公开(公告)号：US06759165B2

公开(公告)日：2004-07-06

申请号：US09933900

申请日：2001-08-22

申请人： Shinji Tsuruta ,  Tatsuoki Kohno ,  Motoya Kanda

发明人： Shinji Tsuruta ,  Tatsuoki Kohno ,  Motoya Kanda

IPC分类号： H01M446

CPC分类号： H01M4/383 ,  H01M6/10 ,  H01M10/345 ,  Y10S420/90

摘要： A hydrogen-absorbing alloy which is excellent in stability in an aqueous solution and in mechanical pulverizability is disclosed. This hydrogen-absorbing alloy contains an alloy represented by the following general formula (I): Mg2M1y  (I) wherein M1 is at least one element selected (excluding Mg, elements which are capable of causing an exothermic reaction with hydrogen, Al and B) from elements which are incapable of causing an exothermic reaction with hydrogen; and y is defined as 1

摘要翻译： 公开了一种在水溶液中的稳定性和机械粉碎性优异的吸氢合金。 该吸氢合金含有由以下通式（I）表示的合金：其中M1是选自（不包括Mg，能够与氢，Al和B发生放热反应的元素）中的至少一种元素， 不能引起与氢的放热反应; y定义为1

公开(公告)号：US06682609B1

公开(公告)日：2004-01-27

申请号：US09270763

申请日：1999-03-17

申请人： Shinji Tsuruta ,  Tatsuoki Kohno ,  Motoya Kanda

发明人： Shinji Tsuruta ,  Tatsuoki Kohno ,  Motoya Kanda

IPC分类号： C22C2300

CPC分类号： H01M4/383 ,  H01M6/10 ,  H01M10/345 ,  Y10S420/90

摘要： A hydrogen-absorbing alloy which is excellent in stability in an aqueous solution and in mechanical pulverizability is disclosed. This hydrogen-absorbing alloy contains an alloy represented by the following general formula (I): Mg2M1y  (I) wherein M1 is at least one element selected (excluding Mg, elements which are capable of causing an exothermic reaction with hydrogen, Al and B) from elements which are incapable of causing an exothermic reaction with hydrogen; and y is defined as 1

摘要翻译： 公开了一种在水溶液中的稳定性和机械粉碎性优异的吸氢合金。 该吸氢合金含有由以下通式（I）表示的合金：其中M1是选自（不包括Mg，能够与氢，Al和B发生放热反应的元素）中的至少一种元素， 不能引起与氢的放热反应; y定义为1

公开(公告)号：US06268084B1

公开(公告)日：2001-07-31

申请号：US09475037

申请日：1999-12-30

申请人： Hirotaka Hayashida ,  Masaaki Yamamoto ,  Hiroshi Kitayama ,  Shusuke Inada ,  Isao Sakai ,  Tatsuoki Kono ,  Hideki Yoshida ,  Takamichi Inaba ,  Motoya Kanda

发明人： Hirotaka Hayashida ,  Masaaki Yamamoto ,  Hiroshi Kitayama ,  Shusuke Inada ,  Isao Sakai ,  Tatsuoki Kono ,  Hideki Yoshida ,  Takamichi Inaba ,  Motoya Kanda

IPC分类号： H01M458

CPC分类号： H01M2/0285 ,  H01M2/022 ,  H01M4/383 ,  H01M10/345 ,  H01M2010/4292 ,  Y10S420/90

摘要： There is provided a hydrogen-absorbing alloy comprising, as a principal phase, at least one kind of phase selected from the group consisting of a first phase having a hexagonal crystal system (excluding a phase having a CaCu5 type crystal structure) and a second phase having a rhombohedral crystal system, the hydrogen-absorbing alloy having a composition represented by the following general formula (1): R1−a−bMgaTbNiZ−X−Y−&agr;M1XM2YMn60   (1) wherein R is at least one kind of element selected from rare earth elements (which include Y), T is at least one element selected from the group consisting of Ca, Ti, Zr and Hf, M1 is at least one element selected from the group consisting of Co and Fe, M2 is at least one element selected from the group consisting of Al, Ga, Zn, Sn, Cu, Si, B, Nb, W, Mo, V, Cr, Ta, Li, P and S, and the atomic ratios of a, b, X, Y, &agr; and Z are respectively a number satisfying the conditions of: 0.15≦a≦0.37, 0≦b≦0.3, 0≦X≦1.3, 0≦Y≦0.5, 0≦&agr;≦0.135, and 2.5≦Z≦4.2.

