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    TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE
    4.
    发明申请
    TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
    含有低玻璃化转变温度的氟乙烯弹性体的TRIAZINE

    公开(公告)号：US20140073737A1

    公开(公告)日：2014-03-13

    申请号：US14003141

    申请日：2012-02-24

    申请人： Miguel A. Guerra ,  Rudolf J. Dams ,  Steven G. Corveleyn

    发明人： Miguel A. Guerra ,  Rudolf J. Dams ,  Steven G. Corveleyn

    IPC分类号： C08L71/00 ,  C08G65/00

    CPC分类号： C08G65/00 ,  C08G65/007 ,  C08G2650/48 ,  C08L71/00

    摘要： There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.

    摘要翻译： 提供了一种可固化组合物，其包含：a）具有约400g / mol至约20,000g / mol的分子量的含氟聚醚，并且含有选自（ - （CF 2）4 O-），（ - （CF 2） ），（-CF 2 O-）或其组合，并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b）一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂，所述残基含有至少三个碳原子，其中官能团选自伯胺，仲胺和官能团，其中 在热处理时产生伯胺或仲胺，其中组合物可以通过产生具有三嗪结构的基团来固化。 还提供固化组合物，固化组合物的制备方法，固化组合物固化的制品以及使用该可固化组合物制造制品的方法。

    TRIAZINE CONTAINING FLUOROELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE
    7.
    发明申请
    TRIAZINE CONTAINING FLUOROELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
    含有低玻璃化转变温度的含荧光物质的TRIAZINE

    公开(公告)号：US20120009438A1

    公开(公告)日：2012-01-12

    申请号：US12833522

    申请日：2010-07-09

    申请人： Rudolf J. Dams ,  Steven G. Corveleyn ,  Werner M. A. Grootaert ,  Gregg D. Dahlke ,  Miguel A. Guerra

    发明人： Rudolf J. Dams ,  Steven G. Corveleyn ,  Werner M. A. Grootaert ,  Gregg D. Dahlke ,  Miguel A. Guerra

    IPC分类号： B32B9/00 ,  C08L27/12 ,  C08F214/18

    CPC分类号： C08G65/007 ,  C08G2650/48 ,  C08L71/00 ,  C08L27/12

    摘要： There is provided a curable fluoroelastomer composition comprising i. a first compound which comprising repeating units derived from a fluorinated olefin and further comprising at least one functional group, ii. a second compound comprising repeating units selected from (—C4F8O—), (—C2F4O—) or (—CF2O) or a combination thereof and further containing at least one functional group capable of reacting with the at least one functional group of the first compound either directly or in the presence of a curing compound to form a triazine unit, wherein the composition after curing by forming triazine units has a glass transition temperature of less than −60° C. Also provided are shaped articles comprising the cured compositions, methods of making cured compositions and methods for making shaped articles.

    摘要翻译： 提供了可固化的含氟弹性体组合物，其包含i。 包含衍生自氟化烯烃的重复单元并且还包含至少一个官能团的第一化合物，ii。 包含选自（-C 4 F 8 O-），（-C 2 F 4 O-）或（-CF 2 O）的重复单元或其组合的第二化合物，并且还含有至少一个能够与第一化合物的至少一个官能团反应的官能团 直接或在固化化合物存在下形成三嗪单元，其中通过形成三嗪单元固化后的组合物具有小于-60℃的玻璃化转变温度。还提供了包含固化组合物的成型制品， 制成固化组合物和制造成型制品的方法。

    Catalyst for making fluoroelastomer compositions and methods of using the same
    8.
    发明授权
    Catalyst for making fluoroelastomer compositions and methods of using the same 失效
    制备含氟弹性体组合物的催化剂及其使用方法

    公开(公告)号：US07655591B2

    公开(公告)日：2010-02-02

    申请号：US11867969

    申请日：2007-10-05

    申请人： Werner M. A. Grootaert ,  Miguel A. Guerra

    发明人： Werner M. A. Grootaert ,  Miguel A. Guerra

    IPC分类号： B01J31/04

    CPC分类号： C07C257/06 ,  C08K5/29 ,  C08L27/12

    摘要： A catalyst is preparable from a first component represented by R′C(CF2R)O− Q+ and a second component (NCCFR″)bZ. The catalyst may be combined with a fluoropolymer having nitrogen-containing cure-sites to form a curable composition that is useful for preparing fluoroelastomer compositions.

    摘要翻译： 催化剂可由由R'C（CF2R）O-Q +和第二组分（NCCFR“）bZ表示的第一组分制备。 催化剂可与具有含氮固化位点的含氟聚合物组合以形成可用于制备含氟弹性体组合物的可固化组合物。

    Polymer electrolyte membranes crosslinked by nitrile trimerization
    9.
    发明授权
    Polymer electrolyte membranes crosslinked by nitrile trimerization 有权
    通过腈三聚交联的聚合物电解质膜

    公开(公告)号：US07435498B2

    公开(公告)日：2008-10-14

    申请号：US11419515

    申请日：2006-05-22

    申请人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    发明人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    IPC分类号： B01J39/16 ,  B01J39/18 ,  C08F12/02 ,  C08F12/20 ,  C08F14/18 ,  H01M8/10

    CPC分类号： C08J5/225 ,  C08J2327/12

    摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

    摘要翻译： 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R