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51.发明授权Systems having digestion units with capability for loading cellulosic biomass under high pressure and associated methods for cellulosic biomass processing 有权具有消化单元的系统，其具有在高压下加载纤维素生物质的能力和用于纤维素生物质处理的相关方法公开(公告)号：US09175227B2
公开(公告)日：2015-11-03
申请号：US13332329
申请日：2011-12-20
CPC分类号： C10G3/00 , C10G1/065 , C10G2300/1014 , C10G2300/4012 , D21C7/00 , D21C11/00 , Y02P30/20
摘要： When processing cellulosic biomass, it may be desirable for a digestion unit to operate without being fully depressurized for process efficiency purposes. A biomass conversion system can comprise a first digestion unit and a second digestion unit that are operatively connected to one another; a valve separating the first digestion unit from the second digestion unit; a fluid circulation loop establishing fluid communication between an outlet of the first digestion unit and an inlet of the second digestion unit; and a bypass line establishing fluid communication between an outlet of the second digestion unit and the fluid circulation loop.
摘要翻译： 当处理纤维素生物质时，为了过程效率目的，消化单元可能需要操作而没有完全减压。 生物质转化系统可以包括可操作地彼此连接的第一消化单元和第二消化单元; 将所述第一消化单元与所述第二消化单元分离的阀; 流体循环回路，其在所述第一消化单元的出口和所述第二消化单元的入口之间建立流体连通; 以及在第二消化单元的出口和流体循环回路之间建立流体连通的旁通管线。
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52.发明授权Systems capable of adding cellulosic biomass to a digestion unit operating at high pressures and associated methods for cellulosic biomass processing 有权能够将纤维素生物质加入到以高压操作的消化装置的系统以及用于纤维素生物质处理的相关方法的系统公开(公告)号：US08945243B2
公开(公告)日：2015-02-03
申请号：US13332322
申请日：2011-12-20
IPC分类号： C10L1/00
CPC分类号： B01J19/245 , B01J19/24 , B01J2219/24 , C10G1/002 , C10G1/065 , C10G3/42 , C10G2300/1014 , C10L1/02 , C13K1/02 , Y02P30/20
摘要： When processing cellulosic biomass, it may be desirable for a digestion unit to operate without being fully depressurized for process efficiency purposes. Methods for processing cellulosic biomass may comprise providing a biomass conversion system comprising a pressurization zone and a digestion unit that are operatively connected to one another; providing cellulosic biomass at a first pressure; introducing at least a portion of the cellulosic biomass into the pressurization zone and pressurizing the pressurization zone to a second pressure higher than the first pressure; after pressurizing the pressurization zone, transferring at least a portion of the cellulosic biomass from the pressurization zone to the digestion unit, which is at a third pressure that is less than or equal to the second pressure but higher than the first pressure; and digesting at least a portion of the cellulosic biomass in the digestion unit to produce a hydrolysate comprising soluble carbohydrates.
摘要翻译： 当处理纤维素生物质时，为了过程效率目的，消化单元可能需要操作而没有完全减压。 处理纤维素生物质的方法可以包括提供生物质转化系统，其包括可操作地彼此连接的加压区和消化单元; 在第一压力下提供纤维素生物质; 将至少一部分纤维素生物质引入加压区并将加压区加压至高于第一压力的第二压力; 在对加压区进行加压之后，将至少一部分纤维素生物质从加压区转移到消化单元，消化单元处于小于或等于第二压力但高于第一压力的第三压力; 并消化消化单元中的至少一部分纤维素生物质以产生包含可溶性碳水化合物的水解产物。
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53.发明授权Biomass conversion systems having integrated heat management and methods for use thereof 有权具有集成热管理的生物质转换系统及其使用方法公开(公告)号：US08729324B2
公开(公告)日：2014-05-20
申请号：US13332301
申请日：2011-12-20
IPC分类号： C07C1/00
CPC分类号： C10G3/00 , C10G1/002 , C10G1/065 , C10G3/40 , C10G3/52 , C10G2300/1014 , C10G2300/202 , C10G2300/4081 , C10L1/026 , Y02P30/20
摘要： Biomass conversion systems may incorporate integrated heat management to operate more efficiently during biomass conversion. Biomass conversion systems may comprise a first fluid circulation loop comprising a hydrothermal digestion unit, and a first catalytic reduction reactor unit in fluid communication with an inlet and an outlet of the hydrothermal digestion unit; and a second fluid circulation loop comprising a reaction product take-off line in fluid communication with the first fluid circulation loop, a second catalytic reduction reactor unit in fluid communication with the reaction product take-off line, and a recycle line establishing fluid communication between the first fluid circulation loop and an outlet of the second catalytic reduction reactor unit, where the first catalytic reduction reactor unit contains at least one first catalyst and the second catalytic reduction reactor unit contains at least one second catalyst, each being capable of activating molecular hydrogen.