摘要翻译： 提供一种吸氢合金，其包含作为主相的至少一种相，其选自具有六方晶系的第一相（不包括具有CaCu 5型晶体结构的相）和第二相 具有菱方晶系的吸氢合金具有由以下通式（1）表示的组成：其中R是选自稀土元素（包括Y）中的至少一种元素，T是至少一种元素 选自由Ca，Ti，Zr和Hf组成的组，M1是选自Co和Fe中的至少一种元素，M2是选自Al，Ga，Zn，Sn， Cu，Si，B，Nb，W，Mo，V，Cr，Ta，Li，P和S，a，b，X，Y，α和Z的原子比分别为满足以下条件的数：0.15 <= a <= 0.37,0 <= b <= 0.3,0 <= X <= 1.3,0 <= Y <= 0.5,0 <=α<= 0.135和2.5 <= Z <= 4.2。

公开(公告)号：US06200705B1

公开(公告)日：2001-03-13

申请号：US09200890

申请日：1998-11-27

申请人： Hirotaka Hayashida ,  Hiroshi Kitayama ,  Masaaki Yamamoto ,  Shusuke Inada ,  Isao Sakai ,  Tatsuoki Kono ,  Hideki Yoshida ,  Takamichi Inaba ,  Motoya Kanda

发明人： Hirotaka Hayashida ,  Hiroshi Kitayama ,  Masaaki Yamamoto ,  Shusuke Inada ,  Isao Sakai ,  Tatsuoki Kono ,  Hideki Yoshida ,  Takamichi Inaba ,  Motoya Kanda

IPC分类号： H01M466

CPC分类号： H01M4/242 ,  H01M2010/4292

摘要： A nickel-hydrogen secondary battery having a negative electrode comprising a hydrogen-absorbing alloy containing magnesium, a rare earth element and nickel as essential elements, which is capable of suppressing the self-discharge being occurred under the condition of high temperature storage, or the like. This secondary battery comprises a negative electrode containing a hydrogen-absorbing alloy, a positive electrode containing nickel hydroxide, a separator comprising a non-woven fabric, and an alkaline electrolyte. The hydrogen-absorbing alloy is represented by (R1−xMgx)NiyAz (wherein R is at least one element selected from rare earth elements (including yttrium), Ca, Zr and Ti, A is at least one element selected from Co, Mn, Fe, V, Cr, Nb, Al, Ga, Zn, Sn, Cu, Si, P and B), and x, y and z are atomic ratio individually defined as 0

摘要翻译： 一种具有负极的镍氢二次电池，其具有包含镁，稀土元素和镍作为必需元素的吸氢合金，其能够在高温储存条件下发生自放电，或者 喜欢。 该二次电池包括含有吸氢合金的负极，含有氢氧化镍的正极，包含无纺布的隔膜和碱性电解质。 吸氢合金由（R1-xMgx）NiyAz（其中R是选自稀土元素（包括钇），Ca，Zr和Ti中的至少一种元素）表示，A是选自Co，Mn， Fe，V，Cr，Nb，Al，Ga，Zn，Sn，Cu，Si，P和B），x，y和z分别定义为0

公开(公告)号：US6130006A

公开(公告)日：2000-10-10

申请号：US97817

申请日：1998-06-16

申请人： Tatsuoki Kohno ,  Isao Sakai ,  Masaaki Yamamoto ,  Motoya Kanda ,  Hideki Yoshida ,  Fumiyuki Kawashima ,  Takao Sawa ,  Takamichi Inaba ,  Shusuke Inada ,  Hirotaka Hayashida ,  Hiroshi Kitayama

发明人： Tatsuoki Kohno ,  Isao Sakai ,  Masaaki Yamamoto ,  Motoya Kanda ,  Hideki Yoshida ,  Fumiyuki Kawashima ,  Takao Sawa ,  Takamichi Inaba ,  Shusuke Inada ,  Hirotaka Hayashida ,  Hiroshi Kitayama

IPC分类号： C01B3/00 ,  H01M4/38 ,  H01M4/32

CPC分类号： C01B3/0057 ,  H01M4/383 ,  Y02E60/327 ,  Y10S420/90

摘要： There is provided a hydrogen-absorbing alloy which contains an alloy ingot manufactured by means of a casting or sintering method or a pulverized product of the alloy ingot, and the alloy ingot being represented by the following general formula (1),(Mg.sub.1-a-b R1.sub.a M1.sub.b)Ni.sub.z (1)wherein R1 is at least one element selected from rare earth elements (including Y), M1 is at least one element selected from elements having a larger electronegativity than that of Mg (excluding the elements of R1, Cr, Mn, Fe, Co, Cu, Zn and Ni), and a, b and z are respectively a number satisfying conditions 0.1.ltoreq.a.ltoreq.0.8, 0 0, and 3.ltoreq.z.ltoreq.3.8.

