Thermoplastic vulcanizate compositions having improved extrusion performance and methods of formation thereof
    43.
    发明授权
    Thermoplastic vulcanizate compositions having improved extrusion performance and methods of formation thereof 有权
    具有改进挤出性能的热塑性硫化橡胶组合物及其形成方法

    公开(公告)号:US07935763B2

    公开(公告)日:2011-05-03

    申请号:US11546076

    申请日:2006-10-11

    IPC分类号: C08F8/00 C08L23/00 C08L23/04

    摘要: In one embodiment is a thermoplastic vulcanizates having improved extrusion properties formed from a composition that includes from 20% to about 80% by weight of an elastomer, from about 80% to about 20% by weight of a thermoplastic, from about 0.05 to about 12 phr of a multifunctional methacrylate monomer peroxide curing coagent; and from about 0.02 to about 6 phr of a phosphorous containing stabilizer. The resultant thermoplastic vulcanizate may be cured with a peroxide curing agent and shows improved die lip build up compared to conventionally prepared thermoplastic vulcanizates. Methods of forming thermoplastic vulcanizates having improved die lip build up are also taught.

    摘要翻译: 在一个实施方案中是具有改进挤出性能的热塑性硫化橡胶,其由组合物形成,所述组合物包含20重量%至约80重量%的弹性体,约80重量%至约20重量%的热塑性塑料,约0.05至约12重量% phr多功能甲基丙烯酸酯单体过氧化物固化助剂; 和约0.02至约6phr的含磷稳定剂。 所得到的热塑性硫化橡胶可用过氧化物固化剂固化,并且与常规制备的热塑性硫化橡胶相比显示出改善的模唇密度。 还教导了形成具有改善的模唇密度的热塑性硫化橡胶的方法。

    Thermoplastic vulcanizates having improved fabricability
    44.
    发明授权
    Thermoplastic vulcanizates having improved fabricability 有权
    具有改进的可加工性的热塑性硫化橡胶

    公开(公告)号:US07829623B2

    公开(公告)日:2010-11-09

    申请号:US11251516

    申请日:2005-10-14

    IPC分类号: C09B67/00 C08K5/00 C08L23/00

    摘要: A TPV composition having improved fabricability and surface appearance is achieved by a process for preparing a thermoplastic vulcanizate composition having a dispersed, cross-linked rubber phase in a continuous thermoplastic polypropylene phase comprising: a) providing into melt processing equipment at least the following components; i) at least one thermoplastic polypropylene homopolymer or copolymer having a melt temperature greater than 120° C.; ii) 6-12 wt. %, based on the total weight of the thermoplastic vulcanizate composition, at least one propylene copolymer having from 7 to 30 wt. % ethylene, based upon the weight of the random propylene copolymer, and a melting point less than 120° C.; iii) at least one cross-linkable rubber, where, if including an ethylene copolymer rubber, said copolymer rubber having equal to or more than 40 wt. % the total copolymer rubber weight; b) melt processing the blend of i), ii), and iii) of a); c) dynamically vulcanizing the cross-linkable rubber iii) in the presence of the thermoplastic i) and random copolymer ii); and d) removing a thermoplastic vulcanizate product of c) from the melt processing equipment, wherein the dispersed, cross-linked rubber phase of the product thermoplastic vulcanizate d) consists of particles having an effective diameter not greater than 2 millimicrons.

    摘要翻译: 具有改进的可制造性和表面外观的TPV组合物通过制备在连续热塑性聚丙烯相中具有分散的交联橡胶相的热塑性硫化橡胶组合物的方法实现,该方法包括:a)至少提供以下组分的熔融加工设备; i)至少一种熔体温度大于120℃的热塑性聚丙烯均聚物或共聚物; ii)6-12重量% %,基于热塑性硫化橡胶组合物的总重量,至少一种丙烯共聚物为7〜30wt。 %乙烯,基于无规丙烯共聚物的重量,熔点低于120℃。 iii)至少一种可交联橡胶,其中如果包括乙烯共聚物橡胶,所述共聚物橡胶具有等于或大于40wt。 总共共聚物橡胶重量% b)熔融加工a),ii)和iii)的混合物; c)在热塑性i)和无规共聚物ii)的存在下动态硫化可交联橡胶iii) 和d)从熔融加工设备中除去c)的热塑性硫化产品,其中产物热塑性硫化橡胶的分散的交联橡胶相d)由有效直径不大于2毫微子的颗粒组成。

    Polyolefin composition with high filler loading capacity
    45.
    发明授权
    Polyolefin composition with high filler loading capacity 失效
    具有高填料负载能力的聚烯烃组合物

    公开(公告)号:US07737206B2

    公开(公告)日:2010-06-15

    申请号:US11282906

    申请日:2005-11-18

    申请人: Trazollah Ouhadi

    发明人: Trazollah Ouhadi

    IPC分类号: C08K3/26

    摘要: Disclosed are highly filled thermoplastic olefin compositions and, in particular, thermoplastic olefin compositions that comprise propylene/alpha-olefin copolymers and a high level of organic or inorganic filler. Specifically, the description addresses a filled polymer composition comprising: (a) a first polymer component comprising propylene copolymer having a heat of fusion

