Process for treating aminosilane discolorations
    41.
    发明授权
    Process for treating aminosilane discolorations 失效
    处理氨基硅烷变色的方法

    公开(公告)号:US06696587B2

    公开(公告)日:2004-02-24

    申请号:US10234385

    申请日:2002-09-05

    申请人: Peter Jenkner

    发明人: Peter Jenkner

    IPC分类号: C07F710

    摘要: A discoloration of an aminosilane having a content of a free base is treated by adding an acid chloride to the aminosilane to obtain a mixture having a molar excess of acid chloride; neutralizing the molar excess of the acid chloride in one or more steps with a molar deficit of a base to obtain a mixture containing a salt; separating off the salt from; and irradiating the remaining aminosilane with UV-containing light.

    摘要翻译: 通过向氨基硅烷中加入酰氯处理具有游离碱含量的氨基硅烷的变色,得到摩尔过量的酰氯的混合物; 在一个或多个步骤中中和摩尔过量的酰基氯以摩尔缺乏碱,得到含有盐的混合物; 将盐分离; 并用含有UV的光照射剩余的氨基硅烷。

    Process for producing surface-sealed hollow glass containers having a high use strength
    42.
    发明授权
    Process for producing surface-sealed hollow glass containers having a high use strength 失效
    具有高使用强度的表面密封中空玻璃容器的制造方法

    公开(公告)号:US06403175B1

    公开(公告)日:2002-06-11

    申请号:US09387721

    申请日:1999-09-01

    IPC分类号: B05D302

    摘要: A process for producing surface-sealed hollow glass containers, the hollow glass containers are, in the production process in the region of the exit from the annealing lehr which is located downstream of a machine for producing hollow glass containers, coated by means of a water-based cold end coating composition comprising at least the following components: I. a trialkoxysilane, a dialkoxysilane and/or a tetralkoxysilane or their hydrolysis and/or condensation products and also II. a water-soluble or water-dispersible mixture of a polyol and a crosslinker, wherein the applied layer of the cold end coating composition is subsequently subjected to a crosslinking step. The hollow glass containers produced in this way have an improved strength.

    摘要翻译: 一种生产表面密封的中空玻璃容器的方法,该中空玻璃容器在退火退火炉出口区域的生产过程中,该退火炉是位于用于制造中空玻璃容器的机器的下游,用水 的冷端涂料组合物,其至少包含以下组分:I。 三烷氧基硅烷,二烷氧基硅烷和/或四氮烷氧基硅烷或其水解和/或缩合产物,以及II。 多元醇和交联剂的水溶性或水分散性混合物,其中冷端涂料组合物的涂覆层随后进行交联步骤。 以这种方式生产的中空玻璃容器具有改进的强度。

    Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use
    45.
    发明授权
    Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use 有权
    水溶性氨基和烯基官能的有机硅氧烷的稳定组合物,其制备方法及其应用

    公开(公告)号:US06255513B1

    公开(公告)日:2001-07-03

    申请号:US09300448

    申请日:1999-04-28

    IPC分类号: C07F710

    摘要: The present invention relates to a stable composition of water-soluble organosiloxanes obtained by reacting a) a water-soluble amino-functional alkoxysilane with at least one water-insoluble alkenyl-functional alkoxysilane b) by adding water to form a mixture, and c) removing the alcohol formed during step b) from the mixture, where the amino-functional alkoxysilane and the water are used in the reaction at least in amounts such that substantially all of the alkoxy groups of the water-insoluble silane can react and such that when a resulting composition is diluted with water, essentially no alcohol is liberated by hydrolysis, and the composition, during an/or after the reaction, has a pH of from 2 to 6, the pH being preferably adjusted by adding an organic or inorganic, optionally aqueous, acid. In addition, the present invention discloses a process for the preparation of such a composition and also its use.

