Heat-sensitive lithographic printing plate
    541.
    发明申请
    Heat-sensitive lithographic printing plate 失效
    热敏平版印刷版

    公开(公告)号:US20040166431A1

    公开(公告)日:2004-08-26

    申请号:US10777686

    申请日:2004-02-13

    Inventor: Toshifumi Inno

    Abstract: A heat-sensitive lithographic printing plate of the present invention, which enables image recording by infrared-ray scanning exposure based on digital data and has excellent on-press developability, high resistance to scumming and a long press life, the heat-sensitive lithographic printing plate having on a support with a hydrophilic surface an image-forming layer made up of microcapsules in which a reactive group-containing hydrophobic compound is enclosed, a light-to-heat converting agent and a water-soluble compound which has a reactive group capable of reacting with the hydrophobic compound and is situated outside the microcapsules.

    Abstract translation: 本发明的热敏平版印刷版,其能够通过基于数字数据的红外线扫描曝光进行图像记录,并且具有优异的印刷显影性,高抗浮渣性和长的印刷寿命,热敏平版印刷 在具有亲水性表面的载体上具有由包含反应性基团的疏水化合物的微胶囊构成的成像层,光热转换剂和具有反应性基团的水溶性化合物 与疏水性化合物反应并位于微胶囊外部。

    Polymerizable composition
    543.
    发明申请
    Polymerizable composition 有权
    可聚合组合物

    公开(公告)号:US20040068026A1

    公开(公告)日:2004-04-08

    申请号:US10669526

    申请日:2003-09-25

    Abstract: A photo- or thermo-polymerizable composition including an alkali-soluble polymerizable polymer that contains a structure represented by the following general formula (I) on a side chain. In general formula (I), X represents a polymerizable group; A represents an alkali-soluble group; Q represents a hydrocarbon linking group or a hetero ring; Z1 and Z2 each independently represent a single bond or a hydrocarbon linking group; and P1 to P5 each independently represent a single bond, or a linking group constituted by a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a carbonyl group (>CnullO). 1

    Abstract translation: 一种含有在侧链上含有下述通式(I)表示的结构的碱溶性聚合性聚合物的光聚合性组合物。 在通式(I)中,X表示可聚合基团; A表示碱溶性基团; Q表示烃连接基或杂环; Z 1和Z 2各自独立地表示单键或烃连接基团; 和P 1至P 5各自独立地表示单键或由氢原子,氮原子,氧原子,硫原子和羰基(> C = O)构成的连接基团。

    Printing plate precursor and printing method
    544.
    发明申请
    Printing plate precursor and printing method 审中-公开
    印版前体和印刷方法

    公开(公告)号:US20040055490A1

    公开(公告)日:2004-03-25

    申请号:US10655103

    申请日:2003-09-03

    Inventor: Takeshi Sampei

    Abstract: Disclosed is a printing plate precursor comprising an aluminum support having been subjected to surface roughening treatment and then to anodizing treatment, and provided thereon, a component layer comprising an image formation layer containing heat melting particles or heat fusible particles, the support satisfying the following conditions (a) and (b): (a) a surface of the support contains a double structure with a waviness and small pits in the waviness; and (b) d1 is from 0.1 to 3 nullm, and a ratio h1/d1 is not more than 0.4, wherein d1 (nullm) represents an average aperture diameter of the small pits, and h1 (nullm) represents an average depth of the small pits.

