公开(公告)号：US4777247A

公开(公告)日：1988-10-11

申请号：US34870

申请日：1987-04-06

Applicant: Hermann Henk

Inventor： Hermann Henk

IPC: C09B45/14 ,  C09B62/012 ,  C09B62/095 ,  C09B62/255 ,  C09B62/335 ,  C09B62/477 ,  D06P3/10 ,  D06P3/32 ,  C09B45/18 ,  C09B45/12 ,  D06P1/10

CPC classification number: C09B62/012 ,  C09B45/14

Abstract: A dyestuff which, in the form of its free acid, corresponds to the formula ##STR1## wherein W=a direct bond or a bridge member to a C atom of the naphthalene nucleus C or the benzene nucleus A, wherein the bridge member is ##STR2## wherein R=H or C.sub.1 -C.sub.4 -alkyl,alkylene=C.sub.2 -C.sub.5 -alkylene andarylene=unsubstituted or substituted phenylene,R.sub.1, R.sub.2 and R.sub.3 =H--, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl, halogen, carboxyl, sulphonamido, nitro, alkyl or arylcarbonylamino, --SO.sub.3 H, --SO.sub.2 --CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 --CH.sub.2 --Z, whereinZ=--OSO.sub.3 H, --SSO.sub.3 H, OPO.sub.3 H.sub.2, --OCOCH.sub.3, dialkylamino, or quaternary ammoniumR.sub.4 =H or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, --OSO.sub.3 H, --SO.sub.3 H, --COOH or hydroxyl.X=a fibre-reactive radical,p=1 or 2,q=0 or 1,l, m and n=0 or 1,k=1 or 2 andMe=Cu. --

Abstract translation: 其游离酸形式的染料对应于下式：其中W =与萘核C或苯核A的C原子的直接键或桥连构件，其中桥构件为< 其中R = H或C 1 -C 4 - 烷基，亚烷基= C 2 -C 5亚烷基和亚芳基=未取代或取代的亚苯基 ，R1，R2和R3 = H + 13，C1-C4-烷基，C1-C4-烷氧基，羟基，卤素，羧基，磺酰氨基，硝基，烷基或芳基羰基氨基，-SO3H，-SO2-CH = CH2或-SO2CH2- CH2-Z，其中Z = -OSO3H，-SSO3H，OPO3H2，-OCOCH3，二烷基氨基或季铵R4 = H或未被取代或被C1-C4-烷氧基取代的C1-C4-烷基，-OSO3H，-SO3H， -COOH或羟基。 X =纤维反应性基团，p = 1或2，q = 0或1,1，m和n = 0或1，k = 1或2，Me = Cu。 - + PG，4

公开(公告)号：US4618673A

公开(公告)日：1986-10-21

申请号：US304621

申请日：1981-09-22

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/16 ,  C09B45/06 ,  D06P1/10

CPC classification number: C09B45/16

Abstract: Asymmetric 1:2 chromium complexes of the formula, ##STR1## in which A is a group of the formula ##STR2## in which X is halogen, nitro or methyl,Y is hydrogen or nitro,* designates the carbon atom bound to the azo group,each Z is halogen or nitro, both substituents being the same, each of R.sub.1 and R.sub.2, independently, is phenyl or phenyl substituted by a total of up to three substituents selected from halogen, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, nitro and cyano (maximum of two nitro and/or cyano), andM.sup..sym. is hydrogen or an equivalent of a non-chromophoric cation, with the proviso that the sulpho group is in salt form, and mixtures of two or more of such 1:2 asymmetric complexes, which complexes and mixtures are useful for dyeing nitrogen-containing organic substrates e.g., natural and synthetic polyamides such as wool, silk and nylon, polyurethanes and leather. The dyes build-up well and the obtained dyeings exhibit notable fastness to light, wet treatments, rubbing, ironing, wool chlorination, acids and alkalis and resistance to carbonization. Some of the dyes are also useful in printing lacquers and ball-point pen inks and for dyeing metals such as anodized aluminum.

