Mixture of fluorinated polyethers and use thereof as surfactant
    43.
    发明授权
    Mixture of fluorinated polyethers and use thereof as surfactant 失效
    氟化聚醚的混合物及其作为表面活性剂的用途

    公开(公告)号:US07141537B2

    公开(公告)日:2006-11-28

    申请号:US10696950

    申请日:2003-10-30

    IPC分类号: C11D17/00

    摘要: The present invention provides the use of a fluorinated polyether composition as a surfactant, said fluorinated polyether composition comprising a mixture of fluorinated polyethers of the formula: (Rf)n—Xw—Z   (I) wherein n is 1 or 2, w is 0 or 1, X is a divalent or trivalent organic linking group, Z is a polar group selected from the group consisting of an acid group or a salt thereof, an ammonium group, an amine-oxide group and an amphoteric group, and Rf represents a perfluorinated polyether group of the formula: CF3CF2CF2—O—[CF(CF3)CF2O]k—CF(CF3)— wherein k is at least 1; said mixture of fluorinated polyethers having a weight average molecular weight between 750 g/mol and 5000 g/mol and the amount of perfluorinated polyether groups in said mixture where k is 2 or less, is not more than 10% by weight of the total amount of perfluorinated polyether groups in said mixture.

    摘要翻译: 本发明提供氟化聚醚组合物作为表面活性剂的用途,所述氟化聚醚组合物包含下列化学式的氟化聚醚的混合物:<?in-line-formula description =“In-line Formulas”end =“lead”? (R>)))-X -X -X w w w <<<<<<<<<<<<<<<<<<<<<<<<<<<“”“”“”“”“”“”“”“ 其中n为1或2,w为0或1,X为二价或三价有机连接基团,Z为选自酸基或其盐的极性基团, 铵基团,氧化胺基团和两性基团,R f表示下式的全氟化聚醚基团:<?in-line-formula description =“In-line Formulas”end =“ CF 3 CF 3 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 3 > 2 -CF(CF 3) - <?in-line-formula description =“In-line Formulas”end =“tail” 其中k至少为1; 所述重均分子量在750g / mol至5000g / mol之间的所述氟化聚醚的混合物和所述混合物中的全氟化聚醚基团的量不超过总量的10重量% 的全氟化聚醚基团。

    Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith
    45.
    发明授权
    Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith 有权
    含氟化合物的氟化合物组合物和其纤维基质的处理

    公开(公告)号:US07094829B2

    公开(公告)日:2006-08-22

    申请号:US10444878

    申请日:2003-05-23

    IPC分类号: C08K3/00

    摘要: A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.

    摘要翻译: 一种氟化合物,用于使纤维基质具有防油性,防水性和/或防污性,并且包含分散在水中或溶解或分散在有机溶剂中的氟化聚合物,所述氟化聚合物包含衍生自(i)两种或 至少其分子量不同的氟化聚醚单体,具有烯属不饱和基团的氟化聚醚单体和全氟化聚醚基团,其中至少90重量%的混合物由具有全氟化聚醚基团的氟化聚醚单体组成, 至少750g / mol的分子量和(ii)一种或多种衍生自除氟化聚醚单体之外的一种或多种共聚单体的单元,其中共聚单体包含至少一种非氟化单体。 此外,用这种组合物处理纤维基材的方法,氟化聚醚单体和衍生自这些单体的氟化聚合物。

    Method of contacting hydrocarbon-bearing formations with fluorinated phosphate and phosphonate compositions
    48.
    发明授权
    Method of contacting hydrocarbon-bearing formations with fluorinated phosphate and phosphonate compositions 有权
    使含烃地层与氟化磷酸盐和膦酸盐组合物接触的方法

    公开(公告)号:US09057012B2

    公开(公告)日:2015-06-16

    申请号:US13140313

    申请日:2009-12-14

    摘要: Method comprising contacting a hydrocarbon-bearing formation with a composition comprising solvent and a fluoropolyether compound. The fluoropolyether compound: is represented by formula Rf—[C(0)-NR1—X′—(Z)m]n; or comprises at least one first divalent unit represented by formula (I) and, at least one of, a second divalent unit comprising a pendant Z group; or a monovalent unit comprising a thioether linkage and at least one terminal Z group. Each Rf is independently a fluoropolyether group. Rf is a monovalent or divalent fluoropolyether group, and each Z group is independently —P(O)(OY)2 or —O—P(O)(OY)2. Hydrocarbon-bearing formations treated according to this method are also disclosed.

    摘要翻译: 方法包括使含烃地层与包含溶剂和含氟聚醚化合物的组合物接触。 氟聚醚化合物:由式Rf- [C(O)-NR1-X' - (Z)m] n表示; 或包含至少一个由式(I)表示的第一二价单元和至少一个包含侧基Z基团的第二二价单元; 或包含硫醚键和至少一个末端Z基团的一价单元。 每个Rf独立地是氟聚醚基团。 Rf是单价或二价氟代聚醚基团,每个Z基团独立地是-P(O)(OY)2或-O-P(O)(OY)2。 还公开了根据该方法处理的含烃地层。

    TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE
    50.
    发明申请
    TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
    含有低玻璃化转变温度的氟乙烯弹性体的TRIAZINE

    公开(公告)号:US20140073737A1

    公开(公告)日:2014-03-13

    申请号:US14003141

    申请日:2012-02-24

    IPC分类号: C08L71/00 C08G65/00

    摘要: There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.

    摘要翻译: 提供了一种可固化组合物,其包含:a)具有约400g / mol至约20,000g / mol的分子量的含氟聚醚,并且含有选自( - (CF 2)4 O-),( - (CF 2) ),(-CF 2 O-)或其组合,并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b)一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂,所述残基含有至少三个碳原子,其中官能团选自伯胺,仲胺和官能团,其中 在热处理时产生伯胺或仲胺,其中组合物可以通过产生具有三嗪结构的基团来固化。 还提供固化组合物,固化组合物的制备方法,固化组合物固化的制品以及使用该可固化组合物制造制品的方法。