公开(公告)号：US06518453B1

公开(公告)日：2003-02-11

申请号：US09856479

申请日：2001-07-03

申请人： Heinz Friedrich Sutoris ,  Gerhard Wagenblast ,  Volker Schliephake ,  Jürgen Schröder ,  Klaus Joachim Müller-Engel ,  Harald Keller ,  Thomas Jaworek

发明人： Heinz Friedrich Sutoris ,  Gerhard Wagenblast ,  Volker Schliephake ,  Jürgen Schröder ,  Klaus Joachim Müller-Engel ,  Harald Keller ,  Thomas Jaworek

IPC分类号： C07C6952

CPC分类号： C07C51/64 ,  C07B63/04 ,  C07C67/62 ,  C07C57/04 ,  C07C69/54

摘要： In a process for stabilizing chemical compounds having at least one ethylenically unsaturated bond to undesired free radical polymerization, a nitroxyl radical and a chemical compound containing phosphorus in chemically bonded form are added to the unsaturated compound present as pure substance or as a component of a mixture.

公开(公告)号：US08128904B2

公开(公告)日：2012-03-06

申请号：US12013693

申请日：2008-01-14

申请人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Ulrich Cremer

发明人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Ulrich Cremer

IPC分类号： B01J23/00

CPC分类号： C01G49/009 ,  C01G49/00

摘要： A process for preparing a multielement oxide composition comprising the element iron in oxidic form, in which the source of the elemental constituent of iron used is an aqueous iron nitrate solution whose preparation comprises the melting of a solid hydrate of iron nitrate.

摘要翻译： 一种制备多元氧化物组合物的方法，其包含氧化形式的元素铁，其中所用铁的元素成分源是硝酸铁水溶液，其制备方法包括硝酸铁的固体水合物的熔融。

公开(公告)号：US20110275856A1

公开(公告)日：2011-11-10

申请号：US13093333

申请日：2011-04-25

申请人： Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

发明人： Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

IPC分类号： C07C51/16 ,  B01J35/02 ,  B01J23/888

CPC分类号： B01J37/0219 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On  (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.

摘要翻译： 一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料 通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

公开(公告)号：US07999120B2

公开(公告)日：2011-08-16

申请号：US12209594

申请日：2008-09-12

申请人： Jörg Heilek ,  Peter Schlemmer ,  Ulrich Hammon ,  Klaus Joachim Müller-Engel

发明人： Jörg Heilek ,  Peter Schlemmer ,  Ulrich Hammon ,  Klaus Joachim Müller-Engel

IPC分类号： C07D227/00 ,  C07C51/43 ,  C07C7/14

CPC分类号： B01D9/0013 ,  B01D9/0045 ,  B01D9/0063 ,  C07C51/43 ,  C07C57/04

摘要： A process for continuously removing a target product X in the form of fine crystals from a liquid phase P comprising the target product X and constituents other than the target product X by cooling suspension crystallization in the secondary chamber, into which the liquid phase P flows continuously, of an indirect heat exchanger with simultaneous continuous flow of a coolant through the primary chamber of the indirect heat exchanger and continuous withdrawal of a crystal suspension S having a degree of crystallization Y from the secondary chamber, in which the degree of crystallization Y is adjusted on the basis of a heat balance conducted continuously with the aid of a process computer.

摘要翻译： 从液相P连续除去来自包含目标产物X的液相P和除了目标产物X以外的成分的微晶形式的目标产物X的方法，通过冷却液相P连续流入的二次室中的悬浮液结晶 的间接热交换器，其通过间接热交换器的主室同时连续流动冷却剂，并且从二级室连续取出具有结晶度Y的晶体悬浮液S，其中结晶度Y被调节 基于在过程计算机的帮助下连续进行的热平衡。

公开(公告)号：US20110124834A1

公开(公告)日：2011-05-26

申请号：US12897199

申请日：2010-10-04

申请人： Jörg HEILEK ,  Dirk Litters ,  Klaus Joachim Müller-Engel

发明人： Jörg HEILEK ,  Dirk Litters ,  Klaus Joachim Müller-Engel

IPC分类号： C08F20/06 ,  C07C51/42

CPC分类号： C07C51/43 ,  C07C51/47 ,  C07C57/04

摘要： A process for starting up a separating process for purifying removal of acrylic acid crystals from a suspension S of crystals thereof in mother liquor with a hydraulic wash column which has a crystal melt circuit including crystal melt space, and a process space and a distributor space which are separated by an end with passages connecting the two spaces, in which the crystal bed is formed for the first time by first filling the crystal melt circuit and, at least partly, the process space with an acrylic acid-comprising startup liquid whose acrylic acid crystal formation temperature is less than or equal to the temperature of the suspension S increased by 15° C., and then continuing the filling of the wash column with the suspension S and optionally with control liquor until the difference between the pressure in the crystal melt space and the pressure in the distributor space falls suddenly, the arithmetic mean of the total waste liquor flow flowing through the filters of the filter tubes of the wash column until this time, based on the area of all filters, being not more than 80 m3/(m2·h).

