公开(公告)号：US06369002B1

公开(公告)日：2002-04-09

申请号：US09702101

申请日：2000-10-30

申请人： Walter Kunz ,  Kurt Nebel

发明人： Walter Kunz ,  Kurt Nebel

IPC分类号： C07D40104

CPC分类号： C07D401/04 ,  A01N43/56 ,  C07D471/04 ,  C07D487/04

摘要： Compounds of formula 1 wherein R1 is hydrogen, fluorine, chlorine, bromine or methyl; R2 is C1-C4alkyl, C1-C4halogenalkyl, halogen, hydroxy, C1-C4alkoxy, C1-C4halogenalkoxy, nitro, amino or cyano; R3, R15 to R39 and X6 to X19 are as defined in claim 1, and the agrochemically acceptable salts and stereoisomers of these compounds of formula I are suitable for use as herbicides.

摘要翻译： R 1为卤素，羟基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，硝基，氨基或氰基; R 3为R 15至R 39和X 6 至X19如权利要求1所定义，并且这些式I化合物的农业化学上可接受的盐和立体异构体适合用作除草剂。

公开(公告)号：US5384321A

公开(公告)日：1995-01-24

申请号：US105096

申请日：1993-08-10

申请人： Walter Kunz ,  Rolf Schurter

发明人： Walter Kunz ,  Rolf Schurter

IPC分类号： A01N43/82 ,  C07D285/14 ,  A01N43/72

CPC分类号： C07D285/14 ,  A01N43/82

摘要： Compositions comprising, as active ingredients, compounds of the formula I ##STR1## in which: X.sub.1, X.sub.2 and X.sub.3 independently of one another are hydrogen, methyl, methoxy, methylthio, halogen or nitro;A is C.sub.1 -C.sub.2 alkyl which is substituted by a maximum of 3 X--C.sub.1 -C.sub.4 alkyl groups, methyl which is substituted by 2 or 3 halogen atoms, ethyl which is substituted by hydroxyl and/or not more than 4 halogen atoms; vinyl which is unsubstituted or substituted by not more than 3 halogen atoms; furthermore ethynyl, propargyl, formyl, acetyl, acetyl which is substituted by not more than 3 halogen atoms, or one of the groups C(R).dbd.N--N(R.sub.2)R.sub.3, C(N.dbd.N--U.sub.1).dbd.N--NH--U.sub.1, CH(R)--[N(R.sub.1)].sub.n --N(R.sub.2)R.sub.3, C(R)(CN)OR.sub.4, C(R).dbd.N(O).sub.n R.sub.3, CH(R)--O--N.dbd.C(R.sub.1)R.sub.2, CH(R)--O--N.dbd.C(CN)--CONH--R.sub.5, C(R.sub.6).dbd.N--(O).sub.n R, CH(R)--Y--E--R.sub.3, CO--[C(OR).sub.2 ].sub.n Q, C(Q).dbd.CH--OR or T--Q;in which furthermore:n is zero or 1;X and Y independently of one another are oxygen or sulfur,R and R.sub.1 independently of one another are hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.2 is hydrogen, C.sub.1-C.sub.8 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or cyano;R.sub.3 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or is an aryl radical U;R.sub.4 is hydrogen, C.sub.1 -C.sub.6 alkyl, Si(C.sub.1 -C.sub.6 alkyl).sub.3 or OCOC.sub.1 -C.sub.3 alkyl;R.sub.5 is hydrogen or CONHR.sub.1 ;R.sub.6 is N(R.sub.1)R.sub.2, hydrazino or Q;E is CO or SO.sub.2 ;U and U.sub.1 independently of one another are a phenyl radical which is unsubstituted or monosubstituted or polysubstituted by identical or different substituents from the series comprising methyl, methoxy, halogen, trifluoromethyl, nitro or cyano;T is C.sub.1 -C.sub.2 alkylene, methylene which is substituted by amino, hydroxyl or halogen, the substituents being independent of one another, or is ethenylene which is unsubstituted or substituted by halogen or cyano;Q is COXR or cyano.The novel compositions have crop-protecting properties and are particularly suitable for protecting plants against infestation by phytopathogenic microorganisms such as fungi, bacteria and viruses.