    摘要翻译: 本发明涉及水溶性有机硅氧烷的稳定组合物,该组合物通过使水溶性氨基官能化烷氧基硅烷与至少一种水不溶性烯基官能烷氧基硅烷b)反应而得到,所述组合物通过加入水以形成混合物,和c)除去醇 在步骤b)中形成的步骤b)中,其中氨基官能的烷氧基硅烷和水在反应中使用至少使得水不溶性硅烷的基本上所有的烷氧基基本上可以反应,并且使得当得到的组合物 用水稀释,基本上没有通过水解释出醇,并且在反应过程中或之后,组合物的pH为2-6,优选通过加入有机或无机的任选含水酸来调节pH 。 此外,本发明公开了一种制备这种组合物的方法及其用途。

    Process for controlled hydrolysis and condensation of epoxy-functional organosilanes and the cocondensation thereof with further organofunctional alkoxysilanes
    46.
    发明授权
    Process for controlled hydrolysis and condensation of epoxy-functional organosilanes and the cocondensation thereof with further organofunctional alkoxysilanes 有权
    控制水解和缩合环氧官能有机硅烷的方法及其与另外的有机官能烷氧基硅烷的共缩聚

    公开(公告)号:US08394972B2

    公开(公告)日:2013-03-12

    申请号:US12673390

    申请日:2008-06-17

    IPC分类号: C07F7/02

    CPC分类号: C08G77/08 C08G77/14

    摘要: The present invention relates to a process for performing a controlled hydrolysis and condensation of an epoxy-functional silane of the general formula I R1-SiR′m(OR)3-m (I) in which R1 is a (III) or (IV) group and R, R′ and R″ groups are the same or different and are each hydrogen (H) or a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 6 carbon atoms, A and A′ groups are the same or different and are each a bivalent alkyl group having from 1 to 10 carbon atoms, R2 groups are the same or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 20 carbon atoms, and m is 0 or 1, and optionally of at least one further organofunctional silane of the general formula II R2-SiR′n(OR)3-n (II) in which R2 is an organofunctional group as already defined above, R′ is methyl, R groups are each independently hydrogen or a linear, branched or cyclic alkyl group having from 1 to 6 carbon atoms and n is 0 or 1, where from 0.001 to ≦5 mol of water is used per mole of alkoxy function of the silanes used, no further hydrolysis or condensation catalyst is used apart from boric acid as the hydrolysis catalyst and condensation component, and the condensates formed in the reaction are based on Si—O—B— and/or Si—O—Si bonds.

    摘要翻译: 本发明涉及一种通式I R 1 -Si R'm(OR)3-m(I)的环氧官能硅烷进行受控水解和缩合的方法,其中R 1是(III)或(IV )基团,R,R'和R“基团相同或不同,各自为氢(H)或具有1至6个碳原子的直链,支链或环状,任选取代的烷基,A和A'基团为 相同或不同,各自为具有1至10个碳原子的二价烷基,R 2基团相同或不同,并且R 2为具有1至20个碳原子的直链,支链或环状的任选取代的烷基,m为 0或1,以及任选地至少一种另外的通式为R 2 -SiR'n(OR)3-n(II)的有机官能硅烷,其中R 2是如上定义的有机官能团,R'是甲基,R 基团各自独立地为氢或具有1至6个碳原子且n为0或1,w的直链,支链或环状烷基 这里为0.001至< nlE;每摩尔使用的硅烷的烷氧基官能度使用5摩尔的水,除了作为水解催化剂和缩合组分的硼酸之外不再使用进一步的水解或缩合催化剂,反应中形成的缩合物 基于Si-O-B和/或Si-O-Si键。

    Polyether-functional siloxanes, polyether siloxane-containing compositions, methods for the production thereof and use thereof
    47.
    发明授权
    Polyether-functional siloxanes, polyether siloxane-containing compositions, methods for the production thereof and use thereof 有权
    聚醚官能硅氧烷,含聚醚硅氧烷的组合物,其制备方法和用途

    公开(公告)号:US08236918B2

    公开(公告)日:2012-08-07

    申请号:US11576504

    申请日:2004-11-05

    CPC分类号: C08G77/46 A61K8/893 C08L83/12

    摘要: The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The present invention further provides aqueous and/or alcoholic compositions which comprise a polyether siloxane according to formula (I), to methods for the production of said systems, and to the use thereof.

