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    Fragrance releasing olefinic silanes
    1.
    发明授权
    Fragrance releasing olefinic silanes 有权
    释放烯烃硅烷的香料

    公开(公告)号：US6153578A

    公开(公告)日：2000-11-28

    申请号：US385319

    申请日：1999-08-30

    申请人： Robert J. Perry

    发明人： Robert J. Perry

    IPC分类号： A61K8/18 ,  A61Q13/00 ,  C07F7/18 ,  C08L83/07 ,  C11B9/00 ,  A61K7/46 ,  C07F7/04

    CPC分类号： C07F7/184 ,  C07F7/1844 ,  C07F7/1852 ,  C07F7/1856

    摘要： Fragrant silanes having the formula:(R.sup.1 O).sub.a (R.sup.2 O).sub.b (R.sup.3 O).sub.c (R.sup.4).sub.d (R.sup.5).sub.e SiR.sup.6where R.sup.1, R.sup.2 and R.sup.3 are derived from the group of alcohols consisting of R.sup.1 OH, R.sup.2 OH and R.sup.3 OH wherein R.sup.1 OH, R.sup.2 OH and R.sup.3 OH are fragrant alcohols or alternatively R.sup.1, R.sup.2 and R.sup.3 are derived from the group of fragrant esters, ketones, or aldehydes having the structure:R.sup.7 --CH.sub.2 (C.dbd.O)--R.sup.8wherein the fragrant ester, ketone or aldehyde is capable of exhibiting the enol form of the carbonyl moiety under reaction conditions, with R.sup.4 and R.sup.5 selected from the group consisting of monovalent hydrocarbon radical having from one to forty carbon atoms and monovalent alkoxy radicals having from one to forty carbon atoms, R.sup.6 a two to forty atom monovalent unsaturated hydrocarbon radical containing a terminal olefinic or acetylenic moiety where the subscript a has a value ranging from 1 to 3 and the subscripts b, c, d, and e have values ranging from 0 to 2 subject to the limitation that a+b+c+d+e=3; R.sup.7 is selected from the group consisting of hydrogen and monovalent hydrocarbon radicals having from one to one hundred carbon atoms and R.sup.8 is selected from the group consisting of hydrogen and monovalent hydrocarbon radicals having from one to one hundred carbon atoms.

    摘要翻译： 具有式（R1O）a（R2O）b（R3O）c（R4）d（R5）eSiR6的芳香硅烷，其中R1，R2和R3衍生自由R1OH，R2OH和R3OH组成的醇，其中R1OH，R2OH 和R 3 OH是芳香醇，或者R1，R2和R3衍生自具有以下结构的芳族酯，酮或醛：R7-CH2（C = O）-R8，其中芳香酯，酮或醛能够 在反应条件下显示羰基部分的烯醇形式，其中R 4和R 5选自具有1至40个碳原子的一价烃基和具有1至40个碳原子的一价烷氧基，R 6为2至40个 含有末端烯属或炔属部分的单价不饱和烃基，其中下标a的值范围为1至3，下标b，c，d和e的值范围为0至2，但受限于a + b + c + d + e = 3; R 7选自氢和具有一至一百个碳原子的一价烃基，R 8选自氢和具有一至一百个碳原子的一价烃基。

    (alpha, omega)phenylethynyl siloxane monomers, oligomers, and polymers thereof
    4.
    发明授权
    (alpha, omega)phenylethynyl siloxane monomers, oligomers, and polymers thereof 失效
    （α，ω）苯乙炔基硅氧烷单体，低聚物及其聚合物

    公开(公告)号：US5329036A

    公开(公告)日：1994-07-12

    申请号：US939326

    申请日：1992-09-02

    申请人： Thomas K. Dougherty ,  William E. Elias

    发明人： Thomas K. Dougherty ,  William E. Elias

    IPC分类号： C07F7/08 ,  C07F7/18 ,  C08F38/00 ,  C08F290/00 ,  C08F299/08 ,  C08G77/04 ,  C08G77/20 ,  C08G77/22 ,  C08G77/455 ,  C08F7/08