摘要翻译： 生物量转换系统可以结合集成的热管理，在生物质转化过程中更有效地运行。 生物质转化系统可以包括包含水热消解单元的第一流体循环回路和与水热消解单元的入口和出口流体连通的第一催化还原反应器单元; 以及第二流体循环回路，其包括与所述第一流体循环回路流体连通的反应产物输出管线，与所述反应产物输出管线流体连通的第二催化还原反应器单元，以及在所述第二流体循环回路 所述第一流体循环回路和所述第二催化还原反应器单元的出口，其中所述第一催化还原反应器单元包含至少一个第一催化剂，所述第二催化还原反应器单元含有至少一个第二催化剂，每个所述第二催化剂能够活化分子氢 。
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公开(公告)号：US08692041B2
公开(公告)日：2014-04-08
申请号：US13332292
申请日：2011-12-20
IPC分类号： C07C1/02
CPC分类号： C10G1/002 , C07G1/00 , C10G1/00 , C10G2300/1014 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for producing biofuels from biomass is provided by removing sulfur compounds and nitrogen compounds from the biomass by contacting the biomass with a digestive solvent to form a pretreated biomass containing soluble carbohydrates and having less than 35% of the sulfur content and less than 35% of the nitrogen content, based on untreated biomass on a dry mass basis, prior to carrying out aqueous phase reforming and further processing to form a liquid fuel.
摘要翻译： 通过使生物质与消化溶剂接触来除去生物质中的硫化合物和氮化合物，从生物燃料生产生物燃料的方法提供，以形成含有可溶性碳水化合物并具有小于35％硫含量且小于35％ 在进行水相重整和进一步加工以形成液体燃料之前，基于未处理的生物质在干质量基础上的氮含量。
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公开(公告)号：US20120174471A1
公开(公告)日：2012-07-12
申请号：US13331065
申请日：2011-12-20
CPC分类号： C10G3/00 , C10G3/42 , C10G2300/1014 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10L1/04 , Y02P30/20
摘要： Biomass is contacted with an aqueous media to form an extracted biomass. An aqueous liquor separated from the extracted biomass is treated with a purification substrate to form a treated carbohydrate stream having less than 35% of the sulfur content and less than 35% of the nitrogen content, based on the untreated aqueous liquor stream, prior to contact with an aqueous phase reforming catalyst to form oxygenated intermediates that can be further processed to form a liquid fuel. An extracted biomass solids stream is also separated from the extracted biomass which is contacted with a first digestive solvent and then a second digestive solvent to form a solubilized pulp. This solublilized pulp may be combined with the aqueous liquor stream or combined to an aqueous reforming reaction system or recycled to the aqueous media to be processed further for an effective process to produce the liquid fuel.
摘要翻译： 生物质与水性介质接触以形成提取的生物质。 用提取的生物质分离的含水液体用净化底物处理，以在接触之前基于未处理的含水液体流形成具有少于35％的硫含量和小于氮含量的35％的经处理的碳水化合物流 与水相重整催化剂形成氧化中间体，其可进一步加工以形成液体燃料。 提取的生物质固体物流也与提取的生物质分离，其与第一消化溶剂接触，然后与第二消化溶剂接触以形成溶解的纸浆。 这种溶解的纸浆可以与含水液体流合并或与水性重整反应体系结合或再循环到水性介质中以进一步进行处理以产生液体燃料。
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公开(公告)号：US20110154722A1
公开(公告)日：2011-06-30
申请号：US12972154
申请日：2010-12-17
CPC分类号： C10L1/1826 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G2300/1011 , C10G2300/4025 , C10G2300/44 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/1824 , Y02E50/13 , Y02E50/30 , Y02P30/20 , Y02T50/678
摘要： A method comprises providing a bio-based feedstock; contacting the bio-based feedstock with a solvent in a hydrolysis reaction to form an intermediate stream comprising carbohydrates; contacting the intermediate stream with an apr catalyst to form a plurality of oxygenated intermediates, wherein a first portion of the oxygenated intermediates are recycled to form the solvent; and processing at least a second portion of the oxygenated intermediates to form a fuel blend.