Abstract translation: 不对称1：2的下式的铬配合物，其中A是式（ⅩⅩⅥ）基团，其中X是卤素，硝基或甲基，Y是氢或硝基，*表示与偶氮键合的碳原子 基团，每个Z是卤素或硝基，两个取代基相同，R 1和R 2各自独立地是苯基或被总数最多三个选自卤素，C 1-6烷基，C 1-6烷氧基，硝基的取代基取代的苯基或 氰基（最多两个硝基和/或氰基），M（+）​​是氢或非发色阳离子的当量，条件是磺基是盐形式，并且两个或更多个这样的1 ：2种不对称配合物，其复合物和混合物可用于染色含氮有机基材，例如天然和合成聚酰胺如羊毛，丝绸和尼龙，聚氨酯和皮革。 染料积聚良好，得到的染色剂具有显着的耐光牢度，湿润处理，摩擦，熨烫，羊毛氯化，酸和碱，耐碳化。 一些染料也可用于印刷漆和圆珠笔墨水和用于染色金属如阳极氧化铝。

公开(公告)号：US4594410A

公开(公告)日：1986-06-10

申请号：US409111

申请日：1982-08-18

Applicant: Reinhard Pedrazzi

Inventor： Reinhard Pedrazzi

IPC: C09B31/16 ,  C09B31/00 ,  C09B33/00 ,  C09B33/18 ,  C09B35/00 ,  C09B35/35 ,  C09B35/50 ,  C09B43/10 ,  C09B43/16 ,  C09B44/02 ,  C09B45/00 ,  C09B45/04 ,  C09B45/18 ,  C09B31/047 ,  C09B31/12 ,  C09B31/26 ,  C09B31/30 ,  C09B45/28 ,  D06P1/10

CPC classification number: C09B31/00 ,  C09B33/00 ,  C09B35/00 ,  C09B43/16 ,  C09B45/00

Abstract: Azo dyes of the formula ##STR1## and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound in metal-free or 1:1 metal complex form,each X is independently --NR.sub.2 --Q--NR.sub.3 R.sub.4 or --NR.sub.2 --Q--N.sup..sym. R.sub.5 R.sub.6 R.sub.7, whereinQ is linear or branched C.sub.2-6 alkylene or --NH--CO--CH.sub.2 --,R.sub.2 is hydrogen or C.sub.1-4 alkyl,each of R.sub.3 and R.sub.4 is independently hydrogen; C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups or --NR.sub.3 R.sub.4 is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom,each of R.sub.5 and R.sub.6 is independently C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups, andR.sub.7 is C.sub.1-4 alkyl or benzyl or ##STR2## is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom or--N.sup..sym. R.sub.5 R.sub.6 R.sub.7 is pyridinium or pyridinium substituted by 1 or 2 methyl groups,each Z.sub.1 is independently --CO--, --SO.sub.2 -- or ##STR3## wherein R.sub.1 is hydrogen or C.sub.1-4 alkyl, andY is chloro, hydroxy, amino, an aliphatic, cycloaliphatic or aromatic amino group or a saturated heterocyclic amino group in which the nitrogen atom is part of the heterocyclic ring,each Z.sub.2 is independently ##STR4## wherein R.sub.1 is hydrogen or C.sub.1-4 alkyl,m is 1, 2 or 3,n is 0, 1, 2, 3 or 4, andp is 0, 1, 2, 3 or 4,with the proviso that n+2p.gtoreq.m+1, useful for dyeing and printing cotton, paper and leather.

