Electrochemical coating of carbon fibers
    51.
    发明授权
    Electrochemical coating of carbon fibers 失效
    碳纤维的电化学涂层

    公开(公告)号:US4724062A

    公开(公告)日:1988-02-09

    申请号:US899605

    申请日:1986-08-25

    摘要: A layer of electrically conductive polymers is applied by a process in which carbon fibers of filaments or sheet-like structures of carbon fibers or filaments are coated with sulfonic acids of phthalocyanines or porphyrins, the filaments treated in this manner are made the anode in a solution which contains monomers from the class consisting of the 5-membered heterocycles, and the monomers are anodically polymerized so that a conductive layer is formed on the fibers, filaments or sheet-like structures.

    摘要翻译: 一层导电聚合物通过其中碳纤维或细丝的碳纤维或纤维的片状结构被酞菁或卟啉的磺酸涂覆的方法施加,以这种方式处理的长丝被制成溶液中的阳极 其包含由5元杂环组成的类别的单体,并且单体被阳极聚合,使得在纤维,长丝或片状结构上形成导电层。

    Preparation of electrically conductive polymeric systems
    54.
    发明授权
    Preparation of electrically conductive polymeric systems 失效
    导电聚合体系的制备

    公开(公告)号:US4404126A

    公开(公告)日:1983-09-13

    申请号:US278668

    申请日:1981-06-29

    摘要: A process for the preparation of electrically conductive polymers, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.1 to 95% by weight of black phosphorus and from 0.5 to 25% by weight of sodium, potassium, rubidium or cesium or of an amide of these, preferably in tetrahydrofuran, dimethoxyglycol, nitromethane or methylene chloride (the molar ratio of alkali metal or amide to organic compound preferably being from 1:1 to 1:5) are added to an organic polymer chosen from the group comprising the polyphenylenes, heteropolyphenylenes and polyacetylenes, in the absence of moisture and of oxygen. The electrically conductive polymers obtained can be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, and can also be used for the antistatic treatment of plastics.

    摘要翻译: 一种导电聚合物的制备方法,其电导率大于10-2S / cm,其中0.1至95重量%的黑磷和0.5至25重量%的钠,钾,铷或铯或 这些的酰胺优选在四氢呋喃,二甲氧基乙二醇,硝基甲烷或二氯甲烷中(碱金属或酰胺与有机化合物的摩尔比优选为1:1至1:5)加入到选自以下的有机聚合物中: 聚苯乙烯,杂多亚苯基和聚乙炔,在没有水分和氧气的情况下。 得到的导电性聚合物可用于电气工业中用于生产太阳能电池,用于辐射的转换和固定以及用于电气和磁性开关的生产,并且还可以用于塑料的抗静电处理。

    Preparation of electrically conductive hetero-polyaromatics
    56.
    发明授权
    Preparation of electrically conductive hetero-polyaromatics 失效
    导电杂多元芳烃的制备

    公开(公告)号:US4344870A

    公开(公告)日:1982-08-17

    申请号:US237636

    申请日:1981-02-24

    IPC分类号: H01B1/12 H01L51/30 H01B1/00

    摘要: A process for the preparation of electrically conductive hetero-polyaromatics, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+PF.sub.6.sup.-, NO.sup.+BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyaromatic in the absence of moisture and of oxygen.

    摘要翻译: 一种制备电导率大于10-2S / cm的导电杂多元芳族化合物的方法,其中0.5至35重量%的pka为-10至+4的强路易斯酸,优选AsF 5,SbF 5 ,UF6,HClO4,NO + SbF6-,NO + AsF6-,NO + PF6-,NO2 + PF6-,NO + BF4-,NO2 + BF4-,NO + ClO4-,(CF3) - 二硝基苯酚,2,4,6-三硝基苯磺酸或2,4,6-三硝基苯甲酸,在不存在水分和氧气的情况下加入到杂多芳族化合物中。

    Polymers containing aromatic aldehyde groups
    57.
    发明授权
    Polymers containing aromatic aldehyde groups 失效
    含有芳族醛基团的聚合物

    公开(公告)号:US4315089A

    公开(公告)日:1982-02-09

    申请号:US93931

    申请日:1979-11-13

    CPC分类号: C08F20/58 C08F12/22 C08F20/30

    摘要: Abstract of the disclosure: Novel polymers which have K values of from 20 to 140 and which contain structural units of the general formula--CH.sub.2 --C(R.sup.1 A)--where R.sup.1 is H or CH.sub.3 and A is an aromatic radical which contains aldehyde groups and has the formula ##STR1## where R.sup.2 is H, OH, O-alkyl, alkoxyalkyl or O--Si(CH.sub.3).sub.3. The polymers are prepared by polymerizing the corresponding monomers CH.sub.2 .dbd.C(R.sup.1 A) in the presence of free-radical initiators.

    摘要翻译: 本发明摘要:K值为20〜140的新型聚合物,其含有通式-CH 2 -C(R1A)的结构单元,其中R 1为H或CH 3,A为含有醛基的芳基, 其中R2是H,OH,O-烷基,烷氧基烷基或O-Si(CH3)3,具有式 。 聚合物通过在自由基引发剂存在下聚合相应的单体CH 2 = C(R 1A)来制备。

    Disperse dye formulations
    59.
    发明授权
    Disperse dye formulations 失效
    分散染料配方

    公开(公告)号:US4286959A

    公开(公告)日:1981-09-01

    申请号:US18765

    申请日:1979-03-08

    摘要: The invention seeks to provide a free-flowing formulation of one or more disperse dyes, with which packages can be dyed homogeneously by the HT process without filtering out of the dye, and which is suitable for the thermosol dyeing process. According to the invention such a formulation comprises one or more disperse dyes (a) enclosed in a matrix of one or more polymers (b) which are soluble, or colloidally soluble, both in water and in an organic solvent, in the form of a solid solution in a state of molecular dispersion or of extremely fine subdivision so that in an X-ray spectrum the dye appears amorphous.The formulations may contain additional assistants conventionally present when dyeing hydrophobic fibers. The formulations contain the disperse dye in an extremely fine state of subdivision. Because of the latter, the formulations give level package dyeings, without filtration of the dye, and very level dyeings when used by the thermofixing process.

    摘要翻译: 本发明寻求提供一种或多种分散染料的自由流动配方,通过该方法可以通过HT方法将包装均匀地染色,而不过滤出染料,并且适用于热溶胶染色方法。 根据本发明,这种制剂包含一种或多种分散染料(a),其包封在一种或多种聚合物(b)的基质中,所述聚合物(b)在水和有机溶剂中都是可溶于或胶体可溶的,形式为 在分子分散状态或极细细分的状态下的固溶体,使得在X射线光谱中,染料看起来是无定形的。 当染色疏水性纤维时,制剂可以含有通常存在的其它助剂。 制剂含有极细细分的分散染料。 由于后者,制剂在不过滤染料的情况下给予水平的包装染色,而当用热固定方法使用时,会产生非常高的染色。