摘要翻译： 一种方法包括提供基于生物的原料; 在水解反应中使生物基原料与溶剂接触以形成包含碳水化合物的中间物流; 使中间流与apr催化剂接触以形成多个含氧中间体，其中将氧化中间体的第一部分再循环以形成溶剂; 以及处理所述氧化中间体的至少第二部分以形成燃料混合物。
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公开(公告)号：US20080154071A1
公开(公告)日：2008-06-26
申请号：US11950294
申请日：2007-12-04
IPC分类号： C07C29/141
CPC分类号： C07C29/141 , C07C29/80 , C07C45/58 , C07C45/64 , C07C45/80 , C07C47/19 , C07C31/205
摘要： The invention provides a process for preparing 1,3-alkanediols, such as 1,3-propanediol (PDO), from 3-hydroxyaldehydes, such as 3-hydroxypropanal (HPA), comprising providing a mixture of 3-hydroxyaldehydes in an organic solvent; extracting into an aqueous liquid a major portion of the 3-hydroxyaldehydes to provide an aqueous phase comprising 3-hydroxyaldehydes in greater concentration than the concentration of 3-hydroxyaldehydes in the 3-hydroxyaldehyde mixture, and an organic phase; separating the aqueous phase from the organic phase; contacting the aqueous phase with hydrogen in the presence of a hydrogenation catalyst to provide a hydrogenation product mixture comprising 1,3-alkanediols and water; separating water from the 1,3-alkanediols using a multi-effect evaporation scheme; recycling water containing about 50 wt % or less 1,3-propanediol based upon the total amount of 1,3-propanediol and water to the extraction stage; and recovering 1,3-alkanediols.
摘要翻译： 本发明提供了从3-羟基醛如3-羟基丙醛（HPA）制备1,3-烷二醇如1,3-丙二醇（PDO）的方法，其包括在有机溶剂中提供3-羟基醛的混合物 ; 将大部分3-羟基醛萃取到含水液体中以提供包含3-羟基醛的水相，其浓度高于3-羟基醛混合物中3-羟基醛的浓度和有机相; 将水相与有机相分离; 在氢化催化剂存在下使水相与氢气接触，以提供包含1,3-烷二醇和水的氢化产物混合物; 使用多效蒸发方案从1,3-烷二醇分离水; 基于1,3-丙二醇和水的总量将含有约50重量％或更少的1,3-丙二醇的水循环到萃取阶段; 并回收1,3-链烷二醇。
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58.发明授权Solid acid catalyzed reactive stripping of impurities formed during the production of 1, 3-propanediol 失效在制备1,3-丙二醇期间形成的固体酸催化反应性汽提公开(公告)号：US06972346B2
公开(公告)日：2005-12-06
申请号：US10676796
申请日：2003-10-01
IPC分类号： C07C29/141 , C07C29/80 , C07C29/88 , C07C31/18 , C07C27/26 , C07C27/28 , C07C29/74 , C07C31/20
CPC分类号： C07C29/141 , C07C29/80 , C07C29/88 , C07C31/205
摘要： A process for producing 1,3-propanediol comprising the steps of: a) forming an aqueous solution of 3-hydroxypropanal, b) hydrogenating the 3-hydroxypropanal to form a first crude 1,3-propanediol mixture comprising 1,3-propanediol, water, and MW 132 cyclic acetal, c) distilling the first crude 1,3-propanediol mixture to remove water and low boiling impurities and form a second crude 1,3-propanediol mixture, d) contacting the second crude 1,3-propanediol mixture with a solid acid purifier at a temperature of from about 50 to about 250° C. to convert the MW 132 cyclic acetal to more volatile cyclic acetals, and e) separating the more volatile cyclic acetals from the 1,3-propanediol by distillation or gas stripping.
