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公开(公告)号：US07780879B2
公开(公告)日：2010-08-24
申请号：US12316993
申请日：2008-12-18
摘要： The instant invention pertains to a method and a fluid composition for producing contact lenses with improved lens quality and with increased product yield. The method of the invention involves adding a phospholipid into a fluid composition including a lens-forming material in an amount sufficient to reduce an averaged mold separation force by at least about 40% in comparison with that without the phospholipids.
摘要翻译： 本发明涉及一种用于制造具有改善的镜片质量和增加的产品产量的隐形眼镜的方法和流体组合物。 本发明的方法包括将磷脂添加到包含透镜形成材料的流体组合物中，其量足以将平均的模具分离力与没有磷脂的模具分离力相比降低至少约40％。
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公开(公告)号：US5408280A
公开(公告)日：1995-04-18
申请号：US805733
申请日：1991-12-09
摘要： The invention relates to a process for rendering contact lenses hydrophilic, which comprises treating a contact lens with a compound of formula IAr--Z--Ar' (I)wherein Ar and Ar' are each independently of the other an aromatic radical that may be substituted by lower alkoxy and/or by lower alkyl and wherein one of the radicals Ar and Ar' or both radicals Ar and Ar' contain one or more substituents X selected independently of one another from a polar functional group Y, lower alkyl substituted by a polar functional group Y, and lower alkoxy substituted by a polar functional group Y, and wherein Z is a divalent group that separates Ar and Ar' from each other by from one to six atoms. The invention relates also to contact lenses treated according to the invention and to the use of compounds of formula I in the process according to the invention.
摘要翻译： 本发明涉及一种使隐形眼镜亲水化的方法，其包括用式I Ar-Z-Ar'（I）化合物处理隐形眼镜，其中Ar和Ar'各自独立地为可以是芳族基团 被低级烷氧基和/或被低级烷基取代，并且其中一个基团Ar和Ar'或两个基团Ar和Ar'含有一个或多个从极性官能团Y彼此独立选择的取代基X，被 极性官能团Y和被极性官能团Y取代的低级烷氧基，其中Z是使Ar和Ar'彼此分开1至6个原子的二价基团。 本发明还涉及根据本发明处理的隐形眼镜和根据本发明的方法中式I化合物的用途。
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公开(公告)号：US5196493A
公开(公告)日：1993-03-23
申请号：US691626
申请日：1991-04-25
IPC分类号： C08F220/18 , C08F20/10 , C08F20/22 , C08F30/08 , C08F220/22 , C08F230/08 , C08F290/06 , G02B1/04 , G02C7/04
CPC分类号： G02B1/043 , C08F220/22 , C08F230/08 , C08F290/068
摘要： The present invention relates to novel polymers, to processes for the preparation thereof, to contact lenses consisting substantially of those polymers and to processes for the manufacture thereof and to the use of the novel polymers for the manufacture of contact lenses. The polymers according to the invention are especially the copolymerisation products of monomer mixtures comprising the following monomers:a) 20-60% siloxane monovinyl componentb) 1-25% siloxane oligovinyl componentc) 10-55% fluorine-containing vinyl componentd) 3-30% hydrophobic vinyl component having a bulky hydrocarbon radical,e) 0-10% hydrophilic vinyl componentf) 0-15% additional cross-linking vinyl component.The novel polymers and the contact lenses made therefrom are distinguished by a high degree of hardness while at the same time being highly permeable to oxygen.
摘要翻译： 本发明涉及新型聚合物，其制备方法，基本上由这些聚合物组成的隐形眼镜及其制造方法以及用于制造隐形眼镜的新型聚合物的用途。 根据本发明的聚合物特别是包含以下单体的单体混合物的共聚产物：a）20-60％硅氧烷单乙烯基组分b）1-25％硅氧烷低聚乙烯基组分c）10-55％含氟乙烯基组分d） 3-30％具有大体积烃基的疏水乙烯基组分，e）0-10％亲水性乙烯基组分f）0-15％额外的交联乙烯基组分。 新型聚合物和由其制成的隐形眼镜的特征在于高度的硬度，同时对氧气具有高度透气性。
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公开(公告)号：US08383744B2
公开(公告)日：2013-02-26
申请号：US12783591
申请日：2010-05-20
IPC分类号： C08F30/08
CPC分类号： C08F283/124 , B29D11/00038 , C08F290/068 , G02B1/043 , C08L83/04 , C08L51/085 , C08F220/56 , C08F220/20
摘要： The invention provide a class of actinically-crosslinkable silicone-containing prepolymers which comprise dangling polysiloxane chains each having a terminal ethylenically-unsaturated group and are obtained in a one-step of RAFT polymerization of a reactive mixture comprising a polysiloxane crosslinker, a hydrophilic vinylic monomer, a RAFT agent, and a free-radical initiator. The present invention is also related to silicone hydrogel contact lenses made from a prepolymer of the invention and methods for making the contact lenses in a cost-effective way and with high consistency and high fidelity to the original lens design.