    CPC分类号： C07F7/0896 ,  C07F7/0836 ,  C07F7/0847 ,  C07F7/1844 ,  C08G77/045 ,  C08G77/20 ,  C08G77/455

    摘要： Novel acetylene-terminated silicone monomers with (a) silane (Si--H) functionalities, (b) silanol (Si--OH) functionalities, or (c) (alpha,omega)phenylethynyl terminated siloxanes, and a novel synthetic route. The (alpha,omega)phenylethynyl-terminated siloxane monomers are prepared, starting with 1,3-bromobenzene, which is converted to 3-TMS-ethynylbromobenzene, where TMS represents the trimethylsilyl group, by reacting 1,3-dibromobenzene with trimethylsilylacetylene and triethylamine in the presence of a palladium catalyst. The 3-bromo-TMS protected phenyl acetylene is then reacted with an alkyllithium compound, such as n-butyllithium, or with magnesium to form the corresponding lithio or Grignard compound, respectively, followed by reaction with a halogenated compound, such as chlorodimethylsilane, to form 3-trimethylsilyl-ethynylphenyldimethyl silane. Next, the TMS protected ethynylphenyl silane is subjected to deprotection and methanolysis of the Si--H bond to form 3-ethynylphenyldimethyl methoxy silane, employing methanol. This silane is then hydrolyzed to form the corresponding silanol. Finally, the silanol is then condensed by known methods to form the disiloxane. The disiloxane monomer can be reacted with a cyclic siloxane, having .gtoreq.3 silicon atoms, each independently substituted with hydrogen, C.sub.1 to C.sub.6 alkyl, phenyl, or phenyl substituted with one or more alkyl or halogen groups, to form oligomers. Both monomers and oligomers form thermoset polymers by heating to a temperature of at least about 250.degree. C.

    摘要翻译： 具有（a）硅烷（Si-H）官能团，（b）硅烷醇（Si-OH）官能团或（c）（α，ω））苯基乙炔基封端的硅氧烷的新型乙炔封端的有机硅单体和新的合成路线。 制备（α，ω）苯基乙炔基封端的硅氧烷单体，通过1,3-二溴苯与三甲基甲硅烷基乙炔和三乙胺反应，由1,3-溴苯转化成3-TMS-乙炔基溴苯，其中TMS代表三甲基甲硅烷基 在钯催化剂存在下。 然后将3-溴-TT保护的苯基乙炔与烷基锂化合物如正丁基锂或与镁反应，分别形成相应的锂或格利雅化合物，随后与卤代化合物如氯二甲基硅烷反应， 形成3-三甲基甲硅烷基 - 乙炔基苯基二甲基硅烷。 接着，使用甲醇对TMS保护的乙炔基苯基硅烷进行Si-H键的去保护和甲醇分解以形成3-乙炔基苯基二甲基甲氧基硅烷。 然后将该硅烷水解形成相应的硅烷醇。 最后，通过已知的方法使硅烷醇缩合形成二硅氧烷。 二硅氧烷单体可与具有大于或等于3个硅原子的环状硅氧烷，各自独立地被氢取代，C1至C6烷基，苯基或被一个或多个烷基或卤素基团取代的苯基，以形成低聚物。 单体和低聚物通过加热至至少约250℃的温度形成热固性聚合物

    Metallized polymeric substrates
    7.
    发明授权
    Metallized polymeric substrates 失效
    金属化聚合物基材

    公开(公告)号：US5233067A

    公开(公告)日：1993-08-03

    申请号：US522375

    申请日：1990-05-08

    申请人： Gwo Swei ,  Kenneth W. Kristal

    发明人： Gwo Swei ,  Kenneth W. Kristal

    IPC分类号： C07F7/08 ,  C07F7/18 ,  C07F9/50 ,  H05K3/38

    CPC分类号： C07F9/5009 ,  C07F7/0818 ,  C07F7/0854 ,  C07F7/0858 ,  C07F7/182 ,  C07F7/184 ,  C07F7/1844 ,  H05K3/389

    摘要： A method for metallizing a polymeric substrate is disclosed. The method includes contacting a surface of an etched polymeric substrate with a silane coupling agent and depositing a metallic layer over the surface. The silane coupling agent forms a chemical linkage between the substrate and the metallic layer. A coupling agent composition and a metallized polymeric substrate are also described.

    摘要翻译： 公开了一种金属化聚合物基材的方法。 该方法包括使蚀刻的聚合物基材的表面与硅烷偶联剂接触并在表面上沉积金属层。 硅烷偶联剂在基材和金属层之间形成化学键。 还描述了偶联剂组合物和金属化聚合物基材。