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    APPARATUS AND METHOD TO MEASURE ELECTROCHEMICAL IMPEDANCE
    53.
    发明申请
    APPARATUS AND METHOD TO MEASURE ELECTROCHEMICAL IMPEDANCE 审中-公开
    测量电化学阻抗的装置和方法

    公开(公告)号：US20100155262A1

    公开(公告)日：2010-06-24

    申请号：US12338061

    申请日：2008-12-18

    申请人： Omar J. Yepez ,  Bruce B. Randolph ,  Xiaoyi Gong

    发明人： Omar J. Yepez ,  Bruce B. Randolph ,  Xiaoyi Gong

    IPC分类号： G01N17/04 ,  C25B9/00

    CPC分类号： G01N17/02 ,  G01N33/2888

    摘要： An electrochemical cell apparatus and method comprising a first electrode and a second electrode wherein the area ratio between them is 15 or higher, for example a metal plate and a metal wire; wherein said first and second electrodes are made from the same material; and wherein the distance between said first electrode and said second electrode is in the range of from about 1 mm to about 1 μm is provided. Such electrochemical cell can be used to measure crude oil corrosion using an electrochemical impedance method.

    摘要翻译： 一种电化学电池装置和方法，包括第一电极和第二电极，其中它们之间的面积比例为15或更高，例如金属板和金属线; 其中所述第一和第二电极由相同的材料制成; 并且其中提供所述第一电极和所述第二电极之间的距离在约1mm至约1μm的范围内。 这种电化学电池可用于使用电化学阻抗法测量原油腐蚀。

    Alkylation process with recontacting in settler
    55.
    发明授权
    Alkylation process with recontacting in settler 有权
    烷基化过程，在沉降器中重新溶解

    公开(公告)号：US07446238B2

    公开(公告)日：2008-11-04

    申请号：US11047514

    申请日：2005-01-31

    申请人： Keith W. Hovis ,  Bruce B. Randolph

    发明人： Keith W. Hovis ,  Bruce B. Randolph

    IPC分类号： C07C2/60

    CPC分类号： C07C2/62 ,  B01J8/0453 ,  B01J19/30 ,  B01J19/32 ,  B01J2208/00884 ,  B01J2208/025 ,  B01J2219/30203 ,  B01J2219/30223 ,  B01J2219/30261 ,  B01J2219/30265 ,  B01J2219/30296 ,  C07C2527/1206

    摘要： A system and/or process for decreasing the level of at least one organic fluoride present in a hydrocarbon phase contained in an alkylation settler by contacting the hydrocarbon phase with an HF containing stream, containing greater than about 80 wt. % and less than about 94 wt. % HF, in the intermediate portion of the settler which contains at least one tray system, with each tray system comprising a perforated tray defining a plurality of perforations and a layer of packing below the perforated tray, are disclosed.

    摘要翻译： 通过使烃相与包含大于约80重量％的含HF的物流接触，降低存在于烷基化沉淀器中的烃相中存在的至少一种有机氟化物的水平的系统和/或方法。 ％且小于约94wt。 公开了在包含至少一个托盘系统的沉降器的中间部分中的HF，其中每个托盘系统包括限定多个穿孔的多孔托盘和多孔托盘下面的一层填料。

    Alkylation of isobutene feeds
    56.
    发明申请
    Alkylation of isobutene feeds 有权
    异丁烯进料的烷基化

    公开(公告)号：US20070282150A1

    公开(公告)日：2007-12-06

    申请号：US11445354

    申请日：2006-06-01

    申请人： Bruce B. Randolph ,  Keith W. Hovis ,  Kenneth C. Hoover

    发明人： Bruce B. Randolph ,  Keith W. Hovis ,  Kenneth C. Hoover

    IPC分类号： C07C2/56

    CPC分类号： C07C7/20 ,  C07C2/62 ,  C07C2527/054 ,  C07C2527/1206 ,  C07C9/16

    摘要： A process for alkylating isobutene by introducing a feed containing isobutene and an isoparaffin, in the form of droplets, into an acid catalyst to produce an alkylation product, wherein the Sauter mean diameter of the droplets is greater than or equal to about 150 μm and is less than or equal to about 500 μm, is disclosed.

