Abstract:
High purity monomers, such as methyl p-hydroxymethylbenzoate, are produced by selective reduction of dicaboxylic acid monoesters with diborane. The resultant monomers are suitable for producing new polymers with improved physical properties.
Abstract:
7,8-Diacyl bicyclo 2.2.2!oct-5-ene-bis(2,3-dicarboximide) and 7,8-diacyl bicyclo 2.2.2!octane-bis(2,3-dicarboximide) compounds useful for the production of polyimides.
Abstract:
This invention relates to a new catalyst and to a novel oxidation process. In this novel process, aromatic compounds with an alkyl group having at least one alpha hydrogen, including aromatic compounds wherein the alkyl groups are unsubstituted and substituted, are contacted in the liquid phase at reaction conditions with an oxygen-containing gas in the presence of a novel catalyst which is prepared by milling an anhydrous transition metal halide with silver nitrite, the transition metal being selected from the Groups IVb to VIII and Ib and IIb of the Periodic Table, wherein the mole ratios of metal halide to silver nitrite are in the ratio of 1:1 to 1:5.
Abstract:
The trans- acidolysis reaction between carboxylic acids and lower alkanoic acid esters of organic hydroxy or mercapto compounds is catalyzed by Group Ia and IIa metal salts of alkanoic acids such as sodium acetate.
Abstract:
A decarboxylation process for substituting cyano radicals for silver carboxylate radicals which comprises reacting the silver salts of carboxylic acids with silver cyanide under decarboxylation conditions of at least 320.degree.C.
Abstract:
Quaternary ammonium compounds containing an anhydride groups are prepared by halogenating dimethylmaleic anhydride and reacting the halogenated product with a tertiary amine. The products are useful as surfactants, biocides and as cosurfactants in enhanced oil recovery.
Abstract:
Cyclic dianhydrides and polyimides are prepared from maleic anhydride compounds and diolefins. The diolefins are alpha- , omega-linear diolefins of up to 100 carbon atoms or cyclic diolefins of up to 40 carbon atoms. The polyimides and copolyimides prepared from these cyclic dianhydrides are useful in films, fibers and coatings.
Abstract:
3-Sulfoxy-1,2-propylene glycols-1-esters of tricyclo (4.2.2.0.sup.2,5) dec-9-ene-3,4,7,8-tetracarboxylic acid are prepared. These compounds are useful as surfactants, biocides and as cosurfactants in enhanced oil recovery.
Abstract:
This invention relates to carbamates of beta-hydroxyethylsulfoxides which are useful as cosurfactants in enhanced oil recovery, surfactants and biocides, and as hydraulic fluids when of sufficiently low molecular weight.
Abstract:
Novel polyimides and molding compositions are prepared from novel tricyclo[4.2.1.0.sup.2,5 ] nonane-3,4-dimethyl-3,4,7,8-tetracarboxylic acid dianhydride. The dianhydride is useful for the manufacture of polyimides which are useful as engineering plastics.