公开(公告)号：US4560744A

公开(公告)日：1985-12-24

申请号：US241105

申请日：1981-03-06

Applicant: Hans Baumann ,  Klaus Grychtol

Inventor： Hans Baumann ,  Klaus Grychtol

IPC: C09B45/14 ,  C09B45/16 ,  C09B55/00 ,  C09B56/02 ,  C09B45/06 ,  C09B46/00 ,  D06P1/10

CPC classification number: C09B55/001 ,  C09B45/16

Abstract: Compounds which in the form of the free acids correspond to the formula ##STR1## where A is a radical of a diazo component or of an amine,B is a radical of a coupling component or of an aldehyde,R.sup.1 is chlorine or bromine,R.sup.2 is methoxy or ethoxy,X is .dbd.N-- or .dbd.CH--,Y is --O-- or --COO-- andZ is --O-- or --NH--,are dyes which are very suitable for dyeing nylons and natural polyamides.

Abstract translation: 游离酸形式的化合物对应于式“IMAGE”，其中A是重氮组分或胺的基团，B是偶联组分或醛的基团，R 1是氯或溴，R 2 是甲氧基或乙氧基，X是=或 - = CH-，Y是-O-或-COO-，Z是-O-或-NH-，是非常适合染色尼龙和天然聚酰胺的染料。

公开(公告)号：US4525170A

公开(公告)日：1985-06-25

申请号：US496036

申请日：1983-05-19

Applicant: Paolo Balliello

Inventor： Paolo Balliello

IPC: C09B45/00 ,  C09B67/24 ,  C09B67/42 ,  D06P1/10 ,  D06P1/44 ,  D06P1/607 ,  D06P1/613 ,  D06P3/14 ,  D06P3/24 ,  D06P3/02

CPC classification number: C09B67/0072 ,  Y10S8/904 ,  Y10S8/917 ,  Y10S8/924

Abstract: The invention relates to solid formulations of metal complex dyes, which formulations are obtained by dissolving or suspending at least one metal complex dye in water with the addition of an anionic dispersant or mixture of dispersants, and 1 to 20% by weight, based on the final formulation, of a non-ionic ethylene oxide adduct having a molecular weight of 200 to 5000, and optionally further ingredients, subsequently mixing the components and spray drying the solution or suspension.Such formulations are readily wettable and have a cold water dispersibility of .gtoreq.30 g/l.

Abstract translation: 本发明涉及金属络合物染料的固体制剂，该制剂是通过将至少一种金属络合物染料溶解或悬浮在水中，通过加入阴离子分散剂或分散剂混合物，以及1-20重量％，基于 最终制剂，分子量为200至5000的非离子环氧乙烷加合物，以及任选的其它成分，随后将组分混合并喷雾干燥溶液或悬浮液。 这些制剂易于润湿，并且具有≥30g/ l的冷水分散性。

公开(公告)号：US4427585A

公开(公告)日：1984-01-24

申请号：US287020

申请日：1981-07-27

Applicant: Fabio Beffa

Inventor： Fabio Beffa

IPC: C09B45/14 ,  D06P1/10

CPC classification number: C09B45/14 ,  D06P1/10 ,  Y10S534/01

Abstract: 1:2 Metal complex dyes of formula I ##STR1## and mixtures thereof with the metal complex dyes of formulae II and III ##STR2## wherein Me is chromium or cobalt and Q.sup..sym. is a cation. The dyes and dye mixtures are suitable for dyeing and printing natural or synthetic polyamide material. Printing pastes and padding liquors prepared from these dyes or mixtures have no tendency to gel.

Abstract translation: 1：2式I的金属络合染料（I）及其与式II和III的金属络合染料的混合物其中Me是铬或钴，Q（+ ）是阳离子。 染料和染料混合物适用于染色和印刷天然或合成聚酰胺材料。 从这些染料或混合物制备的印刷浆料和填充液不会凝胶化。

