Ultraviolet crosslinking pressure-sensitive adhesive composition, process for producing same, pressure-sensitive adhesive sheet and process for producing same
    42.
    发明申请
    Ultraviolet crosslinking pressure-sensitive adhesive composition, process for producing same, pressure-sensitive adhesive sheet and process for producing same 审中-公开
    紫外线交联压敏粘合剂组合物,其制造方法,压敏粘合片及其制造方法

    公开(公告)号:US20050049366A9

    公开(公告)日:2005-03-03

    申请号:US10803976

    申请日:2004-03-19

    摘要: An ultraviolet crosslinking pressure-sensitive adhesive composition showing good pressure-sensitive adhesive characteristics is obtained by using a block copolymer of styrenic polymer component and acrylic polymer component. The pressure-sensitive adhesive composition is produced by conducting living radical polymerization of styrenic monomer and acrylic monomer in a proper order in the presence of a transition metal and its ligand using a polymerization initiator to obtain a block copolymer (a) wherein at least one styrenic polymer block A and at least one acrylic polymer block B are bound to each other and mixing it with a trichloromethyl group-containing triazine derivative (b) or, alternatively, to obtain a block copolymer (a) which contains carboxy precursor groups in the acrylic polymer block B, and converting the precursor groups to carboxyl groups, before or after mixing with the component (b), by heat-treating in the presence of an acid catalyst.

    摘要翻译: 通过使用苯乙烯类聚合物组分和丙烯酸类聚合物组分的嵌段共聚物,获得显示出良好的压敏粘合剂特性的紫外线交联压敏粘合剂组合物。 通过使用聚合引发剂在过渡金属及其配位体的存在下,以适当的顺序进行苯乙烯类单体和丙烯酸类单体的活性自由基聚合,得到嵌段共聚物(a),其中至少一种苯乙烯类 聚合物嵌段A和至少一个丙烯酸类聚合物嵌段B彼此结合并与含三氯甲基的三嗪衍生物(b)混合,或者可以获得在丙烯酸中含有羧基前体基团的嵌段共聚物(a) 聚合物嵌段B,并且在与组分(b)混合之前或之后,通过在酸催化剂的存在下进行热处理将前体基团转化成羧基。

    Heat-resistant vibration-damping pressure-sensitive adhesive
composition, process for producing the same and vibration-damping
adhesive tape or sheet using the composition
    43.
    发明授权
    Heat-resistant vibration-damping pressure-sensitive adhesive composition, process for producing the same and vibration-damping adhesive tape or sheet using the composition 失效
    耐热振动阻尼压敏粘合剂组合物,其制造方法和使用该组合物的减震胶带或片材

    公开(公告)号:US5279896A

    公开(公告)日:1994-01-18

    申请号:US973697

    申请日:1992-11-09

    摘要: A vibration-damping pressure-sensitive adhesive composition containing a crosslinked structure of a copolymer comprising (A) from 75 to 92% by weight of a main monomer comprising an alkyl (meth)acrylate containing from 8 to 12 carbon atoms in the alkyl moiety thereof and (B) from 8 to 25% by weight of a carboxyl-containing monomer whose homopolymer has a glass transition temperature of 50.degree. C. or more, said crosslinked structure having a solvent-insoluble content of 80% by weight or more and a weight loss of 3% by weight or less on heating at 120.degree. C. for 240 hours, and said composition having a T-peel strength of 400 g/20 mm-width or more from a SUS plate and a loss factor of 0.05 or more at 60.degree. C. in the vicinity of 1 kHz as determined by a half-value width method. The composition exhibits satisfactory heat resistance against long-term use in high temperatures as well as satisfactory adhesion to various parts at room temperature.

    摘要翻译: 一种包含共聚物交联结构的减振压敏粘合剂组合物,其包含(A)75-92重量%的包含其烷基部分中含有8至12个碳原子的(甲基)丙烯酸烷基酯的主单体 和(B)8〜25重量%的均聚物的玻璃化转变温度为50℃以上的含羧基单体,所述交联结构的溶剂不溶成分为80重量%以上, 在120℃下加热240小时时重量减轻3重量%以下,所述组合物从SUS板的T剥离强度为400g / 20mm以上,损耗系数为0.05或 在半值宽度法确定的1kHz附近的60摄氏度以上。 该组合物在高温下表现出令人满意的长期使用耐热性以及在室温下对各种部件的令人满意的粘合性。