    Abstract translation: 公开了一种印版前体,其包括已经经过表面粗糙化处理然后进行阳极氧化处理的铝载体,并且在其上提供包含含有热熔颗粒或热熔颗粒的图像形成层的组分层,所述载体满足以下条件 (a)和(b):(a)支撑体的表面包含波纹和波纹的小凹坑的双重结构; 和(b)d1为0.1〜3μm,比例h1 / d1为0.4以下,d1(mum)表示小坑的平均孔径,h1(mum)表示平均深度 小坑

    Polymerizable composition and negative-working planographic printing plate precursor using the same
    545.
    发明申请
    Polymerizable composition and negative-working planographic printing plate precursor using the same 失效
    可聚合组合物和使用其的负性平版印刷版原版

    公开(公告)号:US20040043325A1

    公开(公告)日:2004-03-04

    申请号:US10645796

    申请日:2003-08-22

    Abstract: The invention provides a polymerizable composition comprising: a binder polymer containing at least an acid group having an acid dissociation constant (pKa) of 5.5 or more and a radical addition polymerizable group, and a radical-generating compound capable of generating a radical with light or heat. Further, the invention provides a negative-working planographic printing plate precursor which has a recording layer containing the polymerizable composition. Use of the polymerizable composition of the invention provides a planographic printing plate precursor that is capable of forming high-quality images free from stains in non-image portions, and further has high strength in formed image portions and excellent printing endurance.

    Abstract translation: 本发明提供一种可聚合组合物,其包含:至少含有酸解离常数(pKa)为5.5以上的酸基和自由基加成聚合性基团的粘合剂聚合物和能够产生光的自由基的自由基产生化合物 热。 此外,本发明提供一种具有含有可聚合组合物的记录层的负性平版印刷版原版。 使用本发明的聚合性组合物提供能够形成无图像部分中的污渍的高质量图像的平版印刷版前体,并且在成像图像部分中还具有高强度和优异的印刷耐久性。

    Infrared-sensitive composition containing a metallocene derivative
    546.
    发明申请
    Infrared-sensitive composition containing a metallocene derivative 失效
    含有茂金属衍生物的红外敏感组合物

    公开(公告)号:US20040023136A1

    公开(公告)日:2004-02-05

    申请号:US10210508

    申请日:2002-08-01

    Abstract: The present invention provides an initiator system including an infrared-absorbing compound that exhibits an electronic transition band in the near-infrared region, an initiator, and a metallocene compound. Upon exposure to infrared radiation, the initiator system is capable of producing radicals sufficient to initiate a photopolymerization reaction. Suitable infrared-absorbing compounds include indocyanine dyes, for example. Trihalomethyl triazine compounds and onium compounds are suitable initiators. Suitable metallocene compounds include ferrocenes and titanocenes. The present invention also provides an infrared-sensitive composition including an ethylenically unsaturated polymerizable component, an infrared-absorbing compound that exhibits an electronic transition band in the near-infrared region, an initiator, and a metallocene compound. The infrared-sensitive composition provides improved photospeed and sensitivity in some embodiments. A printing plate precursor including an infrared-sensitive coating is also provided. The printing plate precursor exhibits enhanced shelf life in some embodiments. A method of making a printing plate precursor and a method for making a printable lithographic printing plate are further provided by the invention.

    Abstract translation: 本发明提供了包含在近红外区域呈现电子跃迁带的红外线吸收性化合物,引发剂和金属茂化合物的引发剂体系。 在暴露于红外线辐射下,引发剂体系能够产生足以引发光聚合反应的自由基。 合适的红外线吸收化合物例如包括靛蓝染料。 三卤甲基三嗪化合物和鎓化合物是合适的引发剂。 合适的茂金属化合物包括二茂铁和二茂钛。 本发明还提供了包含烯属不饱和可聚合组分,在近红外区域表现出电子跃迁带的红外线吸收化合物,引发剂和茂金属化合物的红外线敏感性组合物。 在一些实施方案中,红外敏感组合物提供改进的感光速度和灵敏度。 还提供了包括红外线感光涂层的印版前体。 在一些实施方案中,印版前体表现出增强的保存期限。 本发明还提供了一种制备印版前体的方法和制备可印版的平版印刷版的方法。

    Non-alkaline aqueous development of thermosensitive lithographic printing plates
    548.
    发明申请
    Non-alkaline aqueous development of thermosensitive lithographic printing plates 有权
    非碱性水性显影热敏平版印刷版

