公开(公告)号：US07408017B2

公开(公告)日：2008-08-05

申请号：US11155599

申请日：2005-06-20

申请人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

发明人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC分类号： C08G63/688

CPC分类号： G03G9/08755 ,  C08G63/6882 ,  C12P7/625 ,  C12P11/00 ,  G03G9/08791 ,  G03G9/09733 ,  G03G9/09775

摘要： A polyhydroxyalkanoate is disclosed which has in the molecule a unit represented by Chemical Formula (1). wherein R is arbitrarily selected from a hydrogen atom, a halogen atom, CN, NO2, COOR′, SO2R″, CH3, C2H5, C3H7, C(CH3)2H and C(CH3)3; where R′ is H, Na, K, CH3 or C2H5, and R″ is OH, ONa, OK, a halogen atom, OCH3 or OC2H5; and x is an integer arbitrarily selected from 1 to 8; with the proviso that a polyhydroxyalkanoate is excluded which has a hydrogen atom as R and x in all the units is 2 or 4. Also disclosed is a process for producing the polyhydroxyalkanoate by the use of a microorganism having the ability to produce the polyhydroxyalkanoate and accumulate it in the bacterial body.

摘要翻译： 公开了在分子中具有由化学式（1）表示的单元的聚羟基链烷酸酯。 其中R可以任选地选自氢原子，卤原子，CN，NO 2，COOR'，SO 2 R“，CH 3 C 2 H 3，C 3 H 3，C（CH 3）3 H 3，C 3 H 3， 2）H和C（CH 3 3）3。 其中R'是H，Na，K，CH 3或C 2 H 5，并且R“是OH，ONa，OK， 卤素原子，OCH 3或OC 2 H 5; x是任意选自1至8的整数; 条件是排除了具有氢原子作为R的聚羟基链烷酸酯，并且所有单元中的x均为2或4.还公开了通过使用具有生产聚羟基链烷酸酯的能力的微生物来生产聚羟基链烷酸酯并累积 它在细菌体内。

公开(公告)号：US20070155912A1

公开(公告)日：2007-07-05

申请号：US10579805

申请日：2005-06-09

申请人： Takashi Kenmoku ,  Chieko Mihara ,  Tatsuki Fukui ,  Ako Kusakari ,  Tetsuya Yano

发明人： Takashi Kenmoku ,  Chieko Mihara ,  Tatsuki Fukui ,  Ako Kusakari ,  Tetsuya Yano

IPC分类号： C08F20/00

CPC分类号： C08G63/6882 ,  C08G63/6852 ,  C08G63/912

摘要： A novel polyhydroxyalkanoate having a reactive functional group in a molecule and a method of producing the same; and a novel polyhydroxyalkanoate having a new function obtained by chemically modifying the polyhydroxyalkanoate having a reactive functional group and a method of producing the same. A polyhydroxyalkanoate containing units having a carboxyl group, an amide group, and a sulfonic group in a molecule is induced.

摘要翻译： 分子中具有反应性官能团的新型聚羟基链烷酸酯及其制造方法， 和具有通过化学改性具有反应性官能团的聚羟基链烷酸酯获得的新功能的新型聚羟基链烷酸酯及其制备方法。 诱导分子中含有羧基，酰胺基和磺酸基的单元的聚羟基链烷酸酯。

公开(公告)号：US20060040196A1

公开(公告)日：2006-02-23

申请号：US10532136

申请日：2003-10-24

申请人： Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

发明人： Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC分类号： G03G9/087

CPC分类号： G03G9/08791 ,  C08G63/6882 ,  C08G63/912 ,  C08L23/10 ,  C08L25/06 ,  C08L67/02 ,  C08L67/04 ,  C08L75/00 ,  C08L77/00 ,  C12P7/625 ,  G03G9/08755 ,  G03G9/08757 ,  Y10T428/24083 ,  Y10T428/24099 ,  Y10T428/2424 ,  Y10T428/24322 ,  C08L2666/04 ,  C08L2666/02

