Process for preparing solid base catalyst
    51.
    发明授权
    Process for preparing solid base catalyst 失效
    固体碱催化剂的制备方法

    公开(公告)号:US4711873A

    公开(公告)日:1987-12-08

    申请号:US896951

    申请日:1986-08-15

    摘要: A solid base with improved properties, particularly excellent catalytic performance is prepared by reacting alumina and an alkali metal hydroxide at a temperature of from 200.degree. to 500.degree. C. and followed by reacting the resultant product with an alkali metal at a temperature of from 180.degree. to 350.degree. C. or reacting water-containing alumina and an alkali metal in such an amount that corresponds to a molar equivalent of water contained in alumina at a temperature in a range between a melting point of the alkali metal and 500.degree. C. and then reacting the reaction product with an alkali metal at a temperature of from 180.degree. to 350.degree. C.

    摘要翻译: 通过氧化铝和碱金属氢氧化物在200〜500℃的温度下反应制备具有改善性能,特别优异催化性能的固体碱,然后使所得产物与碱金属在180℃的温度下反应 在350℃下反应,或使含水氧化铝和碱金属反应,其量相当于在碱金属的熔点和500℃之间的范围内的氧化铝中所含的水的摩尔当量。 然后使反应产物与碱金属在180至350℃的温度下反应。

    Process for producing 5-halomethylfurfural
    54.
    发明授权
    Process for producing 5-halomethylfurfural 失效
    5-卤代甲基糠醛的制备方法

    公开(公告)号:US4424390A

    公开(公告)日:1984-01-03

    申请号:US437254

    申请日:1982-10-28

    CPC分类号: C07D307/46

    摘要: A process for producing 5-halomethylfurfural represented by the formula, ##STR1## wherein X is Cl or Br, which comprises carrying out a acid-decomposition of saccharide in a water/organic solvent/magnesium halide system with hydrochloric acid, sulfuric acid, hydrogen chloride or other mineral acid in the presence or absence of surface active agent as a catalyst. The 5-halomethylfurfural is useful as an intermediate of medicines, agricultural chemicals, perfumes and the like.

    摘要翻译: 一种由下式表示的5-卤代甲基糠醛的方法,其中X是Cl或Br,其中包括用盐酸,硫酸,氢气在水/有机溶剂/卤化镁体系中进行糖分解 氯化物或其他无机酸在表面活性剂的存在或不存在下作为催化剂。 5-卤代甲基糠醛可用作药物,农药,香料等的中间体。

    Chiral copper complex and production processes thereof and using the same
    55.
    发明授权
    Chiral copper complex and production processes thereof and using the same 失效
    手性铜络合物及其制备方法及其使用

    公开(公告)号:US07009079B2

    公开(公告)日:2006-03-07

    申请号:US10625604

    申请日:2003-07-24

    IPC分类号: C07C251/24

    摘要: There is disclosed an optically active salicylideneaminoalcohol compound of formula (1): wherein R1 represents an alkyl group or the like, R2 represents an aryl group and the like, and when X1 represents a nitro, X2 is a hydrogen atom, when X1 represents a chlorine atom, X2 is a chlorine atom, and when X1 is a hydrogen atom, X2 is a fluorine atom; and the carbon atom denoted by “*” is an asymmetric carbon atom having either an S or R configuration, and a chiral copper complex produced from the optically active salicylidenaminoalcohol compound and a copper compound.

    摘要翻译: 公开了式(1)的光学活性亚水杨基氨基醇化合物:其中R 1代表烷基等,R 2代表芳基等,和 当X 1代表硝基时,X 2是氢原子,当X 1表示氯原子时,X 2是氢原子, SUB>是氯原子,当X 1是氢原子时,X 2是氟原子; 并且由“*”表示的碳原子是具有S或R构型的不对称碳原子和由光学活性水杨酰氨基醇化合物和铜化合物制备的手性铜络合物。

    Optically active bisoxazoline compounds, production and use thereof
    56.
    发明授权
    Optically active bisoxazoline compounds, production and use thereof 有权
    光学活性的双恶唑啉化合物,其生产和使用

    公开(公告)号:US6072081A

    公开(公告)日:2000-06-06

    申请号:US128971

    申请日:1998-08-04

    摘要: An optically active bisoxazoline compound of the formula [I]: ##STR1## wherein R.sub.1 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted or alkoxy group and two geminal alkyl groups may be joined together to form a cyclic structure;R.sub.2 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted;R.sub.3 represents hydrogen atom, (C2-C4)alkyl group or cycloalkyl group; andthe asterisk * represents an asymmetric carbon atom.

    摘要翻译: 式[I]的光学活性双恶唑啉化合物:其中R1表示烷基,环烷基,芳烷基,可被取代的苯基或烷氧基和两个偕烷基可以连接在一起形成环状结构; R2代表烷基,环烷基,芳烷基,可被取代的苯基; R3表示氢原子,(C2-C4)烷基或环烷基; 星号*表示不对称碳原子。

    Process for producing optically active cyclopropanecaboxylic acid esters
    57.
    发明授权
    Process for producing optically active cyclopropanecaboxylic acid esters 失效
    光学活性环丙烷甲酸酯的制备方法

    公开(公告)号:US6011169A

    公开(公告)日:2000-01-04

    申请号:US113502

    申请日:1998-07-10

    IPC分类号: C07C67/347 C07C69/74

    CPC分类号: C07C67/347

    摘要: A process for producing an optically active cyclopropanecarboxylic acid ester which is characterized by reacting a prochiral olefin with a diazoacetic acid ester in the presence of a copper complex obtained by reacting an optically active bisoxazoline ligand with a copper compound.

    摘要翻译: 一种光学活性环丙烷羧酸酯的制备方法,其特征在于使前手性烯烃与重氮乙酸酯在光学活性双恶唑啉配体与铜化合物反应得到的铜络合物存在下反应。