公开(公告)号：US5302607A

公开(公告)日：1994-04-12

申请号：US58838

申请日：1993-05-06

申请人： Walter Kunz ,  Rolf Schurter

发明人： Walter Kunz ,  Rolf Schurter

IPC分类号： A01N43/82 ,  C07D285/14 ,  C07D417/12 ,  C07F7/08 ,  C07F7/18

CPC分类号： C07D285/14 ,  A01N43/82 ,  C07D417/12 ,  C07F7/0812 ,  C07F7/0836 ,  C07F7/0898 ,  C07F7/184 ,  C07F7/1844

摘要： Novel benzo-1,2,3-thiadiazole-7-carboxylic acid esters of formula ##STR1## in which Y is oxygen or sulfur;Q.sub.1 and Q.sub.2 independently of one another are each hydrogen or halogen;R.sub.1 and R.sub.2 independently of one another are each hydrogen or C.sub.1 -C.sub.4 alkyl; X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, trifluoromethyl, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.2 alkoxy halo-substituted in the alkyl moiety, nitro, cyano, dimethylamino, phenyl, phenoxy, or phenyl or phenoxy each substituted by halogen and/or by C.sub.1 -C.sub.2 alkyl and/or by C.sub.1 -C.sub.2 alkoxy;X.sub.2 is hydrogen, halogen or methyl;X.sub.3 is hydrogen or halogen; andA comprises the bridge member ##STR2## R.sub.5 is C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.6 alkoxy, phenyl, or phenyl substituted by halogen or methoxy; R.sub.6 is C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy; ##STR3## that together represents a saturated or unsaturated 3- to 7-membered heterocycle W.sub.3 having a maximum of 2 oxygen or sulfur atoms as additional hetero atoms.The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

摘要翻译： 新的式（Ⅰ）的苯并1,2,3-噻二唑-7-羧酸酯，其中Y是氧或硫; Q1和Q2各自独立地为氢或卤素; R 1和R 2彼此独立地为氢或C 1 -C 4烷基; X 1是氢，卤素，C 1 -C 4烷基，三氟甲基，C 1 -C 3烷基，在烷基部分被卤素取代的C 1 -C 2烷氧基，硝基，氰基，二甲基氨基，苯基，苯氧基，或各自被卤素和/或被C1 C 2烷基和/或被C 1 -C 2烷氧基取代; X2是氢，卤素或甲基; X3是氢或卤素; 并且A包含桥连构件，R 5是C 1 -C 6烷基，C 3 -C 6环烷基，C 1 -C 6烷氧基，苯基或被卤素或甲氧基取代的苯基; R6是C1-C6烷基或C1-C6烷氧基; 它们一起表示饱和或不饱和的具有最多2个氧原子或硫原子作为附加杂原子的3-至7-元杂环W3。 新型活性成分具有植物保护性质，特别适用于植物防止植物病原微生物如真菌，细菌和病毒侵袭的预防性保护。

公开(公告)号：US5229384A

公开(公告)日：1993-07-20

申请号：US845518

申请日：1992-02-27

申请人： Walter Kunz ,  Rolf Schurter

发明人： Walter Kunz ,  Rolf Schurter

IPC分类号： A01N43/82 ,  C07D285/14

CPC分类号： C07D285/14 ,  A01N43/82

摘要： Novel benzo-1,2,3-thiadiazole derivatives of the formula ##STR1## in which; A is --OR.sub.4, --SR.sub.4, --N(R.sub.5)R.sub.6, --N(R.sub.7)--N(R.sub.5)R.sub.6, --O--N.dbd.C(R.sub.8)R.sub.9, --N(R.sub.7)--OR.sub.10, or ##STR2## R.sub.4 is C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.35 alkyl which is interrupted by an oxygen or sulfur atom, C.sub.1 -C.sub.8 alkyl which is substituted by halogen or --COOR.sub.7, C.sub.3 -C.sub.6 alkenyl which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.6 alkinyl which is unsubstituted or substituted by halogen, C.sub.4 -C.sub.7 cycloalkyl which is unsubstituted or substituted by halogen or methyl, an aryl or heterocyclic radical U having not more than 3 heteroatoms O, N and/or S, or a radical U which is linked via an alkylene bridge containing not more than 6 carbon atoms and up to 2 oxygen atoms.The novel active substances have plant protection properties and are particularly suitable for preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

