reaction zone through a reduction zone maintained at an elevated temperature for a time sufficient to at least partially passivate said metal contaminant.CROSS-REFERENCE TO RELATED APPLICATIONSThis application is related to U.S. Patent Application, Ser. No. 108,395 filed on even date herewith.
摘要翻译： 公开了一种用于钝化用于将烃原料裂解成反应区中较低分子量产物的催化剂的方法，其中原料含有至少一种选自镍，钒和铁的金属污染物，并且其中污染物沉积在 催化剂，使得沉积在催化剂上的所述金属杂质总量的至少大部分仅包含一种金属污染物。 该方法包括监测催化剂上所述金属污染物的组成，在催化剂上加入预定量的至少一种不作为主要污染物存在的所述金属污染物，并使催化剂从反应区通过保持在 升高的温度足以至少部分地钝化所述金属污染物的时间。
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公开(公告)号：US4280895A
公开(公告)日：1981-07-28
申请号：US108395
申请日：1979-12-31
申请人： Gordon F. Stuntz , Roby Bearden
发明人： Gordon F. Stuntz , Roby Bearden
CPC分类号： C10G11/02 , C10G11/18 , Y10S502/521
摘要： A method for passivating a catalyst utilized to crack hydrocarbon feedstock to lower molecular weight products in a reation zone is disclosed, where the feedstock contains at least two metal contaminants selected from the class consisting of nickel, vanadium and iron and where these contaminants become deposited on the catalyst. The method comprises passing the catalyst from the reaction zone through a reduction zone maintained at an elevated temperature for a time sufficient to at least partially passivate the catalyst.
摘要翻译： 公开了一种用于钝化用于将烃原料裂解成再生区中的较低分子量产物的催化剂的方法，其中原料含有选自镍，钒和铁中的至少两种金属污染物，并且这些污染物沉积在 催化剂。 该方法包括将催化剂从反应区通过保持在升高温度下的还原区一段足以至少部分钝化催化剂的时间。
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