    摘要翻译: 公开了高度填充的热塑性烯烃组合物,特别是包含丙烯/α-烯烃共聚物和高水平有机或无机填料的热塑性烯烃组合物。 具体地,该描述涉及填充的聚合物组合物,其包含:(a)第一聚合物组分,其包含熔融热<约75J / g,三单元组立构规整度为约50%至约99%的丙烯共聚物,第一聚合物组分 熔体流动速率为230℃,约800g / 10分钟。 和(b)至少约15重量%的填料,基于填充的组合物的总重量。 这样的组合物可用作声屏障,阻燃组合物,屋顶膜等。

    Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction
    46.
    发明申请
    Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction 审中-公开
    具有优异的EPDM热固性橡胶粘合性和低摩擦系数的热塑性弹性体

    公开(公告)号:US20100119855A1

    公开(公告)日:2010-05-13

    申请号:US12579963

    申请日:2009-10-15

    IPC分类号: B32B27/08 B29C45/16

    摘要: A thermoplastic elastomer with a low coefficient of friction and a composite structure made therefrom. The composite structure can include a first piece comprising a thermoplastic vulcanizate component and a second piece at least partially adhered to the first piece. The thermoplastic vulcanizate component includes an at least partially crosslinked rubber, a COF modifier, and a propylene-based copolymer that has (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences and (iii) a heat of fusion less than 45 J/g. The second piece includes an EPDM thermoset based component that comprises one or more thermoset ethylene copolymer rubbers.

    摘要翻译: 具有低摩擦系数和由其制成的复合结构的热塑性弹性体。 复合结构可以包括包含热塑性硫化橡胶组件的第一件和至少部分地粘附到第一件的第二件。 热塑性硫化橡胶组分包括至少部分交联的橡胶,COF改性剂和丙烯基共聚物,其具有(i)60重量%或更多来自丙烯的单元,(ii)等规排列的丙烯衍生的顺序和(iii) 熔化热小于45J / g。 第二件包括基于EPDM热固性的组分,其包含一种或多种热固性乙烯共聚物橡胶。

    Thermoplastic vulcanizates having improved fabricability
    49.
    发明申请
    Thermoplastic vulcanizates having improved fabricability 有权
    具有改进的可加工性的热塑性硫化橡胶

    公开(公告)号:US20060100347A1

    公开(公告)日:2006-05-11

    申请号:US11251516

    申请日:2005-10-14

    IPC分类号: C09B67/00

    摘要: A TPV composition having improved fabricability and surface appearance is achieved by a process for preparing a thermoplastic vulcanizate composition having a dispersed, cross-linked rubber phase in a continuous thermoplastic polypropylene phase comprising: a) providing into melt processing equipment at least the following components; i) at least one thermoplastic polypropylene homopolymer or copolymer having a melt temperature greater than 120° C.; ii) 6-12 wt. %, based on the total weight of the thermoplastic vulcanizate composition, at least one propylene copolymer having from 7 to 30 wt. % ethylene, based upon the weight of the random propylene copolymer, and a melting point less than 120° C.; iii) at least one cross-linkable rubber, where, if including an ethylene copolymer rubber, said copolymer rubber having equal to or more than 40 wt. % the total copolymer rubber weight; b) melt processing the blend of i), ii), and iii) of a); c) dynamically vulcanizing the cross-linkable rubber iii) in the presence of the thermoplastic i) and random copolymer ii); and d) removing a thermoplastic vulcanizate product of c) from the melt processing equipment, wherein the dispersed, cross-linked rubber phase of the product thermoplastic vulcanizate d) consists of particles having an effective diameter not greater than 2 millimicrons.

    摘要翻译: 具有改进的可制造性和表面外观的TPV组合物通过制备在连续热塑性聚丙烯相中具有分散的交联橡胶相的热塑性硫化橡胶组合物的方法实现,该方法包括:a)至少提供以下组分的熔融加工设备; i)至少一种熔体温度大于120℃的热塑性聚丙烯均聚物或共聚物; ii)6-12重量% %,基于热塑性硫化橡胶组合物的总重量,至少一种丙烯共聚物为7〜30wt。 %乙烯,基于无规丙烯共聚物的重量,熔点低于120℃。 iii)至少一种可交联橡胶,其中如果包括乙烯共聚物橡胶,所述共聚物橡胶具有等于或大于40wt。 总共共聚物橡胶重量% b)熔融加工a),ii)和iii)的混合物; c)在热塑性i)和无规共聚物ii)的存在下动态硫化可交联橡胶iii) 和d)从熔融加工设备中除去c)的热塑性硫化产品,其中产物热塑性硫化橡胶的分散的交联橡胶相d)由有效直径不大于2毫微子的颗粒组成。