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公开(公告)号：US06843905B2
公开(公告)日：2005-01-18
申请号：US10342731
申请日：2003-01-15
CPC分类号： C10G65/16
摘要： The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.
摘要翻译： 本发明涉及形成低硫汽油汽油的方法及其制成的产品。 在一个实施方案中，方法包括将催化裂化的石脑油分离成沸点低于约165°F的轻馏分和沸点高于约165°F的重馏分。通过非加氢处理方法处理轻馏分以除去硫， 并将重馏分加氢处理以将硫去除至低于约100ppm的水平。
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公开(公告)号：US06610197B2
公开(公告)日：2003-08-26
申请号：US09977000
申请日：2001-10-12
IPC分类号： C10G4500
CPC分类号： C10G65/16
摘要： The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.
摘要翻译： 本发明涉及形成低硫汽油汽油的方法及其制成的产品。 在一个实施方案中，方法包括将催化裂化的石脑油分离成沸点低于约165°F的轻馏分和沸点高于约165°F的重馏分。通过非加氢处理方法处理轻馏分以除去硫， 并将重馏分加氢处理以将硫去除至低于约100ppm的水平。
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3.发明授权Naphtha cracking and hydroprocessing process for low emissions, high octane fuels 失效用于低排放，高辛烷值燃料的石脑油裂解和加氢处理方法公开(公告)号：US06315890B1
公开(公告)日：2001-11-13
申请号：US09436660
申请日：1999-11-10
IPC分类号： C10G6904
CPC分类号： C10G51/023 , C10G57/02 , C10G69/04 , C10G69/06 , C10G2400/20
摘要： The invention is related to a two step process wherein the first step comprises cracking an olefinic naphtha resulting in a cracked product having a diminished total concentration of olefinic species. The second step comprises hydroprocessing at least a portion of the cracked product, especially a naphtha fraction, to provide a hydroprocessed cracked product having a reduced concentration of contaminant species but without a substantial octane reduction.
摘要翻译： 本发明涉及两步法，其中第一步骤包括裂化烯烃石脑油，产生具有减少的烯属物质总浓度的裂化产物。 第二步骤包括对至少一部分裂化产物，特别是石脑油馏分进行加氢处理，以提供具有降低的污染物质浓度但没有显着辛烷值降低的加氢裂化产物。
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公开(公告)号：US07799210B2
公开(公告)日：2010-09-21
申请号：US11100309
申请日：2005-04-06
IPC分类号： C10G67/02
CPC分类号： C10G67/12 , C10G45/08 , C10G67/04 , C10G67/0418 , C10G67/06 , C10G67/14 , C10G2400/02
摘要： A three-step process of removing sulfur from naphtha feeds. The steps include a first hydrotreating step, a mercaptan removal agent and an adsorbent containing a reactive metal on an inorganic support. Step one removes at least 95 wt. % of the sulfur compounds while preserving at least 50 wt. % of the olefins. Treatment with the mercaptan removal agent lowers the sulfur content to 30 wppm total sulfur and final naphtha product contains leas than 10 wppm total sulfur.
摘要翻译： 从石脑油进料中除去硫的三个步骤。 所述步骤包括第一加氢处理步骤，硫醇去除剂和在无机载体上含有活性金属的吸附剂。 第一步除去至少95wt。 ％的硫化合物，同时保留至少50wt。 ％的烯烃。 用硫醇去除剂处理将硫含量降低到总硫含量为30wppm，最终石脑油产品含有超过10wppm的总硫。
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公开(公告)号：US07422679B2
公开(公告)日：2008-09-09
申请号：US10427480
申请日：2003-05-01
申请人： Edward S. Ellis , Thomas R. Halbert , Garland B. Brignac , John P. Greeley , Richard A. Demmin , Theresa A. Lalain
发明人： Edward S. Ellis , Thomas R. Halbert , Garland B. Brignac , John P. Greeley , Richard A. Demmin , Theresa A. Lalain
IPC分类号： C10G45/04
CPC分类号： C10G45/02 , B01J23/882 , B01J27/0515 , B01J37/20 , C10G2400/02
摘要： Naphtha hydrodesulfurization selectivity is increased by reducing the amount of COX (CO plus ½ CO2) in the hydrodesulfurization reaction zone to less than 100 vppm. While this is useful for non-selective hydrodesulfurization, it is particularly useful for selectively desulfurizing an olefin-containing naphtha without octane loss due to olefin saturation by hydrogenation. The COX reduction is achieved by removing COX from the treat gas before it is passed into the reaction zone.
摘要翻译： 通过将加氢脱硫反应区中的CO 2 CO 2（CO + 1/2 CO 2）的量减少到小于100vppm来增加石脑油加氢脱硫选择性。 虽然这对于非选择性加氢脱硫是有用的，但是通过氢化由于烯烃饱和而没有辛烷值损失选择性脱硫含烯烃的石脑油特别有用。 在处理气体进入反应区之前，通过从处理气体中除去CO x X而实现CO 2还原。
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6.发明授权公开(公告)号：US06913688B2
公开(公告)日：2005-07-05
申请号：US10274021
申请日：2002-10-18
申请人： John C. Coker , Garland B. Brignac , Thomas R. Halbert , John G. Matragrano , Brij Gupta , Robert C. Welch , William E. Winter, Jr.
