摘要:
A method of making a fluoropolyether elastomer containing triazine groups and having a glass transition temperature of less than −40° C., including providing (i) one or more saturated fluoropolyethers containing repeating moieties selected from (—C4F8O—), (—C3F6O—), (—C2F4O—), (—CF2O—) and combinations thereof and further containing at least one functional group at a terminal carbon atom of the backbone chain, or of a side chain if present, wherein the terminal carbon atom may be a primary or secondary carbon atom and wherein the functional group is capable of reacting with a functional group of the fluorinated compound according to (ii) below to form a triazine ring, (ii) one or more fluorinated compound containing at least one perfluorinated alkyl or perfluorinated alkylene moiety wherein the carbon atoms of the perfluorinated alkyl or alkylene moiety may be interrupted by one or more oxygen atoms and wherein the fluorinated compound further contains at least one functional group capable of reacting with the functional group of the one or more fluoropolyethers to form a triazine; curing the components according to (i) and (ii) to form triazines. Further provided are cured compositions, articles comprising the cured compositions and methods of making articles.
摘要翻译:包括制备含有三嗪基并具有小于-40℃的玻璃化转变温度的氟聚醚弹性体的方法,包括提供(i)一种或多种含有重复部分的饱和含氟聚醚,所述重复部分选自(-C 4 F 8 O - ),(-C 3 F 6 O- ),(-C 2 F 4 O-),(-CF 2 O-)及其组合,并且在主链的末端碳原子或侧链(如果存在)中还含有至少一个官能团,其中末端碳原子可以是 伯或仲碳原子,其中所述官能团能够与根据下述(ii)的氟化化合物的官能团反应以形成三嗪环,(ii)一种或多种含有至少一种全氟化烷基或全氟化的含氟化合物 亚烷基部分,其中全氟烷基或亚烷基部分的碳原子可被一个或多个氧原子间隔,并且其中所述氟化化合物还含有至少一个f 能够与一种或多种含氟聚醚的官能团反应以形成三嗪的官能团; 根据(i)和(ii)固化组分以形成三嗪。 还提供了固化组合物,包含固化组合物的制品和制造制品的方法。
摘要:
A method of making a fluoropolyether elastomer containing triazine groups and having a glass transition temperature of less than −40° C., including providing (i) one or more saturated fluoropolyethers containing repeating moieties selected from (—C4F8O—), (—C3F6O—), (—C2F4O—), (—CF2O—) and combinations thereof and further containing at least one functional group at a terminal carbon atom of the backbone chain, or of a side chain if present, wherein the terminal carbon atom may be a primary or secondary carbon atom and wherein the functional group is capable of reacting with a functional group of the fluorinated compound according to (ii) below to form a triazine ring, (ii) one or more fluorinated compound containing at least one perfluorinated alkyl or perfluorinated alkylene moiety wherein the carbon atoms of the perfluorinated alkyl or alkylene moiety may be interrupted by one or more oxygen atoms and wherein the fluorinated compound further contains at least one functional group capable of reacting with the functional group of the one or more fluoropolyethers to form a triazine; curing the components according to (i) and (ii) to form triazines. Further provided are cured compositions, articles comprising the cured compositions and methods of making articles.
摘要翻译:包括制备含有三嗪基并具有小于-40℃的玻璃化转变温度的氟聚醚弹性体的方法,包括提供(i)一种或多种含有重复部分的饱和含氟聚醚,所述重复部分选自(-C 4 F 8 O - ),(-C 3 F 6 O- ),(-C 2 F 4 O-),(-CF 2 O-)及其组合,并且在主链的末端碳原子或侧链(如果存在)中还含有至少一个官能团,其中末端碳原子可以是 伯或仲碳原子,其中所述官能团能够与根据下述(ii)的氟化化合物的官能团反应以形成三嗪环,(ii)一种或多种含有至少一种全氟化烷基或全氟化的含氟化合物 亚烷基部分,其中全氟烷基或亚烷基部分的碳原子可被一个或多个氧原子间隔,并且其中所述氟化化合物还含有至少一个f 能够与一种或多种含氟聚醚的官能团反应以形成三嗪的官能团; 根据(i)和(ii)固化组分以形成三嗪。 还提供了固化组合物,包含固化组合物的制品和制造制品的方法。
摘要:
There is provided a curable fluoroelastomer composition comprising i. a first compound which comprising repeating units derived from a fluorinated olefin and further comprising at least one functional group, ii. a second compound comprising repeating units selected from (—C4F8O—), (—C2F4O—) or (—CF2O) or a combination thereof and further containing at least one functional group capable of reacting with the at least one functional group of the first compound either directly or in the presence of a curing compound to form a triazine unit, wherein the composition after curing by forming triazine units has a glass transition temperature of less than −60° C. Also provided are shaped articles comprising the cured compositions, methods of making cured compositions and methods for making shaped articles.
摘要翻译:提供了可固化的含氟弹性体组合物,其包含i。 包含衍生自氟化烯烃的重复单元并且还包含至少一个官能团的第一化合物,ii。 包含选自(-C 4 F 8 O-),(-C 2 F 4 O-)或(-CF 2 O)的重复单元或其组合的第二化合物,并且还含有至少一个能够与第一化合物的至少一个官能团反应的官能团 直接或在固化化合物存在下形成三嗪单元,其中通过形成三嗪单元固化后的组合物具有小于-60℃的玻璃化转变温度。还提供了包含固化组合物的成型制品, 制成固化组合物和制造成型制品的方法。
摘要:
A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than −40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than −40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than −40° C.
摘要:
A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than −40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than −40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than −40° C.
摘要:
There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要:
There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要:
A method of making a fluoroelastomer composition includes curing a fluoroelastomer precursor composition under ambient pressure conditions resulting in a fluoroelastomer composition that is substantially free of surface bubbles. The fluoroelastomer precursor composition includes peroxide-curable fluoropolymer, an effective amount of peroxide consisting essentially of bis(2,4-dichlorobenzoyl) peroxide for curing the peroxide-curable fluoropolymer. The fluoroelastomer precursor composition is essentially free of non-fluorinated carbon particles. A method of making composite articles based on the method is also disclosed.
摘要:
A curable composition includes a functionalized fluoropolyether comprising at least one first free-radically reactive functional group, a functionalized polysiloxane comprising at least one second free-radically reactive functional group, and an effective amount of a free-radical curing system. The curable composition can be cured to making a fluoropolyether-polysiloxane elastomer. Compositions and shaped articles including the fluoropolyether-polysiloxane elastomer are also disclosed.