    公开(公告)号:US20040013968A1

    公开(公告)日:2004-01-22

    申请号:US10200279

    申请日:2002-07-22

    Abstract: Negative thermosensitive lithographic printing plates developable with a non-alkaline aqueous developer and method of developing such plates. The plate comprises on a substrate a thermosensitive layer comprising an ethylenically unsaturated monomer, a free radical initiator, and an infrared absorbing dye. The plate can be imagewise exposed with an infrared laser to cause hardening in the exposed areas and then developed with a non-alkaline aqueous developer to remove the non-exposed areas. The non-alkaline aqueous developer can be water or an aqueous solution comprising at least 60% of water and having a pH of 2.0 to 10.0.

    Abstract translation: 用非碱性水性显影剂显影的负热敏平版印刷版和显影这种印版的方法。 板在基材上包含含有烯属不饱和单体,自由基引发剂和红外吸收染料的热敏层。 该板可以用红外激光成像曝光以在暴露的区域中硬化,然后用非碱性水性显影剂显影以除去未曝光的区域。 非碱性水性显影剂可以是水或含有至少60%的水并且pH为2.0至10.0的水溶液。

    Image-recording material
    549.
    发明授权
    Image-recording material 有权
    图像记录材料

    公开(公告)号:US06653050B2

    公开(公告)日:2003-11-25

    申请号:US10080654

    申请日:2002-02-25

    Abstract: A negative image-recording material for heat-mode exposure, which is able to form images by heat-mode exposure, comprises (A) a polyurethane resin having at least one or more side-chain branches of the following general formulae (1) to (3) which polyurethane resin is soluble in an alkaline aqueous solution, (B) a photo-thermal converting agent, and (C) a compound capable of generating a radical through heat-mode exposure to light of a wavelength which can be absorbed by the photo-thermal converting agent. In formulae (1) to (3), R1 to R11 each independently represents a monovalent organic group; X and Y each independently represents an oxygen atom, a sulfur atom, or —N(R12)—; Z represents an oxygen atom, a sulfur atom, —N(R13)—, or an optionally-substituted phenylene group; R12 represents a hydrogen atom or a monovalent organic group; and R13 represents a hydrogen atom or a monovalent organic group.

    Abstract translation: 能够通过热模式曝光形成图像的用于热模式曝光的负型图像记录材料包括(A)具有至少一个或多个以下通式(1)至 (3)哪种聚氨酯树脂可溶于碱性水溶液中,(B)光热转换剂,和(C)能够通过热模式暴露于能够被 光热转换剂。 在式(1)至(3)中,R 1至R 11各自独立地表示一价有机基团; X和Y各自独立地表示氧原子,硫原子或-N(R 12) - ; Z表示氧原子,硫原子,-N(R 13) - 或任选取代的亚苯基; R 12表示氢原子或一价有机基团; R 13表示氢原子或一价有机基团。

    Method of preparation of lithographic printing plates
    550.
    发明申请
    Method of preparation of lithographic printing plates 有权
    平版印刷版的制备方法

    公开(公告)号:US20030215750A1

    公开(公告)日:2003-11-20

    申请号:US10420857

    申请日:2003-04-23

    Inventor: Toshifumi Inno

    Abstract: A method for preparation of a lithographic printing plate, which comprises the steps of: imagewise recording on a lithographic printing plate precursor comprising a support having a hydrophilic surface and a thermosensitive layer, the thermosensitive layer comprising at least one of polymer particles and a microcapsule encapsulating an oleophilic compound therein; and rubbing the printing plate precursor by a rubbing member in the presence of a processing liquid to remove the thermosensitive layer of non-image portions.

    Abstract translation: 一种制备平版印刷版的方法,其包括以下步骤:在包含具有亲水表面和热敏层的载体的平版印刷版原版上成像记录,所述热敏层包括聚合物颗粒和微胶囊中的至少一种 其中的亲油性化合物; 以及在处理液体的存在下通过摩擦部件摩擦印版前体以除去非图像部分的热敏层。

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