摘要翻译： 一种用于利用具有包括晶体熔融空间的晶体熔融回路的液压洗涤柱从母液中的晶体悬浮液S中纯化除去丙烯酸晶体的分离过程的工艺，以及工艺空间和分配器空间， 通过连接两个空间的通道分开一端，其中通过首先填充晶体熔融回路并且至少部分地与包含丙烯酸的启动液体的工艺空间首次形成晶体床，其中丙烯酸 晶体形成温度小于或等于悬浮液S的温度升高15℃，然后用悬浮液S和任选地与对照液体继续填充洗涤柱，直到晶体熔体中的压力差 空间和分配器空间中的压力突然下降，流过滤器过滤器的总废液流的算术平均值 根据所有过滤器的面积，直到此时为止，洗涤塔的管子不超过80立方米/（m2·h）。

公开(公告)号：US20100152482A1

公开(公告)日：2010-06-17

申请号：US12634143

申请日：2009-12-09

申请人： Volker Schliephake ,  Thorsten Friese ,  Klaus Bott ,  Michael Blechschmitt ,  Till Blum ,  Klaus Joachim Müller-Engel

发明人： Volker Schliephake ,  Thorsten Friese ,  Klaus Bott ,  Michael Blechschmitt ,  Till Blum ,  Klaus Joachim Müller-Engel

IPC分类号： C07C69/54

CPC分类号： C07C51/42 ,  C07C57/04

摘要： A process for redissociating Michael adducts which are present in a liquid F with a proportion by weight of ≧10% by weight and have been formed in the preparation of acrylic acid or esters thereof in a redissociating apparatus which comprises a pump P, a separating column K with separating internals and a circulation heat exchanger UW, wherein, for the purpose of supplying the cleavage energy, the pump P sucks in bottoms liquid from the bottom space of the separating column K and, via the circulation heat exchanger UW, continually recycles it into the bottom space above the level of the bottoms liquid, and wherein the pump P is a radial circulation pump with an open impeller.

摘要翻译： 一种将重量分数为10重量％存在于液体F中的迈克尔加合物重新分离并在制备丙烯酸或其酯的反分离装置中形成的方法，该方法包括泵P，分离塔 K具有分离内部件和循环换热器UW，其中为了提供切割能量，泵P从分离塔K的底部空间吸入液体的底部，并且通过循环热交换器UW连续地再循环 进入底部液面高度的底部空间，并且其中泵P是具有开放式叶轮的径向循环泵。

公开(公告)号：US20100069660A1

公开(公告)日：2010-03-18

申请号：US12557021

申请日：2009-09-10

申请人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Jochen Petzoldt ,  Ulrich Cremer

发明人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Jochen Petzoldt ,  Ulrich Cremer

IPC分类号： B01J21/06 ,  C07C45/27 ,  C07C255/00

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/34 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [BiaZ1bOx]p[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy]1, in which a finely divided oxide BiaZ1bOx and, formed from element sources, a finely divided mixture of stoichiometry BicMo12FedZ2eZ3fZ4gZ5hZ6i are mixed in a ratio of p:1, this mixture is used to form shaped bodies and these are treated thermally, where 0

摘要翻译： 用于生产几何形状的催化剂体K的方法，其活性材料是化学计量的多元素氧化物[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy] 1，其中细分的氧化物BiaZ1bOx和由元素源形成的细分的化学计量比BicMo 12 FedZ 2eZ 3 fZ 4 gZ 5hZ 6i的混合物混合 以p：1的比例，将该混合物用于形成成形体，并将它们热处理，其中0

公开(公告)号：US20100022734A1

公开(公告)日：2010-01-28

申请号：US12509078

申请日：2009-07-24

申请人： Till Blum ,  Peter Zurowski ,  Steffen Rissel ,  Sylke Haremza ,  Thorsten Friese ,  Ulrich Jäger ,  Volker Schliephake ,  Klaus Joachim Müller-Engel ,  Ulrich Hammon ,  Jörg Heilek ,  Imke Britta Müller