摘要： A polyhydroxyalkanoate copolymer comprises one kind of unit of —[OCH((CH2)x—SOC6H5R)CH2CO]— (n=1-7)   (1) (wherein R is any one of H, halogen, CN, NO2, COOR′, SO2R″ (R′ is any one of H, Na, K, CH3 and C2H5; R″ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2—CH and (CH3)3—C) and —[OCH((CH2)x—SO2C6H5R)CH2CO]— (n=1-7)   (2) (wherein R is any one of H, halogen, CN, NO2, COO R′, SO2R″ (R′ is any one of H, Na, K, CH3 and C2H5; R″ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2—CH and (CH3)3—C) and at least one unit of chemical formulae (3) to (6): —[OCH((CH2)m—Rz)CH2CO]— (n=1-8)   (3) (wherein Rz comprises a residue having either a phenyl structure or a thienyl structure), —[OCH((CH2)k—C6H11Ra)CH2CO]— (n=1-8)   (4) (wherein Ra is any one of H, CN, NO2, halogen, CH3, C2H5, C3H7, CF3, C2F5 and C3F7) —[OCH((CH2)n—CH═CH2)CH2CO]— (n=1-8)   (5), and —[OCH((CH2)n—COORb)CH2CO]— (n=1-8)   (6) (wherein Rb is any one of H, Na and K).

公开(公告)号：US20050260514A1

公开(公告)日：2005-11-24

申请号：US10532137

申请日：2003-10-23

申请人： Chieko Mihara ,  Tetsuya Yano ,  Shinya Kozaki ,  Tstutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

发明人： Chieko Mihara ,  Tetsuya Yano ,  Shinya Kozaki ,  Tstutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC分类号： C08G63/06 ,  C08G63/688 ,  G03G9/087 ,  G03G9/097

CPC分类号： C08G63/06 ,  C08G63/6882 ,  G03G9/08755 ,  G03G9/097

摘要： The present invention provides a negataively chargeable charge controlling agent to control a charged state of a powder or granular material such as toner for electrophotography, where the agent comprises a polyhydroxyalkanoate having at least one kind of 3-hydroxy-ω-carboxyalkanoic acid unit represented by the chemical formula (1): wherein n is an integer selected from 1 to 8; R1 is an H, Na or K atom, or and when more than one unit exists, n and R1 is the same or different between the units. The charge controlling agent is excellent in electrophtographic properties and propitious to environment because of the biodegradability of the polyhydroxyalkanoate. wherein n is an integer selected from the range shown in the same chemical formula; R1 is an H atom, Na atom, K atom, or and when more than one unit exists, n and R1 may differ from unit to unit.

摘要翻译： 本发明提供一种负电荷电荷控制剂，用于控制电子照相用调色剂等粉末或颗粒状物质的带电状态，其中该试剂包含具有至少一种3-羟基-ω-羧酸烷基酯的聚羟基链烷酸酯单元， 化学式（1）：其中n是选自1至8的整数; R 1是H，Na或K原子，或者当存在多于一个单元时，单元之间的n和R 1相同或不同。 电荷控制剂由于聚羟基链烷酸酯的生物降解性而具有优异的电泳性质和有利于环境的作用。 其中n是选自相同化学式所示范围的整数; R 1是H原子，Na原子，K原子，或者当存在多于一个单元时，n和R 1可以不同于单元。

公开(公告)号：US20050250191A1

公开(公告)日：2005-11-10

申请号：US11155599

申请日：2005-06-20

申请人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

发明人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC分类号： C08G63/688 ,  C12P7/62 ,  C12P11/00 ,  G03G9/087 ,  G03G9/097 ,  C08G63/68

CPC分类号： G03G9/08755 ,  C08G63/6882 ,  C12P7/625 ,  C12P11/00 ,  G03G9/08791 ,  G03G9/09733 ,  G03G9/09775

摘要： A polyhydroxyalkanoate is disclosed which has in the molecule a unit represented by Chemical Formula (1). wherein R is arbitrarily selected from a hydrogen atom, a halogen atom, CN, NO2, COOR′, SO2R″, CH3, C2H5, C3H7, C(CH3)2H and C(CH3)3; where R′ is H, Na, K, CH3 or C2H5, and R″ is OH, ONa, OK, a halogen atom, OCH3 or OC2H5; and x is an integer arbitrarily selected from 1 to 8; with the proviso that a polyhydroxyalkanoate is excluded which has a hydrogen atom as R and x in all the units is 2 or 4. Also disclosed is a process for producing the polyhydroxyalkanoate by the use of a microorganism having the ability to produce the polyhydroxyalkanoate and accumulate it in the bacterial body.

