公开(公告)号：US4565800A

公开(公告)日：1986-01-21

申请号：US748110

申请日：1985-06-24

申请人： Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

发明人： Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

IPC分类号： B01J23/847 ,  C10G45/06 ,  B01J23/22

CPC分类号： C10G45/06 ,  B01J23/8472

摘要： A catalyst composition is prepared by dissolving a suitable vanadium and oxygen containing compound, a suitable nickel (II) compound and ammonia in water, mixing this solution with an alumina containing support material, and calcining this mixture. This catalyst composition is used primarily for hydrotreating of hydrocarbon feed stream, which contain nickel, vanadium and sulfur impurities, particularly heavy oils.

公开(公告)号：US4560466A

公开(公告)日：1985-12-24

申请号：US665853

申请日：1984-10-29

申请人： Simon G. Kukes ,  Marvin M. Johnson

发明人： Simon G. Kukes ,  Marvin M. Johnson

IPC分类号： B01J27/188 ,  C10G45/04 ,  C10G45/34 ,  C10G45/00

CPC分类号： C10G45/04 ,  B01J27/188

摘要： An improved process for removing metals from heavy oils and other hydrocarbon feed streams is disclosed. The process comprises combining water with the hydrocarbon feed stream at a liquid volume ratio of about 1:50 to about 1:1, and contacting the mixture under suitable demetallizing conditions with hydrogen gas and a catalyst composition comprising (a) AlPO.sub.4 and preferably (b) a Group VIB metal, more preferably molybdenum.

摘要翻译： 公开了一种用于从重油和其他烃进料流中除去金属的改进方法。 该方法包括以约1:50至约1:1的液体体积比将水与烃进料流混合，并在合适的脱金属条件下将混合物与氢气和催化剂组合物接触，所述催化剂组合物包含（a）AlPO 4，优选（b ）VIB族金属，更优选为钼。

公开(公告)号：US4557824A

公开(公告)日：1985-12-10

申请号：US575592

申请日：1984-01-31

申请人： Simon G. Kukes ,  Gil R. Hawley

发明人： Simon G. Kukes ,  Gil R. Hawley

IPC分类号： B01J27/185 ,  C10G45/02 ,  C10G45/06 ,  C10G45/00

CPC分类号： C10G45/06 ,  B01J27/1853 ,  C10G45/02

摘要： Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and iron phosphate. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.

公开(公告)号：US4551230A

公开(公告)日：1985-11-05

申请号：US655798

申请日：1984-10-01

申请人： Simon G. Kukes ,  Gerhard P. Nowack

发明人： Simon G. Kukes ,  Gerhard P. Nowack

IPC分类号： B01J23/00 ,  B01J23/843 ,  C10G45/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/08

CPC分类号： B01J23/8432 ,  B01J23/005 ,  C10G45/06

摘要： Metals contained in a hydrocarbon containing feed stream are at least partially removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising an alumina-containing support and nickel arsenide, NiAs.sub.x. The life and activity of the catalyst composition can be increased by introducing a decomposable compound of a metal selected from the group consisting of the metals of Group IV-B, Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream during or prior to contacting the feed stream with hydrogen and the catalyst composition. The preferred nickel arsenide catalyst composition is prepared by reduction of alumina-supported nickel arsenate with hydrogen gas.

摘要翻译： 通过在合适的脱金属条件下与含氢氧化铝载体和镍砷化物NiAs x的催化剂组合物接触含烃进料流，至少部分地除去包含在含烃进料流中的金属。 催化剂组合物的寿命和活性可以通过引入选自以下的金属的可分解化合物来提高：IV-B族，VB族，VI-B族，VII-B族和VIII族的金属 在将进料流与氢气和催化剂组合物接触期间或之前，将含有烃的进料流的周期表。 优选的镍砷化物催化剂组合物通过用氢气还原氧化铝负载的砷酸镍来制备。

公开(公告)号：US4481377A

公开(公告)日：1984-11-06

申请号：US525518

申请日：1983-08-22

申请人： Simon G. Kukes ,  Robert L. Banks

发明人： Simon G. Kukes ,  Robert L. Banks

IPC分类号： B01J27/187 ,  C07C6/04 ,  C07C3/62

CPC分类号： C07C6/04 ,  B01J27/187

摘要： A process for the disproportionation of olefins involving the use of a catalyst comprising rhenium oxide and thorium phosphate and oxygen in the feed.

摘要翻译： 涉及使用包含氧化铼和磷酸钍和氧气在内的催化剂的烯烃歧化的方法。

公开(公告)号：US5494870A

公开(公告)日：1996-02-27

申请号：US232731

申请日：1994-04-25

申请人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins

发明人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins

IPC分类号： B01J29/74 ,  C10G45/54 ,  B01J29/06

CPC分类号： C10G45/54 ,  B01J29/7415

摘要： A process and catalyst are provided for the hydrogenation of a hydrocarbon feedstock consisting essentially of hydrocarbon boiling between about 150.degree. F. and 700.degree. F. at atmospheric pressure. The process comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising hydrogenation metals and a support comprising beta zeolite. The hydrogenation metals comprise from about 0.1 percent by weight to about 2.0 percent by weight each of palladium and platinum measured as a percentage of the catalyst. The beta zeolite comprises from about 1 ppm by weight to about 3.0 percent by weight sodium calculated as a percentage of said beta zeolite.