公开(公告)号：US4215042A

公开(公告)日：1980-07-29

申请号：US904358

申请日：1978-05-09

Applicant: Arthur Buhler ,  Hans U. Schutz

Inventor： Arthur Buhler ,  Hans U. Schutz

IPC: C09B45/14 ,  C09B45/00 ,  C09B55/00 ,  C09B56/02 ,  D06P1/10 ,  D06P1/13 ,  D06P3/24

CPC classification number: C09B45/00 ,  C09B55/002 ,  D06P1/10 ,  D06P1/13

Abstract: The present invention relates to copper and nickel complexes of the formula ##STR1## wherein Me is copper or nickel;p is 1 or 2;E is the radical of a napthol or a phenol;R.sub.1 is hydrogen or lower alkyl;R.sub.2 is alkylene or arylene; andM is hydrogen, an alkali metal or ammonium.These dyes are suitable for dyeing and printing natural or synthetic polyamide materials; the dyeings obtained being characterized by their purity, depth, brilliance of shade, levelness and fastness properties.

Abstract translation: 本发明涉及下式的铜和镍配合物，其中Me是铜或镍; p为1或2; E是萘酚或苯酚的基团; R1是氢或低级烷基; R2是亚烷基或亚芳基; M是氢，碱金属或铵。 这些染料适用于染色和印刷天然或合成聚酰胺材料; 获得的染色的特征在于其纯度，深度，色泽亮度，水平度和坚牢度性质。

公开(公告)号：US4197087A

公开(公告)日：1980-04-08

申请号：US919676

申请日：1978-06-27

Applicant: Kazuo Ami ,  Toshiyuki Iwahana ,  Junichi Fukuoka

Inventor： Kazuo Ami ,  Toshiyuki Iwahana ,  Junichi Fukuoka

IPC: C09B67/42 ,  C09B67/46 ,  D06P1/52 ,  D06P1/10 ,  D06P1/16 ,  D06P1/41

CPC classification number: C09B67/0086 ,  C09B67/0071 ,  D06P1/525

Abstract: A dispersant-free liquid dye preparation comprising (1) a vehicle consisting of a particular water-soluble-COONH.sub.4 group-containing polymer and a water-miscible organic solvent with or without water, and (2) a water-insoluble or sparingly water-soluble dye dispersed in the vehicle. The dye preparation can be prepared simply by mixing these ingredients and grinding the mixture. Textile articles can be dyed or printed in deep and brilliant shades by using dyeing baths or printing pastes containing the liquid dye preparation.

Abstract translation: 一种无分散剂的液体染料制剂，其包含（1）由特定的含有水溶性-COONH 4基团的聚合物和具有或不具有水的水混溶性有机溶剂组成的载体，和（2）水不溶性或微量水溶性的， 可溶性染料分散在车辆中。 可以简单地通过混合这些成分并研磨混合物来制备染料制剂。 纺织制品可以通过使用含有液体染料制剂的染色浴或印刷浆料以深色和辉煌的色调染色或印刷。

公开(公告)号：US4160643A

公开(公告)日：1979-07-10

申请号：US757913

申请日：1976-12-27

Applicant: Peter Gregory

Inventor： Peter Gregory

IPC: C09B44/02 ,  C09B44/10 ,  C09B69/00 ,  C09B27/00 ,  C09B46/00 ,  D06P1/10 ,  D06P3/70

CPC classification number: C09B69/001 ,  C09B44/10 ,  Y10S8/927

Abstract: A mixture of water soluble cationic azo dyestuffs devoid of carboxylic acid or sulphonic acid groups, each dyestuff in said mixture containing at least one cyclammonium group and said dyestuffs differing only in the constitution of the said cyclammonium group, said cyclammonium group being a gamma-picolinium group in one dyestuff and a beta-picolinium group in another dyestuff in said mixture, the water-solubility of said mixture being superior to that of the individual dyestuffs, the mixture being particularly useful for the coloration of polymers and copolymers of acrylonitrile.