摘要翻译： 提供了一种储氢合金，其包含通过铸造或烧结方法制造的合金锭或合金锭的粉碎产物，并且合金锭由以下通式（1）表示：（Mg1-a -bR1aM1b）Niz（1）其中R1是选自稀土元素（包括Y）中的至少一种元素，M1是选自具有比Mg大的电负性的元素中的至少一种元素（不包括R1，Cr， Mn，Fe，Co，Cu，Zn和Ni），a，b和z分别是满足条件0.1 0和 3

公开(公告)号：US5432023A

公开(公告)日：1995-07-11

申请号：US238703

申请日：1994-05-05

申请人： Shuji Yamada ,  Motoya Kanda ,  Masao Yamamoto ,  Nobukazu Suzuki ,  Yoshiko Kanazawa ,  Akinori Hongu ,  Yuu Kondou ,  Ken Uchida ,  Koji Hashimoto ,  Hirokazu Niki ,  Kunihiko Sasaki ,  Shinji Tsuruta

发明人： Shuji Yamada ,  Motoya Kanda ,  Masao Yamamoto ,  Nobukazu Suzuki ,  Yoshiko Kanazawa ,  Akinori Hongu ,  Yuu Kondou ,  Ken Uchida ,  Koji Hashimoto ,  Hirokazu Niki ,  Kunihiko Sasaki ,  Shinji Tsuruta

IPC分类号： H01M4/86 ,  H01M4/92 ,  H01M8/02 ,  H01M8/04 ,  H01M8/10 ,  H01M8/24

CPC分类号： H01M8/0204 ,  H01M4/86 ,  H01M4/925 ,  H01M4/926 ,  H01M8/023 ,  H01M8/0245 ,  H01M8/0271 ,  H01M8/04156 ,  H01M8/04186 ,  H01M8/04291 ,  H01M8/1004 ,  H01M8/2455 ,  H01M8/247 ,  H01M2300/0082

摘要： In a fuel cell comprising a stack having superposed a plurality of electromotive parts composed of a fuel electrode, an oxidizing electrode, and an electrolyte layer nipped by the two electrodes and using a liquid fuel as the fuel for the fuel cell, this invention contemplates forming a liquid fuel introducing path destined to be directly exposed to the liquid fuel on terminal surfaces of the component parts of the electromotive parts in a direction perpendicular to the flow of an oxidizing gas along at least one of the outer peripheral surfaces of the stack including the terminal surface of the fuel electrode and lying parallelly to the flow of the oxidizing gas and enabling the liquid fuel in the liquid fuel introducing path to be supplied to the fuel electrodes by a capillary attraction. A fuel cell provided with means for recovery of the water produced by the cell reaction in the oxidizing electrodes is also disclosed, which fuel cell effects the removal of the water produced in the oxidizing electrodes during the operation of the fuel cell by a capillary attraction generated by two porous members, i.e. a first porous member disposed in the oxidizing electrodes and a second porous member adjoined to the first porous member and possessed of a smaller average pore diameter than the first porous member.

摘要翻译： 在包括由燃料电极，氧化电极和由两个电极夹持并且使用液体燃料作为燃料电池的燃料的电解质层组成的多个电动部分叠置的燃料电池中，本发明考虑到形成 液体燃料导入路径，其特征在于，所述液体燃料导入路径旨在直接暴露于所述电动部件的所述构成部件的端子面的液体燃料，所述液体燃料导向路径沿与所述氧化气体的流动方向垂直的方向沿着所述堆叠体的至少一个外周面， 燃料电极的端子表面并且与氧化气体的流动平行地放置，并且能够通过毛细吸引力将液体燃料引入路径中的液体燃料供应到燃料电极。 还公开了一种燃料电池，其具有用于回收由氧化电极中的电池反应产生的水的装置，该燃料电池通过产生毛细管吸引力而在燃料电池的操作期间实现氧化电极中产生的水的去除 通过两个多孔构件，即设置在氧化电极中的第一多孔构件和与第一多孔构件相邻并且具有比第一多孔构件更小的平均孔径的第二多孔构件。

公开(公告)号：US5364711A

公开(公告)日：1994-11-15

申请号：US41427

申请日：1993-03-31

申请人： Shuji Yamada ,  Motoya Kanda ,  Masao Yamamoto ,  Nobukazu Suzuki ,  Yoshiko Kanazawa ,  Akinori Hongu ,  Yuu Kondou ,  Ken Uchida ,  Koji Hasimoto ,  Hirokazu Niki ,  Kunihiko Sasaki ,  Shinji Tsuruta