摘要翻译： 公开了在分子中具有由化学式（1）表示的单元的聚羟基链烷酸酯。 其中R可以任选地选自氢原子，卤原子，CN，NO 2，COOR'，SO 2 R“，CH 3 C 2 H 3，C 3 H 3，C（CH 3）3 H 3，C 3 H 3， 2）H和C（CH 3 3）3。 其中R'是H，Na，K，CH 3或C 2 H 5，并且R“是OH，ONa，OK， 卤原子，OCH 3或OC 2 H 5; x是任意选自1至8的整数; 条件是排除了具有氢原子作为R的聚羟基链烷酸酯，并且所有单元中的x均为2或4.还公开了通过使用具有生产聚羟基链烷酸酯的能力的微生物来生产聚羟基链烷酸酯并累积 它在细菌体内。

公开(公告)号：US07078200B2

公开(公告)日：2006-07-18

申请号：US10603996

申请日：2003-06-26

申请人： Tsutomu Honma ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Takashi Kenmoku

发明人： Tsutomu Honma ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Takashi Kenmoku

IPC分类号： C12P7/62 ,  C08G63/06 ,  C08G63/78

CPC分类号： C12P7/625 ,  C08G63/06 ,  C08G63/6822 ,  C08G63/6852

摘要： A method for producing a polyhydroxyalkanoate using a microorganism capable of substantially reducing unintended monomer units and obtaining the polyhydroxyalkanoate in a high yield. A microorganism capable of synthesizing a novel polyhydroxyalkanoate having 3-hydroxy-substituted benzoylalkanoic acid as a monomer unit, using a substituted benzoylalkanoic acid as a material, is cultured in a medium containing a substituted benzoylalkanoic acid. Then, the polyhydroxyalkanoate produced in the cultured bacteria is extracted and recovered.

摘要翻译： 使用能够显着降低非预期的单体单元并以高产率获得聚羟基链烷酸酯的微生物制备聚羟基链烷酸酯的方法。 在含有取代的苯甲酰基链烷酸的培养基中培养能够以取代的苯甲酰基链烷酸为原料合成具有3-羟基取代的苯甲酰基链烷酸作为单体单元的新型聚羟基链烷酸酯的微生物。 然后，提取并回收在培养细菌中产生的聚羟基链烷酸酯。

公开(公告)号：US06858367B2

公开(公告)日：2005-02-22

申请号：US10133378

申请日：2002-04-29

申请人： Tetsuya Yano ,  Etsuko Sugawa ,  Takeshi Imamura ,  Takashi Kenmoku

发明人： Tetsuya Yano ,  Etsuko Sugawa ,  Takeshi Imamura ,  Takashi Kenmoku

IPC分类号： C08G63/06 ,  C08G63/682 ,  C08L67/04 ,  C08L101/00 ,  C08L101/16 ,  G03G9/087 ,  G03G15/16 ,  G03G9/00

CPC分类号： C08G63/06 ,  C08G63/6822 ,  G03G9/08755

摘要： A binder resin which forms a resin powdery product such as a toner for developing electrostatic latent images. The binder resin comprises a biodegradable resin comprising a polyhydroxyalkanoate produced by culturing a microorganism and having as a specific monomer unit a 3-hydroxyalkanoic acid such as 3-hydroxy-5-phenylvaleric acid. This binder resin has very good properties as a binder resin and also has a high safety to human bodies and environment. Also disclosed are a toner for developing electrostatic latent images which contains such a binder resin, and an image-forming method and an image-forming apparatus which make use of the toner.

摘要翻译： 形成树脂粉末产品的粘结剂树脂，例如用于显影静电潜像的调色剂。 粘合剂树脂包括生物降解性树脂，其包含通过培养微生物而产生的聚羟基链烷酸酯，并且具有作为特定单体单元的3-羟基烷酸如3-羟基-5-苯基戊酸。 该粘合剂树脂作为粘合剂树脂具有非常好的性能，并且对人体和环境具有高安全性。 还公开了一种用于显影含有这种粘合剂树脂的静电潜像的调色剂，以及使用调色剂的图像形成方法和图像形成装置。

公开(公告)号：US06635782B2

公开(公告)日：2003-10-21

申请号：US09951720

申请日：2001-09-14

申请人： Tsutomu Honma ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Takashi Kenmoku

发明人： Tsutomu Honma ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Takashi Kenmoku

IPC分类号： C07C6976

CPC分类号： C12P7/625 ,  C08G63/06 ,  C08G63/6822 ,  C08G63/6852

摘要： To provide a novel polyhydroxyalkanoate and a manufacturing method by a microorganism capable of substantially reducing unintended monomer units and obtaining the polyhydroxyalkanoate in a high yield. A microorganism capable of synthesizing a novel polyhydroxyalkanoate having 3-hydroxy-substituted benzoylalkanoic acid as a monomer unit using a substituted benzoylalkanoic acid as a material is cultured in the medium containing a substituted benzoylalkanoic acid, then the polyhydroxyalkanoate produced in the cultured bacteria is extracted and recovered.