摘要翻译： 一种生产1,3-丙二醇的方法，包括以下步骤：a）形成3-羟基丙醛水溶液，b）氢化3-羟基丙醛以形成第一种1,3-丙二醇混合物，其包括1,3-丙二醇， 水和MW 132环缩醛，c）蒸馏第一粗1,3-丙二醇混合物以除去水和低沸点杂质，并形成第二粗1,3-丙二醇混合物，d）使第二粗1,3-丙二醇 与固体酸性净化器的混合物在约50至约250℃的温度下将MW 132环状缩醛转化为更易挥发的环状缩醛，以及e）通过蒸馏从1,3-丙二醇中分离更易挥发的环状缩醛 或气体剥离。
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公开(公告)号：US06545190B2
公开(公告)日：2003-04-08
申请号：US09963068
申请日：2001-09-25
IPC分类号： C07C2700
CPC分类号： C07C29/16 , Y02P20/582 , Y02P20/584 , C07C31/205
摘要： Disclosed is a one step hydroformylation process for preparing a 1,3-diol, comprising the reaction of an oxirane with syngas at hydroformylation conditions in an inert solvent in the presence of a hydroformylation catalyst comprising a ruthenium (+1)-phosphine bidentate: cobalt (−1) complex, wherein the ligated metal is ruthenium, under conditions which preferably upon completion of the oxirane/syngas reaction cause a phase separation of the reaction mixture into a solvent phase which is rich in catalyst and a second phase which is rich in the 1,3-diol, recycling the phase rich in catalyst directly to the hydroformylation reaction for further reaction with previously unreacted starting materials, thus permitting valuable hydroformylation catalyst to be recycled without degradation or exposure to downstream processing and recovering the 1,3-diol from the second phase rich in 1,3-diol.
摘要翻译： 公开了一种用于制备1,3-二醇的一步加氢甲酰化方法，其包括在加氢甲酰化条件下，在惰性溶剂中，在加氢甲酰化催化剂存在下，环氧乙烷与合成气的反应，所述加氢甲酰化催化剂包含钌（+1） - 膦二齿：钴 （-1）络合物，其中连接的金属是钌，在优选在完成环氧乙烷/合成气反应的条件下，使反应混合物相分离成富含催化剂的溶剂相和富含 该1,3-二醇将富含催化剂的相直接再循环到加氢甲酰化反应中以进一步与先前未反应的起始原料反应，从而允许有价值的加氢甲酰化催化剂再循环而不降解或暴露于下游加工并回收1,3-二醇 从第二阶段富含1,3-二醇。
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公开(公告)号：US06518466B2
公开(公告)日：2003-02-11
申请号：US09957279
申请日：2001-09-20
申请人： John Frederick Knifton , Lynn Henry Slaugh , Paul Richard Weider , Talmadge Gail James , Joseph Broun Powell , Kevin Dale Allen , Timothy Scott Williams
发明人： John Frederick Knifton , Lynn Henry Slaugh , Paul Richard Weider , Talmadge Gail James , Joseph Broun Powell , Kevin Dale Allen , Timothy Scott Williams
IPC分类号： C07C2700
CPC分类号： B01J31/2409 , B01J31/20 , B01J31/24 , B01J31/2414 , B01J31/248 , B01J2231/48 , B01J2531/821 , B01J2531/845 , C07C29/16 , Y02P20/52 , Y02P20/584 , C07C31/205
摘要： The invention provides a process for an improved oxirane hydroformylation catalyst, the improved oxirane hydroformylation catalyst, and a one step process for preparing a 1,3-diol in the presence of such a catalyst. One process for preparing the hydroformylation catalyst involves: a) forming a complex (A) by contacting a ruthenium(0) compound with a ditertiary phosphine ligand; and b) forming a complex (B) by subjecting complex (A) to a redox reaction with a cobalt(0) carbonyl compound. This catalyst is used in a one step hydroformylation process for preparing a 1,3-diol, comprising the reaction of an oxirane with syngas at hydroformylation conditions in an inert solvent in the presence of the above hydroformylation catalyst where recovery of product is preferably accomplished via phase separation of a diol rich phase from the bulk reaction liquor.
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