Abstract translation: 不含羧酸或磺酸基团的水溶性阳离子偶氮染料的混合物，所述混合物中的每种染料含有至少一种环状铵基，所述染料仅在所述环状铵基团的构成上不同，所述环状铵基团为γ-吡啶鎓 在所述混合物中的另一种染料中组合一种染料和β-吡啶鎓基团，所述混合物的水溶性优于各种染料的水溶性，该混合物特别可用于着色丙烯腈的聚合物和共聚物。

公开(公告)号：US4155903A

公开(公告)日：1979-05-22

申请号：US681966

申请日：1976-04-30

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C07F15/06 ,  C07C67/00 ,  C07C301/00 ,  C07C309/47 ,  C09B45/02 ,  C09B45/20 ,  C09B45/48 ,  D06P1/10

CPC classification number: C09B45/20 ,  C09B45/487 ,  D06P1/10

Abstract: Disclosed are homogeneous complexes of the formula ##STR1## wherein R.sub.1 is hydrogen, alkyl, phenyl or substituted phenyl, ##STR2## WHEREIN ONE Q is hydrogen and the other is sulfo, and N IS 0 OR 1 (THE SULFO GROUP BEING IN THE 5- OR 6-POSITION WHEN N IS 1),R.sub.4 is hydrogen, alkyl, alkoxy, chloro, bromo or nitro,R.sub.5 is hydrogen, alkyl, alkoxy, chloro, bromo, nitro or sulfo,With the proviso that when one of R.sub.4 and R.sub.5 is hydrogen, the other is other than hydrogen and is in the 4- or 5-position and when both are other than hydrogen, one is in the 4-position and the other is in the 5- or 6-position,One of R.sub.6 and R.sub.7 is hydrogen, chloro or nitro and the other is hydrogen, sulfamoyl or substituted sulfamoyl, and ##STR3## wherein one of R.sub.10 and R.sub.11 is hydrogen and the other is hydrogen, chloro, alkyl, alkoxy or trifluoromethyl,R.sub.12 is hydrogen or methyl,R.sub.13 is methyl, chloro or bromo, with the proviso that R.sub.12 is hydrogen when R.sub.13 is chloro or bromo,Y.sub.1 is hydrogen or acylamino,Y.sub.2 is hydrogen, alkyl, alkoxy, chloro or bromo,Y.sub.3 is hydrogen or 5- or 6-sulfamoyl, alkylsulfamoyl or hydroxyalkylsulfamoyl, andM.sup..sym. is hydrogen or a non-chromophoric cation,wherein the asterisks indicate the carbon atom attached to the azo group,with the proviso that the complex contains a single sulfamoyl or substituted sulfamoyl group and a single sulfo group which is in salt form,and mixtures of such complexes. The complexes and mixtures are useful for dyeing and printing nitrogen-containing organic substrates, for example, polyamides such as wool, silk and nylon, polyurethanes and leather.

Abstract translation: 公开了下式的均匀络合物，其中R1是氢，烷基，苯基或取代的苯基，其中一个Q是氢，另一个是磺基，N是0或1（苏联组在5 - 当N为1时，OR 6位，R 4为氢，烷基，烷氧基，氯，溴或硝基，R 5为氢，烷基，烷氧基，氯，溴，硝基或磺基， R5是氢，另一个不是氢并且在4-或5-位，当两者都不是氢时，一个在4-位，另一个在5-或6-位，其中一个 R 6和R 7是氢，氯或硝基，另一个是氢，氨磺酰基或取代的氨磺酰基，其中R 10和R 11之一是氢，另一个是氢，氯，烷基，烷氧基 或三氟甲基，R 12是氢或甲基，R 13是甲基，氯或溴，条件是当R 13是氯或溴时，R 12是氢，Y1是氢或酰基 不是，Y 2是氢，烷基，烷氧基，氯或溴，Y + HD 3是氢或5-或6-氨磺酰基，烷基氨磺酰基或羟烷基氨磺酰基，M（+）​​是氢或非发色阳离子，其中星号表示 附着于偶氮基团的碳原子，条件是络合物含有单个氨磺酰基或取代的氨磺酰基和盐形式的单个磺基，以及这些络合物的混合物。 复合物和混合物可用于染色和印刷含氮有机基材，例如聚酰胺如羊毛，丝绸和尼龙，聚氨酯和皮革。