摘要翻译： 提供一种新型的聚羟基链烷酸酯及其制造方法，该微生物能够基本上减少非预期的单体单元并以高产率获得聚羟基链烷酸酯。 在含有取代的苯甲酰基链烷酸的培养基中培养能够使用取代的苯甲酰基链烷酸合成具有3-羟基取代的苯甲酰基链烷酸作为单体单元的新型聚羟基链烷酸酯的微生物，然后提取培养细菌中产生的聚羟基链烷酸酯， 恢复。

公开(公告)号：US07056708B2

公开(公告)日：2006-06-06

申请号：US10410349

申请日：2003-04-10

申请人： Takashi Kenmoku ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Tsutomu Honma

发明人： Takashi Kenmoku ,  Etsuko Sugawa ,  Tetsuya Yano ,  Takeshi Imamura ,  Tsutomu Honma

IPC分类号： C12P11/00 ,  C12P7/62

CPC分类号： C08G63/6882 ,  C12P7/625 ,  C12P11/00

摘要： The present invention provides a method of effectively producing polyhydroxyalkanoate having an aromatic substituted residue in its monomer unit. In the method of producing polyhydroxyalkanoate by using microorganisms, microorganisms capable of producing polyhydroxyalkanoate are cultured in a culture medium containing at least one starting compound selected from the group consisting of substituted alkanes represented by formula (1) to produce polyhydroxyalkanoate having, in its molecule, at least one unit selected from the group consisting of 3-hydroxy-substituted alkanoate units represented by formula (2): R—(CH2)n—CH2—CH2—CH3  (1) wherein R represents a residue containing a substituted aromatic ring, and n represents any integer of 1 to 8; wherein R represents a residue containing a substituted aromatic ring, and n represents any integer of 1 to 8. In formulas (1) and (2), a residue R is as described in the specification.

摘要翻译： 本发明提供了在其单体单元中有效制备具有芳族取代残基的聚羟基链烷酸酯的方法。 在通过使用微生物制备聚羟基链烷酸酯的方法中，能够在含有选自由式（1）表示的取代烷烃中的至少一种起始化合物的培养基中培养能够产生聚羟基链烷酸酯的微生物，从而产生在其分子中具有的聚羟基链烷酸酯， 选自由式（2）表示的3-羟基取代的链烷酸酯单元中的至少一个单元：<？in-line-formula description =“In-line Formulas”end =“lead”？> R-（CH （2）-CH 2 CH 2 CH 2 CH 2（1） 其中，R表示含有取代芳环的残基，n表示1〜8的整数，n表示1〜8的整数。 其中R表示含有取代芳环的残基，n表示1至8的任何整数。在式（1）和（2）中，残基R如说明书所述。

公开(公告)号：US06777153B2

公开(公告)日：2004-08-17

申请号：US10105305

申请日：2002-03-26

申请人： Tetsuya Yano ,  Etsuko Sugawa ,  Takeshi Imamura ,  Tsutomu Honma ,  Takashi Kenmoku

发明人： Tetsuya Yano ,  Etsuko Sugawa ,  Takeshi Imamura ,  Tsutomu Honma ,  Takashi Kenmoku

IPC分类号： G03G900

CPC分类号： C08G63/6882 ,  C12P7/62 ,  G03G9/08755 ,  G03G9/08791 ,  Y10S435/874 ,  Y10S435/877

摘要： A polyhydroxyalkanoate characterized by having in the molecule a unit represented by Chemical Formula (1): wherein n may assume any one integral value within the range of from 1 to 8. Also disclosed are a process for producing the polyhydroxyalkanoate by the use of a microorganism having the ability to produce the polyhydroxyalkanoate and accumulate it in the bacterial body; a charge control agent, a toner binder and a toner which contain this polyhydroxyalkanoate; and an image-forming method and an image-forming apparatus which make use of the toner.

摘要翻译： 特征在于在分子中具有由化学式（1）表示的单元的聚羟基链烷酸酯：其中n可以在1至8的范围内呈现任何一个整数值。还公开了通过使用微生物制备聚羟基链烷酸酯的方法 具有生产聚羟基链烷酸酯并将其积聚在细菌体内的能力; 电荷控制剂，调色剂粘合剂和含有该聚羟基链烷酸酯的调色剂; 以及利用调色剂的图像形成方法和图像形成装置。