发明人： Shuji Yamada ,  Motoya Kanda ,  Masao Yamamoto ,  Nobukazu Suzuki ,  Yoshiko Kanazawa ,  Akinori Hongu ,  Yuu Kondou ,  Ken Uchida ,  Koji Hasimoto ,  Hirokazu Niki ,  Kunihiko Sasaki ,  Shinji Tsuruta

IPC分类号： H01M4/86 ,  H01M4/92 ,  H01M8/02 ,  H01M8/04 ,  H01M8/10 ,  H01M8/24

CPC分类号： H01M8/0204 ,  H01M4/86 ,  H01M4/925 ,  H01M4/926 ,  H01M8/023 ,  H01M8/0245 ,  H01M8/0271 ,  H01M8/04156 ,  H01M8/04186 ,  H01M8/04291 ,  H01M8/1004 ,  H01M8/2455 ,  H01M8/247 ,  H01M2300/0082

摘要： In a fuel cell comprising a stack having superposed a plurality of electromotive parts composed of a fuel electrode, an oxidizing electrode, and an electrolyte layer nipped by the two electrodes and using a liquid fuel as the fuel for the fuel cell, this invention contemplates forming a liquid fuel introducing path destined to be directly exposed to the liquid fuel on terminal surfaces of the component parts of the electromotive parts in a direction perpendicular to the flow of an oxidizing gas along at least one of the outer peripheral surfaces of the stack including the terminal surface of the fuel electrode and lying parallelly to the flow of the oxidizing gas and enabling the liquid fuel in the liquid fuel introducing path to be supplied to the fuel electrodes by a capillary attraction. A fuel cell provided with means for recovery of the water produced by the cell reaction in the oxidizing electrodes is also disclosed, which fuel cell effects the removal of the water produced in the oxidizing electrodes during the operation of the fuel cell by a capillary attraction generated by two porous members.

摘要翻译： 在包括由燃料电极，氧化电极和由两个电极夹持并且使用液体燃料作为燃料电池的燃料的电解质层组成的多个电动部分叠置的燃料电池中，本发明考虑到形成 液体燃料导入路径，其特征在于，所述液体燃料导入路径旨在直接暴露于所述电动部件的所述构成部件的端子面的液体燃料，所述液体燃料导向路径沿与所述氧化气体的流动方向垂直的方向沿着所述堆叠体的至少一个外周面， 燃料电极的端子表面并且与氧化气体的流动平行地放置，并且能够通过毛细吸引力将液体燃料引入路径中的液体燃料供应到燃料电极。 还公开了一种燃料电池，其具有用于回收由氧化电极中的电池反应产生的水的装置，该燃料电池通过产生毛细管吸引力而在燃料电池的操作期间实现氧化电极中产生的水的去除 由两个多孔构件。

公开(公告)号：US4696873A

公开(公告)日：1987-09-29

申请号：US872844

申请日：1986-06-11

申请人： Eriko Yagasaki ,  Motoya Kanda ,  Kiyoshi Mitsuyasu ,  Yuji Sato

发明人： Eriko Yagasaki ,  Motoya Kanda ,  Kiyoshi Mitsuyasu ,  Yuji Sato

IPC分类号： B01J23/83 ,  B01J23/84 ,  B01J23/889 ,  H01M4/24 ,  H01M4/38 ,  H01M4/62 ,  H01M10/52

CPC分类号： B01J23/83 ,  B01J23/84 ,  B01J23/8892 ,  H01M4/242 ,  H01M4/383 ,  H01M4/624 ,  H01M4/625

摘要： A rechargeable electrochemical cell a positive electrode, an alkaline electrolyte and a negative electrode made mainly of a hydrogen absorbing alloy containing a mixture of at least two rare earth elements including Ce whose content relative to the total amount of rare earth elements is less than 40 wt % and is preferably 0.1 wt % to 12 wt % or in the range 0.1-8 wt %, which gives still better capacity and life characteristics. Moreover, larger capacity characteristics can be obtained if the negative electrode contains a conductive powder preferably with an average particle diameter of 10 .mu.m or less as a subsidiary material.

摘要翻译： 一种可充电电化学电池，主要由含有至少两种稀土元素的混合物的吸氢合金制成的正极，碱性电解质和负极，Ce的含量相对于稀土元素的总量小于40重量％ ％，优选为0.1重量％〜12重量％，或在0.1〜8重量％的范围内，其赋予更好的容量和寿命特性。 此外，如果负极含有优选具有10μm以下的平均粒径的导电性粉末作为辅助材料，则可以获得更大的容量特性。