Abstract:
The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises coating the water-absorbing polymer particles with at least one sulfinic acid, sulfonic acid and/or salts thereof.
Abstract:
The present invention relates to a process for producing odor-inhibiting water-absorbing composites comprising water-absorbing polymer particles and fibers, wherein the fibers are premixed with at least one metal peroxide, metal hyperoxide or metal ozonide.
Abstract:
The invention concerns water-absorbing polymeric particles possessing high saline flow conductivity in the swollen state which comprise insoluble metal sulfates as synergistic fillers, and also a process for their production and their use.
Abstract:
The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, wherein the temperature of the gas leaving the polymerization chamber is 130° C. or less, the gas velocity inside the polymerization chamber is at least 0.5 m/s, and the droplets are generated by using a droplet plate having a multitude of bores.
Abstract:
The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5. The resin powder is recycled fine-sized material for example. Not only the residual monomer content, specifically the residual crosslinker content, but also the level of extractables in the water-absorbing resin are reduced by the method of addition described. A high fraction of additives can be incorporated without the properties of the water-absorbing resin obtained being adversely affected. The additives enter a sufficiently firm bond with the resin, so that no excessive dusting occurs on exposure to mechanical stress.
Abstract:
A process for producing odor-inhibiting water-absorbing polymer particles based on ethylenically unsaturated monomer bearing acid groups, said acid groups having been neutralized to an extent of 40 to 70 mol % and the polymer particles being coated with a chelating agent.
Abstract:
A process for producing odor-inhibiting water-absorbing polymer particles based on ethylenically unsaturated monomers bearing acid groups, wherein the acid groups have been neutralized to an extent of from 40 to 70 mol % and the polymer particles are coated with a condensed tannin and/or a hydrolyzable tannin.
Abstract:
The present invention relates to a process for postcrosslinking water-absorbing polymeric particles in the absence of oxidizing gases, to the water-absorbing polymers preparable by the process and to their use in hygiene articles and packaging materials.
Abstract:
The present disclosure relates to an absorbent structure for use in a diaper for babies and infants, a feminine hygiene article and/or an incontinence article, said absorbent structure comprising a water-absorbing material, the water-absorbing material being obtainable by a process comprising the steps of A) treating a particulate, non-surface-crosslinked, water-absorbing polymer with a mixture comprising an aqueous solvent and at least one salt of a transition metal and B) irradiating the polymer treated according to A) with UV radiation, and to a process for its production.
Abstract:
(Meth)acrylate salt polymers are prepared by free-radical polymerization of (meth)acrylate salt with or without other monomers in an aqueous medium by using a supersaturated aqueous solution of (meth)acrylate salt. The resulting highly concentrated reaction mixtures are notable for their high solids content and increased space-time yield.