摘要翻译： 新颖的式（I）的苯并-1,2,3-噻二唑衍生物，其中： A是-OR4，-SR4，-N（R5）R6，-N（R7）-N（R5）R6，-ON = C（R8）R9，-N（R7）-OR10或R4是R4 C1-C18烷基，被氧或硫原子间隔的C3-C35烷基，被卤素或-COOR7取代的C1-C8烷基，未被取代或被卤素取代的C3-C6链烯基，未被取代或被卤素取代的C3-C6烷基 未被取代或被卤素或甲基取代的C 4 -C 7环烷基，具有不超过3个O，N和/或S杂原子的芳基或杂环基团U或通过不超过6个亚烷基桥连接的基团U 碳原子和至多2个氧原子。 新型活性物质具有植物保护性，特别适用于植物防止植物病原微生物如真菌，细菌和病毒侵袭的预防性保护。

公开(公告)号：US5169951A

公开(公告)日：1992-12-08

申请号：US684549

申请日：1991-04-11

申请人： Marius Sutter ,  Walter Kunz

发明人： Marius Sutter ,  Walter Kunz

IPC分类号： A01N43/80 ,  C07C323/22 ,  C07D275/04

CPC分类号： C07D275/04 ,  A01N43/80 ,  C07C323/22

摘要： Nematicidal compositions which comprise as active ingredient compounds of formula I ##STR1## wherein R is nitro or halogen, and also processes for the preparation of the compounds of formula I, novel intermediates of the preparation process and methods of using the compounds and the compositions in the control of nematodes are described.

摘要翻译： 包含作为活性成分的式I化合物（I）的杀线虫组合物其中R是硝基或卤素，以及制备式I化合物的方法，制备方法的新中间体和使用该化合物的方法和 描述了控制线虫的组成。

公开(公告)号：US5128371A

公开(公告)日：1992-07-07

申请号：US731356

申请日：1991-07-15

申请人： Hans Moser ,  Wolfgang Eckhardt ,  Walter Kunz ,  Adolf Hubele

发明人： Hans Moser ,  Wolfgang Eckhardt ,  Walter Kunz ,  Adolf Hubele

IPC分类号： C07D249/08 ,  A01N37/18 ,  A01N37/44 ,  A01N43/08 ,  A01N43/56 ,  A01N43/653 ,  C07C67/00 ,  C07C231/12 ,  C07C233/54 ,  C07C235/16 ,  C07C235/68 ,  C07C241/00 ,  C07C243/14 ,  C07C243/22 ,  C07C301/00 ,  C07C307/02 ,  C07C313/00 ,  C07C319/20 ,  C07C323/60 ,  C07D231/12 ,  C07D307/20 ,  C07D307/24 ,  C07D307/32 ,  C07D307/33 ,  C07D307/58 ,  C07D307/68 ,  C07D521/00

CPC分类号： A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D307/24 ,  C07D307/33 ,  C07D307/68

摘要： There are described novel acylated naphthylamines of the formula I defined herein ##STR1## which have valuable fungicidal properties. They can be used in practice on their own or in the form of compositions for the protection of cultivated plants against fungus infection.

摘要翻译： 描述了具有有价值的杀真菌性质的本文定义的式I的新型酰化萘胺。 它们可以在实践中自己使用或以组合物的形式用于保护栽培植物免受真菌感染。

公开(公告)号：US5126358A

公开(公告)日：1992-06-30

申请号：US632771

申请日：1990-12-21

申请人： Walter Kunz

发明人： Walter Kunz

IPC分类号： C07D213/76 ,  A01N43/40 ,  C07D213/81 ,  C07D213/86 ,  C07D405/14 ,  C07D409/14 ,  C07D471/04

CPC分类号： C07D213/86 ,  A01N43/40 ,  C07D405/14 ,  C07D409/14 ,  C07D471/04

摘要： The invention relates to novel isonicotinoylpyridinyl hydrazine derivatives of formula I ##STR1## wherein Hal is halogen,R.sub.1 is hydrogen, methyl or --COR.sub.5,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, or a radical selected from --COR.sub.5 and --CO--Z--R.sub.6,R.sub.3 is hydrogen, halogen, trifluoromethyl, trichloromethyl, --COOH, --COOCH.sub.3, --OH or nitro.R.sub.4 is hydrogen, halogen, methoxy or methyl,R.sub.5,R.sub.6, Z are as defined hereinafter.with the exception of 1-(pyridin-2'-yl)-2-(2,6-dichloroisonicotinoyl) hydrazine.The novel compounds have plant-protective properties and are especially suitable for protecting plants from attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