    摘要翻译: 本发明提供通式(I)R [-O(3-h)/ 2Si(R 1)(OR)h] x]的直链,环状或支链聚醚官能的硅氧烷或聚醚官能的硅氧烷的混合物, -O(3-ij)/ 2Si(R2)(R3)i(OR)j] y,(Ⅱ)其中基团R相同或不同,R基本上为H,甲基,乙基,正丙基,异丙基, 正丁基,异丁基,叔丁基,2-甲氧基乙基或2-羟乙基,或在环状硅氧烷的情况下,可以是式(I)的甲硅烷基单元的甲硅烷基,基团R1相同或不同,R1 是式(II)的末端封闭的聚醚基团,R 4 -O [-R 5 -O] n [( - R 6)m] - (II)和基团R 2相同或不同,并且R 2是直链,支链或环状 ,可以具有取代基的碳原子数1〜18的烷基或巯基烷基或碳原子数2〜8的烯基或碳原子数2〜8的烯基或碳原子数6〜12的芳基或氨基烷基, 通式(III)H2N( CH 2)d [(NH)e(CH 2)f] g - (CH 2)3 - (III)本发明进一步提供包含根据式(I)的聚醚硅氧烷的水性和/或醇组合物, 所述系统的生产及其使用。

    PROCESS FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF EPOXY-FUNCTIONAL ORGANOSILANES AND THE COCONDENSATION THEREOF WITH FURTHER ORGANOFUNCTIONAL ALKOXYSILANES
    50.
    发明申请
    PROCESS FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF EPOXY-FUNCTIONAL ORGANOSILANES AND THE COCONDENSATION THEREOF WITH FURTHER ORGANOFUNCTIONAL ALKOXYSILANES 有权
    环氧官能有机物的控制水解和缩合方法及其与有机官能烷氧基化合物的共聚

    公开(公告)号:US20100191001A1

    公开(公告)日:2010-07-29

    申请号:US12673390

    申请日:2008-06-17

    IPC分类号: C07D303/02 C07F7/02

    CPC分类号: C08G77/08 C08G77/14

    摘要: The present invention relates to a process for performing a controlled hydrolysis and condensation of an epoxy-functional silane of the general formula I R1-SiR′m(OR)3-m (I) in which R1 is a (III) or (IV) group and R, R′ and R″ groups are the same or different and are each hydrogen (H) or a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 6 carbon atoms, A and A′ groups are the same or different and are each a bivalent alkyl group having from 1 to 10 carbon atoms, R2 groups are the same or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 20 carbon atoms, and m is 0 or 1, and optionally of at least one further organofunctional silane of the general formula II R2-SiR′n(OR)3-n (II) in which R2 is an organofunctional group as already defined above, R′ is methyl, R groups are each independently hydrogen or a linear, branched or cyclic alkyl group having from 1 to 6 carbon atoms and n is 0 or 1, where from 0.001 to ≦5 mol of water is used per mole of alkoxy function of the silanes used, no further hydrolysis or condensation catalyst is used apart from boric acid as the hydrolysis catalyst and condensation component, and the condensates formed in the reaction are based on Si—O—B— and/or Si—O—Si bonds.

    摘要翻译: 本发明涉及一种通式I R 1 -Si R'm(OR)3-m(I)的环氧官能硅烷进行受控水解和缩合的方法,其中R 1是(III)或(IV )基团,R,R'和R“基团相同或不同,各自为氢(H)或具有1至6个碳原子的直链,支链或环状,任选取代的烷基,A和A'基团为 相同或不同,各自为具有1至10个碳原子的二价烷基,R 2基团相同或不同,并且R 2为具有1至20个碳原子的直链,支链或环状的任选取代的烷基,m为 0或1,以及任选地至少一种另外的通式II的有机官能硅烷R2-SiR'n(OR)3-n(II),其中R2是如上定义的有机官能团,R'是甲基,R 基团各自独立地为氢或具有1至6个碳原子且n为0或1,w的直链,支链或环状烷基 这里为0.001至< nlE;每摩尔使用的硅烷的烷氧基官能度使用5摩尔的水,除了作为水解催化剂和缩合组分的硼酸之外不再使用进一步的水解或缩合催化剂,反应中形成的缩合物 基于Si-O-B和/或Si-O-Si键。