Cationically polymerizable macromolecular monomers and graft copolymers
therefrom
    41.
    发明授权
    Cationically polymerizable macromolecular monomers and graft copolymers therefrom 失效
    可阳离子聚合的大分子单体及其接枝共聚物

    公开(公告)号:US4327201A

    公开(公告)日:1982-04-27

    申请号:US199656

    申请日:1980-10-22

    摘要: The method and production of macromolecular monomers from cationically polymerizable monomers and vinyl-substituted hydrocarbon halides is disclosed. These cationically polymerizable monomers may react in the presence of a catalyst with the hydrocarbon halide to produce a macromer retaining a polymerizable headgroup. This compound may be used in a variety of copolymerization processes with a variety of copolymerizable monomers to form graft copolymers.

    摘要翻译: 公开了从阳离子聚合单体和乙烯基取代的烃卤化物制备大分子单体的方法和制备方法。 这些阳离子可聚合单体可以在催化剂存在下与烃卤化物反应,以产生保持可聚合头基的大分子单体。 该化合物可用于与多种可共聚单体的各种共聚方法中以形成接枝共聚物。

    Process to prepare polyketones
    43.
    发明授权
    Process to prepare polyketones 失效
    制备聚酮的方法

    公开(公告)号:US3984388A

    公开(公告)日:1976-10-05

    申请号:US582949

    申请日:1975-06-02

    CPC分类号: C08G67/02

    摘要: Interpolymers of carbon monoxide and alpha-olefins are prepared under substantial anhydrous conditions by employing a solvent selected from the group consisting of hexafluoroisopropanol and meta-cresol and a catalyst selected from the group consisting of nickel (II) cyanide, specified tetracyanonickelate (II) salts, and mixtures thereof.

    摘要翻译: 通过使用选自六氟异丙醇和间甲酚的溶剂和选自氰化镍(II),特定的四氰基烟酸镍(II)盐的催化剂,在大体无水条件下制备一氧化碳和α-烯烃的共聚物 ,及其混合物。

    Preparation of isobutene homo- or copolymer derivatives

    公开(公告)号:US11306161B2

    公开(公告)日:2022-04-19

    申请号:US16916611

    申请日:2020-06-30

    申请人: BASF SE

    摘要: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.