发明人： John C. Coker , Garland B. Brignac , Thomas R. Halbert , John G. Matragrano , Brij Gupta , Robert C. Welch , William E. Winter, Jr.
CPC分类号： C10G65/04 , C10G45/08 , C10G2300/202 , C10G2300/207 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2400/02 , C10L1/06
摘要： A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically bound sulfur and olefins. The olefinic naphtha stream is selectively hydrodesulfurized in a first sulfur removal stage and resulting product stream, which contains hydrogen sulfide and organosulfur is fractionated at a temperature to produce a light fraction containing less than about 100 wppm organically bound sulfur and a heavy fraction containing greater than about 100 wppm organically bound sulfur. The light fraction is stripped of at least a portion ofits hydrogen sulfide and can be collected or passed to gasoline blending. The heavy fraction is passed to a second sulfur removal stage wherein at least a portion of any remaining organically bound sulfur is removed.
摘要翻译： 一种含有大量有机结合的硫和烯烃的烯烃石脑油流选择性加氢脱硫的方法。 烯烃石脑油流在第一个硫去除阶段中选择性加氢脱硫，并在含有硫化氢和有机硫的所得产物流在一定温度下分馏，生成含有少于约100wppm有机结合硫的轻馏分，含有大于 约100wppm有机结合硫。 将轻馏分汽提至少一部分硫化氢，并可收集或通过汽油混合。 将重馏分送至第二硫去除阶段，其中除去至少一部分剩余的有机结合的硫。
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公开(公告)号：US06596157B2
公开(公告)日：2003-07-22
申请号：US09815686
申请日：2001-03-23
申请人： Brij Gupta , John P. Greeley , Thomas R. Halbert
发明人： Brij Gupta , John P. Greeley , Thomas R. Halbert
IPC分类号： C10G6514
CPC分类号： C10G65/16 , C10G45/00 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2400/02
摘要： The invention relates to a method and dual reactor system for hydrotreating a wide cut cat naphtha stream comprising heavy cat naphtha (HCN) and intermediate cat naphtha (ICN). Accordingly, a HCN fraction is hydrotreated under non-selective hydrotreating conditions and an ICN fraction is hydrotreated under selective hydrotreating conditions. The hydrotreated HCN and ICN effluents may be conducted to heat exchangers to pre-heat the ICN feed, obviating the need for a furnace.
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8.发明授权Hydroconversion process with plug-flow molybdenum catalyst concentrate preparation 失效加氢转化工艺采用活塞式钼催化剂浓缩液制备
公开(公告)号：US5620591A
公开(公告)日：1997-04-15
申请号：US362072
申请日：1994-12-22
摘要： A hydroconversion process for converting a heavy hydrocarbonaceous feedstock to lower boiling products, which process involves the use of a sulfided catalyst concentrate which is prepared in a continuous plug-flow mode. The heavy hydrocarbonaceous feedstock is reacted with said catalyst concentrate in the presence of hydrogen at hydroconversion conditions.
摘要翻译： 用于将重质烃原料转化为较低沸点产物的加氢转化方法，该方法涉及使用以连续插流模式制备的硫化催化剂浓缩物。 在加氢转化条件下，氢气存在下，重烃类原料与所述催化剂浓缩物反应。
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公开(公告)号：US4997962A
公开(公告)日：1991-03-05
申请号：US202342
申请日：1988-06-06
申请人： Liwen Wei , Thomas R. Halbert , Edward I. Stiefel
发明人： Liwen Wei , Thomas R. Halbert , Edward I. Stiefel
IPC分类号： C01G47/00 , C07C211/62 , C07F13/00
CPC分类号： C01G47/006 , C07F13/005 , C01P2002/70 , C01P2002/80
摘要： According to the present invention, an improved method for preparing tetrathioperrhenate salts is provided. Basically, a water soluble, oxygen-containing rhenium compound such as rhenium oxide or a salt containing an oxyanion of rhenium, such as ReO.sub.4.sup.--, is contacted with an aqueous ammonium sulfide or polysulfide solution in the presence of a cation which is capable of forming an aqueous insoluble salt with tetrathioperrhenate.
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公开(公告)号：US4978464A
公开(公告)日：1990-12-18
申请号：US404143
申请日：1989-09-07
IPC分类号： C10M135/14 , C10M135/18 , C10M137/10 , C10M137/14 , C10M159/18 , C10N10/12 , C10N20/02 , C10N30/06 , C10N30/10
CPC分类号： C10M135/18 , C10M135/14 , C10M137/10 , C10M137/14 , C10M159/18 , C10M2219/062 , C10M2219/068 , C10M2223/045 , C10M2223/06 , C10M2223/061 , C10N2210/06 , C10N2270/02
摘要： A lubricating oil composition is provided which comprises a major amount of an oil of lubricating viscosity and a minor amount of an additive having the formula Mo.sub.4 S.sub.4 L.sub.6 in which L is a ligand selected from dithiocarbamates, dithiophosphates, dithiophosphinates, thioxanthates, and mixtures thereof and in which the ligands, L, have organo groups having a sufficient number of carbon atoms to render the additive soluble in the oil. In general, the organo groups of the ligands, L, will be the same, although they may be different and they preferably are selected from alkyl, aryl, substituted aryl and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.
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