发明人： Till Blum ,  Peter Zurowski ,  Steffen Rissel ,  Sylke Haremza ,  Thorsten Friese ,  Ulrich Jäger ,  Volker Schliephake ,  Klaus Joachim Müller-Engel ,  Ulrich Hammon ,  Jörg Heilek ,  Imke Britta Müller

IPC分类号： C08F20/06 ,  B01D53/72 ,  C07C51/43

CPC分类号： C07C51/252 ,  C07C51/43 ,  C07C57/04

摘要： A process for separating acrylic acid present as a main product and glyoxal present as a by-product in a product gas mixture of a partial gas phase oxidation of a C3 precursor compound, in which a liquid phase P is obtained, which consists of acrylic acid to an extent of at least 70% of its weight and, based on the molar amount of acrylic acid present therein, comprises at least 200 molar ppm of glyoxal, in which the glyoxal is separated from the acrylic acid in the liquid phase P by crystallization.

摘要翻译： 将作为主要成分存在的丙烯酸和作为副产物存在的乙二醛的方法分离在得到液相P的C3前体化合物的部分气相氧化的产物气体混合物中，该混合物由丙烯酸 至少其重量的70％的程度，并且基于其中存在的丙烯酸的摩尔量，包含至少200摩尔ppm的乙二醛，其中通过结晶将乙二醛与液相P中的丙烯酸分离 。

公开(公告)号：US07115776B2

公开(公告)日：2006-10-03

申请号：US10460153

申请日：2003-06-13

申请人： Ulrich Hammon ,  Jochen Petzoldt ,  Klaus Joachim Müller-Engel ,  Martin Dieterle

发明人： Ulrich Hammon ,  Jochen Petzoldt ,  Klaus Joachim Müller-Engel ,  Martin Dieterle

IPC分类号： C07C51/16

CPC分类号： C07C51/252 ,  B01J8/003 ,  B01J8/008 ,  B01J8/067 ,  B01J23/002 ,  B01J2208/00707 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/04 ,  B01J2523/12 ,  B01J2523/13

摘要： A process for the heterogeneously catalyzed gas-phase partial oxidation of an organic compound over a fixed catalyst bed present in a fixed-bed reactor having a plurality of catalyst tubes, in which the reduction of the quality of the catalyst load with increasing duration of operation is restored by a partial catalyst change, is described.

摘要翻译： 存在于具有多个催化剂管的固定床反应器中的固定催化剂床上的有机化合物的非均相催化气相部分氧化的方法，其中随着操作持续时间的延长，催化剂负载的质量降低 被部分催化剂改变所恢复。

公开(公告)号：US07038082B2

公开(公告)日：2006-05-02

申请号：US10647335

申请日：2003-08-26

申请人： Frieder Borgmeier ,  Klaus Joachim Müller-Engel ,  Hartmut Hibst ,  Martin Dieterle

发明人： Frieder Borgmeier ,  Klaus Joachim Müller-Engel ,  Hartmut Hibst ,  Martin Dieterle

IPC分类号： B01J29/06

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/31 ,  B01J23/6525 ,  B01J23/8877 ,  B01J27/0576 ,  B01J35/002 ,  B01J37/0045 ,  B01J37/0223 ,  B01J2523/00 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/824 ,  B01J2523/845 ,  B01J2523/54 ,  B01J2523/44 ,  B01J2523/17 ,  B01J2523/847

摘要： A process for preparing a multimetal oxide material which contains the elements Mo, V and Te and/or Sb and at least one of the elements Nb, Ti, W, Ta and Ce and if desired promoters and has a specific X-ray diffraction pattern, in which process the last process step comprises washing with acidic liquids. In addition, a multimetal oxide material obtainable in such a way is used as a catalyst for heterogeneously catalyzed gas-phase partial oxidations and/or ammoxidation of hydrocarbons.

摘要翻译： 一种制备包含元素Mo，V和Te和/或Sb以及元素Nb，Ti，W，Ta和Ce中的至少一种的多金属氧化物材料的方法，并且如果需要的话，具有特定的X射线衍射图 ，其中最后的工艺步骤包括用酸性液体洗涤。 此外，可以以这种方式获得的多金属氧化物材料用作烃的非均相催化气相部分氧化和/或氨氧化的催化剂。