Halogen recovery in a wet process for halogenating unsaturated isoolefin copolymer

    公开(公告)号:US11505628B2

    公开(公告)日:2022-11-22

    申请号:US17299608

    申请日:2019-12-17

    发明人: Adrian H. Murray

    摘要: A process for producing a halogenated isoolefin copolymer involves contacting an unsaturated isoolefin copolymer cement, the cement containing an unsaturated isoolefin copolymer dissolved in an organic solvent, under halogenation conditions with a halogenating agent and an aqueous solution of an organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen. The process leads to higher halogen utilization even when the cement contains significant amounts of water and without the use of an emulsifier.

    HALOGEN RECOVERY IN A WET PROCESS FOR HALOGENATING UNSATURATED ISOOLEFIN COPOLYMER

    公开(公告)号:US20220017658A1

    公开(公告)日:2022-01-20

    申请号:US17299608

    申请日:2019-12-17

    发明人: Adrian H. Murray

    IPC分类号: C08F8/22 C08F210/12

    摘要: A process for producing a halogenated isoolefin copolymer involves contacting an unsaturated isoolefin copolymer cement, the cement containing an unsaturated isoolefin copolymer dissolved in an organic solvent, under halogenation conditions with a halogenating agent and an aqueous solution of an organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen. The process leads to higher halogen utilization even when the cement contains significant amounts of water and without the use of an emulsifier.

    Copolymer having low cyclic oligomer content

    公开(公告)号:US11066498B2

    公开(公告)日:2021-07-20

    申请号:US15307111

    申请日:2015-04-28

    IPC分类号: C08F210/12

    摘要: A copolymer has low levels of cyclic oligomeric compounds, which are undesirable impurities in certain applications. The cyclic oligomeric compounds are provided in an advantageously low ratio of C21/C13 oligomers. The C13 oligomers are extractable using steam to further reduce the total amount of cyclic oligomers. A process for producing the copolymer having low levels of cyclic oligomers involves contacting at least one isoolefin monomer with at least one multiolefin and/or β-pinene monomer in the presence of at least one Lewis acid and at least one initiator in a diluent. The diluent contains a hydrofluorinated olefin (HFO) comprising at least three carbon atoms and at least three fluorine atoms. Hydrofluorinated olefins used in the present invention are better diluents for butyl slurry cationic polymerization than saturated hydrofluorocarbons.