摘要:
Disclosed is a method for easily producing a long porous thermosetting resin sheet which has no resin coating film on the surface. Also disclosed are a porous thermosetting resin sheet produced by the method, and a composite semipermeable membrane having excellent chemical resistance and practical water permeability and salt-blocking property. The porous thermosetting resin sheet can be produced by forming a cylindrical or columnar resin block which is composed of a cured product of a thermosetting resin composition containing a thermosetting resin, a curing agent and a porogen; then forming a long thermosetting resin sheet by cutting the surface of the resin block at a certain thickness; and then removing the porogen from the thermosetting resin sheet.
摘要:
Provided are a pressure sensitive adhesive composition for optical members and a pressure sensitive adhesive composition for optical members. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.1 to 4 parts by weight of an acrylic polymer (B) having a weight-average molecular weight of 2,000 to 50,000, containing at least 70 wt % alkyl (meth)acrylate and 1 to 7 wt % unsaturated carboxylic acid as the monomer unit and having a higher carboxylic acid equivalent than that of the acrylic polymer (A), 0.01 to 1 part by weight of a silane coupling agent, and a crosslinking agent.
摘要:
The present invention provides an optical refractive index-modifying polymer composition which can efficiently modulate (change) refractive index upon light irradiation, and exhibits such high storage stability that the once modulated refractive index does not substantially change anymore upon time elapse, and the optical refractive index-modifying polymer composition comprises as a main component a polymer (A) which is a polymer of monomers including an acrylic vinyl monomer represented by the following formula (1): CH2═C(R1)—C(═O)O—R2═CH2 (1) wherein R1 represents a hydrogen atom or a methyl group, R2 represents a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, and the molecule may contain a hetero atom or a halogen atom, as an essential component and contains a remaining radical-polymerizable side-chain vinyl group in the molecule, wherein the composition comprises a thermally curable polymer (B) in an amount of 5 to 60 parts by weight per 100 parts by weight of the polymer (A).
摘要:
An ultraviolet crosslinking pressure-sensitive adhesive composition showing good pressure-sensitive adhesive characteristics is obtained by using a block copolymer of styrenic polymer component and acrylic polymer component. The pressure-sensitive adhesive composition is produced by conducting living radical polymerization of styrenic monomer and acrylic monomer in a proper order in the presence of a transition metal and its ligand using a polymerization initiator to obtain a block copolymer (a) wherein at least one styrenic polymer block A and at least one acrylic polymer block B are bound to each other and mixing it with a trichloromethyl group-containing triazine derivative (b) or, alternatively, to obtain a block copolymer (a) which contains carboxy precursor groups in the acrylic polymer block B, and converting the precursor groups to carboxyl groups, before or after mixing with the component (b), by heat-treating in the presence of an acid catalyst.
摘要:
It is an object of the present invention to provide a composite semi-permeable membrane exhibiting excellent chemical resistance and having practical water permeability and salt-blocking property, and a method for producing the same. The present invention relates to a composite semi-permeable membrane, including a porous support and a skin layer formed on a surface of the porous support, wherein the porous support contains a thermosetting resin porous sheet having a three-dimensional network structure and pores communicating with each other and wherein the thermosetting resin porous sheet has an average pore diameter of 0.01 to 0.4 μm.
摘要:
Provided is a separator for nonaqueous electrolyte electricity storage devices that includes an improved porous epoxy resin membrane. At least one compound selected from a carboxylic acid, a carboxylic acid salt, a carboxylic acid anhydride, and a carboxylic acid halide, is brought into contact with a porous epoxy resin membrane, and thus hydroxyl groups contained in the porous membrane are reacted with the compound to produce carboxylic acid ester bonds. As a result of this treatment, the amount of active hydroxyl groups present in the porous epoxy resin membrane is reduced, and the porous epoxy resin membrane becomes suitable as a separator for nonaqueous electrolyte electricity storage devices. An epoxy resin sheet yet to be made porous may be subjected to reaction with the compound.
摘要:
Provided is a porous epoxy resin sheet produced by cutting a cured epoxy resin body to a predetermined thickness, the porous epoxy resin sheet having a large surface area and a uniform in-plane pore size distribution. A method for producing a porous epoxy resin sheet, comprising forming a cylindrical or columnar cured resin body from a resin mixture containing an epoxy resin, a curing agent, and a porogen, cutting the surface of the cured resin body at a predetermined thickness to make an epoxy resin sheet, and then removing the porogen from the sheet to render the sheet porous, wherein when the cured resin body is formed from the resin mixture, curing is performed in a state where the viscosity of the mixture is at least 1,000 mPa·s.
摘要:
The present invention provides a hologram recording material which can modulate its refractive index effectively with visible light laser and is excellent also in transparency after this modulation. The present invention relates to a hologram recording material comprising a polymer (A) having a radically polymerizable side chain vinyl group in the molecule thereof, said polymer (A) being a polymer of monomers comprising as an essential component an acryl-vinyl monomer represented by the following formula (1): CH2═C(R1)C(═O)O—R2═CH2 (1) wherein R1 represents a hydrogen atom or methyl group, and R2 represents a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, which may contain hetero atoms or halogen atoms in the molecule thereof; and a photopolymerization initiation source (B) which generates an active seed by visible light, and particularly relates to a hologram recording material having the aforementioned constitution in which the aforementioned photopolymerization initiation source (B) is a photopolymerization initiator which absorbs visible light to generate an active seed or a mixture of visible light-sensitizing dye and photopolymerization initiator.
摘要:
The present invention provides a pressure sensitive adhesive composition for optical members, which is excellent in durability, re-releasability and stress relaxation, as well as a pressure sensitive adhesive composition for optical members, which hardly increases adhesion after storage for a long time and does not leave a residual adhesive on glass upon disposal or repair. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.1 to 4 parts by weight of an acrylic polymer (B) having a weight-average molecular weight of 2,000 to 50,000, containing at least 70 wt % alkyl(meth)acrylate and 1 to 7 wt % unsaturated carboxylic acid as the monomer unit and having a higher carboxylic acid equivalent than that of the acrylic polymer (A), 0.01 to 1 part by weight of a silane coupling agent, and a crosslinking agent.
摘要:
The present invention provides a method for producing a long strip-shaped porous thermosetting resin sheet free of defective portions leading to breakage. The present invention is a method for producing a porous thermosetting resin sheet, the method including the steps of cutting a hollow-cylindrical or solid-cylindrical thermosetting resin block containing a porogen into a sheet of a thermosetting resin with a predetermined thickness by bringing a cutting blade into contact with the thermosetting resin block while rotating the thermosetting resin block about a hollow cylinder axis or a solid cylinder axis; and making the resultant thermosetting resin sheet porous by removing the porogen from the thermosetting resin sheet. The cutting blade is reciprocated approximately parallel to a direction of the rotational axis of the thermosetting resin block while the cutting is being performed.