摘要翻译： 本发明涉及式I的新型异烟酰基吡啶基肼衍生物其中Hal是卤素，R1是氢，甲基或-COR5，R2是氢，C1-C4烷基或选自-COR5和-CO- Z-R6，R3是氢，卤素，三氟甲基，三氯甲基，-COOH，-COOCH 3，-OH或硝基。 R4是氢，卤素，甲氧基或甲基，R5，R6，Z如下文所定义。 除了1-（吡啶-2'-基）-2-（2,6-二氯异烟酰基）肼。 新化合物具有植物保护性质，特别适用于保护植物免受植物病原微生物如真菌，细菌和病毒侵袭。

公开(公告)号：US5015649A

公开(公告)日：1991-05-14

申请号：US403844

申请日：1989-09-01

申请人： Walter Kunz

发明人： Walter Kunz

IPC分类号： C07D213/76 ,  A01N43/40 ,  C07D213/81 ,  C07D213/86 ,  C07D405/14 ,  C07D409/14 ,  C07D471/04

CPC分类号： C07D213/86 ,  A01N43/40 ,  C07D405/14 ,  C07D409/14 ,  C07D471/04

摘要： The invention relates to novel isonicotinoylpyridinyl hydrazine derivatives of formula I ##STR1## wherein Hal is halogen,R.sub.1 is hydrogen, methyl or --COR.sub.5,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, or a radical selected from --COR.sub.5 and --CO--Z--R.sub.6,R.sub.3 is hydrogen, halogen, trifluoromethyl, trichloromethyl, --COOH, --COOCH.sub.3, --OH or nitro,R.sub.4 is hydrogen, halogen, methoxy or methyl,R.sub.5 is C.sub.2 -C.sub.6 alkyl, unsubstituted or substituted by one or more halogen atoms, C.sub.1 -C.sub.6 alkyl which is interrupted by oxygen or sulfur, C.sub.1 -C.sub.6 alkyl which is substituted by one or more halogen atoms and interrupted by oxygen or sulfur; C.sub.2 -C.sub.4 alkenyl, unsubstituted or substituted by one or more halogen atoms; phenyl, benzyl, or phenyl or benzyl each substituted by halogen, methyl, trifluoromethyl or trichloromethyl; a 5- or 6-membered heterocycle which contains nitrogen, oxygen or sulfur as hetero atoms, a 3- to 6-membered cycloalkyl radical or a cycloalkyl radical which is substituted by one or more halogen atoms or methyl groups,R.sub.6 is C.sub.1 -C.sub.5 alkyl, phenyl or, if Z is the --CO group, is O--alkyl containing 1 or 2 carbon atoms, andZ is oxygen, sulfur or the --CO group, with the exception of 1-(pyridin-2'-yl)-2-(2,6-dichloroisonicotinoyl) hydrazine.The novel compounds have plant-protective properties and are especially suitable for protecting plants from attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

摘要翻译： 本发明涉及式I的新型异烟酰基吡啶基肼衍生物其中Hal是卤素，R1是氢，甲基或-COR5，R2是氢，C1-C4烷基或选自-COR5和-CO- Z-R6，R3是氢，卤素，三氟甲基，三氯甲基，-COOH，-COOCH 3，-OH或硝基，R 4是氢，卤素，甲氧基或甲基，R 5是未取代或被一个或多个卤素原子取代的C 2 -C 6烷基 被氧或硫中断的C1-C6烷基，被一个或多个卤素原子取代并被氧或硫中断的C1-C6烷基; 未被取代或被一个或多个卤素原子取代的C 2 -C 4链烯基; 苯基，苄基或各自被卤素，甲基，三氟甲基或三氯甲基取代的苯基或苄基; 含有氮，氧或硫作为杂原子的5-或6-元杂环，被一个或多个卤原子或甲基取代的3-至6-元环烷基或环烷基，R 6是C 1 -C 5烷基 苯基或Z为-CO基时为含有1或2个碳原子的O-烷基，Z为氧，硫或-CO基，除1-（吡啶-2-基） - 2-（2,6-二氯异烟酰基）肼。 新化合物具有植物保护性质，特别适用于保护植物免受植物病原微生物如真菌，细菌和病毒侵袭。

公开(公告)号：US4810724A

公开(公告)日：1989-03-07

申请号：US731350

申请日：1985-05-06

申请人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele

发明人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele

IPC分类号： A01N43/08 ,  A01N43/16 ,  A01N43/56 ,  A01N43/653 ,  C07D307/33 ,  C07D307/68 ,  C07D405/12 ,  C07D521/00 ,  C07D407/12

CPC分类号： C07D307/33 ,  A01N43/08 ,  A01N43/56 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D307/68

