公开(公告)号：US20160009613A1

公开(公告)日：2016-01-14

申请号：US14770657

申请日：2014-03-06

Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

Inventor： Gabor Kiss ,  Thomas E. Green ,  Terry E. Helton ,  William C. Horn ,  William A. Lamberti ,  Tan-Jen Chen

IPC: C07C2/74 ,  C07C45/53 ,  B01J35/02 ,  B01J29/74 ,  B01J35/00 ,  C07C37/08 ,  C07C409/14

CPC classification number: C07C2/74 ,  B01J29/7476 ,  B01J35/0006 ,  B01J35/0073 ,  B01J35/008 ,  B01J35/026 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/02 ,  B01J37/0201 ,  B01J37/0223 ,  B01J2229/20 ,  B01J2229/42 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/14 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C49/403 ,  C07C39/04

Abstract: A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the outer portion of a given catalyst particle is Couter, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where Crim/Ccenter≧2.0 and/or Couter/Ccenter2.0. Also disclosed are rimmed catalyst and process for making phenol and/or cyclohexanone using the catalyst.

Abstract translation: 一种制备烷基化芳族化合物的方法包括在加氢烷基化条件下使芳族起始原料和氢气与多个催化剂颗粒接触以产生包含烷基化芳族化合物的流出物，所述催化剂包含固体酸，不同于 固体酸和氢化金属，其中氢化金属在至少60重量％催化剂颗粒中的分布使得给定催化剂颗粒的边缘部分中的氢化金属的平均浓度为Crim，平均浓度 在给定催化剂颗粒的外部部分的氢化金属是Couter，给定催化剂颗粒的中心部分的氢化金属的平均浓度是Ccenter，其中Crim /Ccenter≥2.0和/或Couter / Ccenter2.0。 还公开了边缘催化剂和使用催化剂制备苯酚和/或环己酮的方法。

公开(公告)号：US20150099910A1

公开(公告)日：2015-04-09

申请号：US14403806

申请日：2013-07-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Gabor Kiss ,  Tan-Jen Chen ,  Thomas E. Green

IPC: B01J29/74 ,  C07C2/74

CPC classification number: B01J29/7476 ,  B01J37/18 ,  B01J38/10 ,  B01J38/56 ,  B01J2229/42 ,  C07C2/74 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/584 ,  C07C13/28

Abstract: A process for activating a hydroalkylation catalyst in a first state comprising an acid component and a hydrogenating metal component, including: (i) treatment at a temperature of at least 120° C. in the presence of hydrogen for a first duration to produce a catalyst in a second state having a first hydroalkylation activity; (ii) contacting the catalyst in the second state with an aromatic compound and hydrogen under a hydroalkylation condition effective to convert at least part of the aromatic compound to a cycloalkylaromatic compound and produce a catalyst in a third state; and (iii) treating the catalyst in the third state at a temperature of at least 160° C. in the presence of hydrogen but advantageously in the substantial absence of the aromatic compound for a third duration to produce an activated catalyst in a fourth state having a third hydroalkylation activity greater than the first hydroalkylation activity.

Abstract translation: 一种在包含酸组分和氢化金属组分的第一状态下活化加氢烷基化催化剂的方法，包括：（i）在氢存在下在至少120℃的温度下处理第一段时间以产生催化剂 在具有第一加氢烷基化活性的第二状态下; （ii）在有效将至少部分芳族化合物转化为环烷基芳族化合物并产生第三种状态的催化剂的加氢烷基化条件下使第二状态的催化剂与芳族化合物和氢气接触; 和（iii）在氢气存在下在至少160℃的温度下处理第三状态的催化剂，但有利地基本上不存在芳族化合物持续第三个时间，以产生具有第四状态的活化催化剂，其具有 第三加氢烷基化活性大于第一加氢烷基化活性。

公开(公告)号：US20150065754A1

公开(公告)日：2015-03-05

申请号：US14394524

申请日：2013-04-10

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Tan-Jen Chen ,  Travis A. Reine ,  Keith H. Kuechler ,  Terry E. Helton ,  Jihad M. Dakka

IPC: C07C5/05 ,  C07C45/53 ,  C07C37/08

CPC classification number: C07C5/05 ,  B01J21/04 ,  B01J23/44 ,  B01J23/462 ,  B01J23/75 ,  B01J23/755 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0009 ,  C07C2/74 ,  C07C5/03 ,  C07C7/163 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/14 ,  C07C2521/04 ,  C07C2523/44 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C49/403 ,  C07C39/04

Abstract: The present invention relates to hydrogenation processes including: contacting a first composition with hydrogen under hydrogenation conditions, in the presence of an eggshell hydrogenation catalyst, wherein the first composition has: (i) greater than about 50 wt % of cyclohexylbenzene, the wt % based upon the total weight of the first composition; and (ii) greater than about 0.3 wt % of cyclohexenylbenzene, the wt % based upon the total weight of the first composition; and thereby obtaining a second composition having less cyclohexenylbenzene than the first composition. Other hydrogenation processes are also described.

Abstract translation: 本发明涉及氢化方法，包括：在加氢条件下，在蛋壳氢化催化剂存在下使第一组合物与氢接触，其中第一组合物具有：（i）大于约50重量％的环己基苯，基于重量％ 基于第一组合物的总重量; 和（ii）大于约0.3重量％的环己烯基苯，所述wt％基于第一组合物的总重量; 从而获得比第一组合物少的环己烯基苯的第二组合物。 还描述了其它氢化方法。