摘要翻译： 提供了一种方法和催化剂，用于氢化烃原料，其基本上由在大气压下在约150°F和700°F之间沸腾的烃组成。 该方法包括在氢化条件下，在包含氢化金属的催化剂和包含β沸石的载体存在下使原料与氢反应。 氢化金属包含以催化剂的百分比测量的钯和铂的约0.1重量％至约2.0重量％。 β-沸石包含以所述β沸石的百分数计算的约1ppm至约3.0重量％的钠。

公开(公告)号：US5489375A

公开(公告)日：1996-02-06

申请号：US255647

申请日：1994-06-08

申请人： Joseph T. Joseph ,  Thomas J. Karol ,  Simon G. Kukes

发明人： Joseph T. Joseph ,  Thomas J. Karol ,  Simon G. Kukes

IPC分类号： C10G47/02 ,  C10G47/26

CPC分类号： C10G47/02 ,  C10G47/26

摘要： Hydroconversion processes employing 2,4-heteroatom-substituted-molybdena-3,3-dioxocyclopentane hydro-conversion catalysts are disclosed. In some embodiments, inexpensive bulk catalysts in accordance with the present invention are synthesized from bulk triglyceridic epoxides or fatty acids.

摘要翻译： 公开了采用2,4-杂原子取代的钼 - 3,3-二氧代环戊烷氢转化催化剂的加氢转化方法。 在一些实施方案中，根据本发明的廉价的本体催化剂由块状甘油三酯环氧化物或脂肪酸合成。

公开(公告)号：US5346874A

公开(公告)日：1994-09-13

申请号：US104780

申请日：1993-08-10

申请人： Frederick T. Clark ,  Simon G. Kukes ,  P. Donald Hopkins

发明人： Frederick T. Clark ,  Simon G. Kukes ,  P. Donald Hopkins

IPC分类号： B01J29/86 ,  B01J37/00 ,  C10G49/08 ,  B01J21/02 ,  B01J29/00

CPC分类号： B01J29/86 ,  C10G49/08 ,  B01J37/0009

摘要： A process and catalyst is provided for the hydrogenation of a hydrocarbon feedstock comprising a substantial portion of a distillate hydrocarbon feedstock, wherein said distillate hydrocarbon feedstock consists essentially of material boiling between about 150.degree. F. and about 700.degree. F. at atmospheric pressure, which comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising from about 0.1% to about 2.0% by weight of palladium and from about 0.1% to about 2.0% by weight of platinum and a support comprising borosilicate, for producing a hydrogenated product.

摘要翻译： 提供了一种方法和催化剂用于包含大部分馏出物烃原料的烃原料的氢化，其中所述馏出物烃原料基本上由在大气压下沸点在约150°F至约700°F之间的材料组成，其中 包括在氢化条件下在催化剂存在下使原料与氢反应，所述催化剂包含约0.1重量％至约2.0重量％的钯和约0.1重量％至约2.0重量％的铂和包含硼硅酸盐的载体，用于生产 氢化产物。

公开(公告)号：US5346612A

公开(公告)日：1994-09-13

申请号：US21530

申请日：1993-02-19

申请人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins

发明人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins

IPC分类号： B01J29/74 ,  C10G45/54 ,  C10G45/00 ,  C10G45/52

CPC分类号： C10G45/54 ,  B01J29/7415

摘要： A process and catalyst are provided for the hydrogenation of a hydrocarbon feedstock consisting essentially of hydrocarbon boiling between about 150.degree. F. and 700.degree. F. at atmospheric pressure. The process comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising hydrogenation metals and a support comprising beta zeolite. The hydrogenation metals comprise from about 0.1 percent by weight to about 2.0 percent by weight each of palladium and platinum measured as a percentage of the catalyst. The beta zeolite comprises from about 1 ppm by weight to about 3.0 percent by weight sodium calculated as a percentage of said beta zeolite.

摘要翻译： 提供了一种方法和催化剂，用于氢化烃原料，其基本上由在大气压下在约150°F和700°F之间沸腾的烃组成。 该方法包括在氢化条件下，在包含氢化金属的催化剂和包含β沸石的载体存在下使原料与氢反应。 氢化金属包含以催化剂的百分比测量的钯和铂的约0.1重量％至约2.0重量％。 β-沸石包含以所述β沸石的百分数计算的约1ppm至约3.0重量％的钠。

公开(公告)号：US5225383A

公开(公告)日：1993-07-06

申请号：US876852

申请日：1992-04-30

申请人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins ,  Lisa M. Green

发明人： Simon G. Kukes ,  Frederick T. Clark ,  P. Donald Hopkins ,  Lisa M. Green

IPC分类号： C10G45/54

CPC分类号： C10G45/54

摘要： A process and catalyst are provided for hydrogenation of a hydrocarbon feedstock consisting essentially of material boiling between about 150.degree. F. and about 700.degree. F. which comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising from about 0.1% to about 2.0% by weight each of palladium and platinum and a support comprising mordenite. The process of the present invention provides substantially improved dearomatization performance, increased desulfurization and denitrogenation, increased distillate product cetane number, increased distillate volume expansion, and utilizes a more durable catalyst.

摘要翻译： 提供了一种方法和催化剂，用于氢化烃原料，其基本上由沸点在约150°F至约700°F之间的材料进行氢化，其包括在氢化条件下使原料与氢气在催化剂存在下反应，所述催化剂包含约0.1％ 至约2.0重量％的钯和铂，以及包含丝光沸石的载体。 本发明的方法提供了显着改进的脱芳构化性能，增加的脱硫和脱氮，增加的馏出物产品十六烷值，增加的馏出物体积膨胀，并且使用更耐用的催化剂。