    摘要翻译： 通过将含有异丁烯和异链烷烃的进料（以液滴形式）引入酸催化剂中以产生烷基化产物来烷基化异丁烯的方法，其中所述液滴的沙特平均直径大于或等于约150μm，并且是 小于或等于约500μm。

    Hydrocarbon purificatin system regeneration
    57.
    发明授权
    Hydrocarbon purificatin system regeneration 有权
    碳氢化合物净化系统再生

    公开(公告)号：US06673239B2

    公开(公告)日：2004-01-06

    申请号：US09747710

    申请日：2000-12-21

    申请人： Marvin M. Johnson ,  Bruce B. Randolph

    发明人： Marvin M. Johnson ,  Bruce B. Randolph

    IPC分类号： C10G2512

    CPC分类号： C07C7/12 ,  C07C7/13 ,  C10G25/12

    摘要： A system and process for removing water and heteroatom-containing compounds from hydrocarbons and for regenerating the adsorbent used in the system and process is disclosed and includes contacting the hydrocarbon stream with a water adsorbent and a heteroatom-containing compound adsorbent. The regeneration includes passing an isoparaffin over the water-adsorbent, then passing the isoparaffin over the heteroatom-containing compound adsorbent; and, optionally; cooling the effluent; separating such into a hydrocarbon phase and a water phase in a settler; removing a portion of the hydrocarbon phase for mixing with water; returning the hydrocarbon/water mixture to the settler; removing some of the hydrocarbon phase from the settler to form a recycle isoparaffin stream for use as a portion of the stripping stream; and removal of a portion of the water phase from the settler to form a waste water stream containing water and heteroatom-containing compound.

    摘要翻译： 公开了一种用于从烃中除去水和含杂原子的化合物和用于再生系统和方法中使用的吸附剂的系统和方法，包括使烃流与水吸附剂和含杂原子的化合物吸附剂接触。 再生包括使异链烷烃在水吸附剂上通过，然后将异链烷烃通过含杂原子的化合物吸附剂; 和，可选地; 冷却流出物; 在沉降器中将其分离成烃相和水相; 除去一部分烃相以与水混合; 将烃/水混合物返回沉降器; 从沉降器中除去一些烃相以形成用作汽提流的一部分的再循环异构烷烃流; 并从沉降器中除去一部分水相以形成含有水和含杂原子的化合物的废水流。

    Oligomerization of olefins
    58.
    发明授权
    Oligomerization of olefins 有权
    烯烃的低聚

    公开(公告)号：US06281401B1

    公开(公告)日：2001-08-28

    申请号：US09397571

    申请日：1999-09-16

    申请人： Bruce B. Randolph

    发明人： Bruce B. Randolph

    IPC分类号： C07C216

    CPC分类号： C07C2/08 ,  C07C2/26 ,  C07C2531/025

    摘要： A process for oligomerizing at least one heavy olefin having at least 5 carbon atoms per molecule in the presence of at least one co-fed light olefin having less than 5 carbon atoms per molecule is disclosed. The presence of the at least one co-fed light olefin results in increased C6=(C6 olefin) conversion (if present as one of the at least one heavy olefins), increased weight % of C11+ hydrocarbons in the C9+ material of the product and increased cetane of the C9+ material of the product as compared to the oligomerization of the at least one heavy olefin without the co-fed at least one light olefin.

    摘要翻译： 公开了在至少一种每分子具有少于5个碳原子的共同供给的轻质烯烃的存在下，使至少一种每分子具有至少5个碳原子的重质烯烃低聚的方法。 至少一种共同进料的轻质烯烃的存在导致C6 =（C6烯烃）转化率增加（如果作为至少一种重质烯烃之一存在），则C9 +材料中C11 +烃的重量％增加，以及 与没有共同进料的至少一种轻质烯烃的至少一种重质烯烃的低聚相比，产物的C9 +材料的增加的十六烷。

    Method for reducing organic fluoride levels in hydrocarbons
    59.
    发明授权
    Method for reducing organic fluoride levels in hydrocarbons 失效

    公开(公告)号：US6114593A

    公开(公告)日：2000-09-05

    申请号：US238244

    申请日：1999-01-27

    申请人： Bruce B. Randolph ,  Kenneth Charles Hoover

    发明人： Bruce B. Randolph ,  Kenneth Charles Hoover

    IPC分类号： C10G35/06 ,  C07C2/62 ,  C07C7/148 ,  C10G29/20 ,  C10G59/02 ,  C07C2/56 ,  C07C7/00 ,  C07C7/10 ,  C07C7/17 ,  C10G17/00

    CPC分类号： C10G29/205 ,  C07C2/62 ,  C07C7/148

    摘要： A system and/or process for decreasing the level of at least one organic fluoride present in a hydrocarbon mixture by first passing the hydrocarbon mixture to an eductor and educting into the hydrocarbon mixture a catalyst comprising a volatility reducing additive and hydrofluoric acid to produce a hydrocarbon-catalyst mixture, permitting the hydrocarbon-catalyst mixture to undergo a phase separation to produce a hydrocarbon phase having a lower concentration of at least one organic fluoride than the hydrocarbon mixture and to produce a catalyst phase, and withdrawing at least a portion of the hydrocarbon phase to thereby form a hydrocarbon product stream, are disclosed. In an alternate embodiment, a system and/or process for controlling the concentration of at least one organic fluoride and/or the RON of the hydrocarbon mixture by adjusting the amount of volatility reducing additive present in the catalyst are disclosed.