摘要： N-Acylated N-phenyl-aminotetrahydro-2-furanones of the formula ##STR1## wherein R represents C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.1 represents C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.2 represents hydrogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.3 represents hydrogen or methyl, with the total number of C atoms of the substituents R, R.sub.1, R.sub.2 and R.sub.3 in the phenyl ring not exceeding the number 8,R.sub.4 represents hydrogen or methyl, whileR.sub.5 represents one of the following groups: an alkylthioalkyl or alkoxyalkyl group having 2 to 5 carbon atoms or an alkoxyalkoxymethyl group having a maximum of 6 carbon atoms, a 2-furanyl or 2-tetrahydrofuranyl group optionally substituted by halogen, a 1,2,4-trizolylmethyl group, a 1,2-pyrazolylmethyl group, or a group --CH.sub.2 --OR.sub.6 in which R.sub.6 represents a 5- or 6-membered heterocyclic having oxygen as the hetero atom,are valuable fungicidal active substances. They can be used as fungicidal compositions, particularly for combating phytopathogenic fungi, e.g. against downy mildew on potatoes, tomatoes, grape vines and sugar beet and other plants. The novel compounds have a systemic action.

摘要翻译： 式（I）的N-酰化N-苯基 - 氨基四氢-2-呋喃酮其中R表示C1-C4-烷基，C1-C4-烷氧基或卤素，R1表示C1-C3-烷基，C1-C4- 烷氧基或卤素，R 2表示氢，C 1 -C 3 - 烷基，C 1 -C 4 - 烷氧基或卤素，R 3表示氢或甲基，苯基环中取代基R，R 1，R 2和R 3的C原子总数不是 超过数8，R 4表示氢或甲基，而R 5表示以下基团之一：烷硫基烷基或具有2至5个碳原子的烷氧基烷基或具有最多6个碳原子的烷氧基烷氧基甲基，2-呋喃基或2- 任选被卤素取代的四氢呋喃基，1,2,4-三唑基甲基，1,2-吡唑基甲基或基团-CH2-OR6，其中R6表示具有氧作为杂原子的5-或6-元杂环 ，是有价值的杀真菌活性物质。 它们可以用作杀真菌组合物，特别是用于防治植物病原真菌，例如， 反对马铃薯，西红柿，葡萄藤和甜菜等植物的霜霉病。 新化合物具有全身作用。

公开(公告)号：US4663463A

公开(公告)日：1987-05-05

申请号：US676765

申请日：1984-11-30

申请人： Walter Kunz ,  Wolfgang Eckhardt

发明人： Walter Kunz ,  Wolfgang Eckhardt

IPC分类号： A01N43/50 ,  A01N43/653 ,  A01N47/06 ,  C07D233/56 ,  C07D233/60 ,  C07D233/61 ,  C07D233/64 ,  C07D249/08 ,  C07D249/10 ,  C07D521/00

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  A01N47/06 ,  C07D233/56 ,  C07D249/08

摘要： There are described microbicidally effective mandelic acid derivatives and mandelonitriles of the formula I ##STR1## wherein X is --CH.dbd. or --N.dbd.; Ar is phenyl, diphenyl or naphthyl group, which can be substituted in the form of the substituents R.sub.1 -R.sub.3 by nitro, halogen, alkyl, alkoxy or haloalkyl; R is any one of the groups --COOR.sub.5, --COSR.sub.6, --CON(R.sub.7)(R.sub.8) or CN; n is 0, 1 or 2; and R.sub.4 to R.sub.8 are aliphatic and aromatic and in part also heterocyclic substituents which are described in the text in greater detail; with the inclusion of the salts and metal complexes thereof.Also methods for producing these products are disclosed, and also pesticidal compositions containing as active ingredient one of these compounds. There is described too a method for combating phytopathogenic microorganisms with the aid of these substances.

摘要翻译： 描述了式I（I）的杀微生物有效的扁桃酸衍生物和扁桃腈，其中X是-CH =或-N =; Ar是苯基，二苯基或萘基，其可以被取代基R 1 -R 3的形式被硝基，卤素，烷基，烷氧基或卤代烷基取代; R是-COOR 5，-COSR 6，-CON（R 7）（R 8）或CN中的任何一个; n为0,1或2; 并且R 4至R 8是脂族和芳族并且部分地还包括文中更详细描述的杂环取代基; 其中包含其盐和金属络合物。 还公开了制备这些产品的方法，以及含有作为这些化合物之一的活性成分的农药组合物。 还描述了借助于这些物质来防治植物病原微生物的方法。