摘要翻译： 本发明提供一类具有光聚合性的含硅氧烷的预聚物，其包含悬链聚硅氧烷链，每个聚硅氧烷链均具有末端烯键式不饱和基团，并且在包括聚硅氧烷交联剂，亲水性乙烯基单体的反应性混合物的一步RAFT聚合反应中获得 ，RAFT试剂和自由基引发剂。 本发明还涉及由本发明的预聚物制成的硅酮水凝胶隐形眼镜以及以成本有效的方式制造隐形眼镜并以与原始透镜设计的高一致性和高保真度的方法。
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公开(公告)号：US20120252921A1
公开(公告)日：2012-10-04
申请号：US13433329
申请日：2012-03-29
申请人： Bernhard Seiferling , Thomas Schmidt , Jürgen Vogt
发明人： Bernhard Seiferling , Thomas Schmidt , Jürgen Vogt
摘要： There is described a composition for forming an contact lens, in particular for forming a silicone hydrogel contact lens, comprising at least one first vinylic monomer or macromer having one first ethylenically unsaturated group and at least one second vinylic monomer or macromer having one second ethylenically unsaturated group, wherein the first and second ethylenically unsaturated groups are different from each other and wherein the composition further comprises a crosslinker with at least two ethylenically unsaturated (polymerizable) groups with a selected kinetic copolymerization parameter r1 of less than 1.0 relative to one of the first and second ethylenically unsaturated (polymerizable) groups as defined above.
摘要翻译： 描述了用于形成隐形眼镜的组合物，特别是用于形成硅氧水凝胶隐形眼镜的组合物，其包含至少一种具有一个第一烯属不饱和基团的至少一种第一乙烯基单体或大分子单体和至少一种具有一个第二烯属不饱和基团的第二乙烯基单体或大分子单体 基团，其中所述第一和第二烯属不饱和基团彼此不同，并且其中所述组合物还包含具有至少两个烯键式不饱和（可聚合）基团的交联剂，其中选择的动力学共聚参数r1相对于所述第一 和第二烯属不饱和（可聚合）基团。
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公开(公告)号：US20100276824A1
公开(公告)日：2010-11-04
申请号：US12834998
申请日：2010-07-13
摘要： The instant invention pertains to a method and a fluid composition for producing contact lenses with improved lens quality and with increased product yield. The method of the invention involves adding a phospholipid into a fluid composition including a lens-forming material in an amount sufficient to reduce an averaged mold separation force by at least about 40% in comparison with that without the phospholipids.
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公开(公告)号：US6156244A
公开(公告)日：2000-12-05
申请号：US180588
申请日：1998-11-12
申请人： Achim Muller , Beat Muller , Bernhard Seiferling , Iris Leder
发明人： Achim Muller , Beat Muller , Bernhard Seiferling , Iris Leder
CPC分类号： G02B1/043 , C08F8/12 , C08F2800/10 , C08F2810/20
摘要： The present invention relates to a process for the preparation of storage-stable hydrogel mouldings, the storage stability of which can be established by controlled hydrolysis. At the same time as the sotrage stability is established, the hydrogel is sterilised in its final packaging, and the salt concentration of the aqueous phase is adjusted preferably to a physiological range.
摘要翻译： PCT No.PCT / EP97 / 02477。 371日期：1998年11月12日 102（e）日期1998年11月12日PCT提交1997年5月15日PCT公布。 公开号WO97 / 44687 日期1997年11月27日本发明涉及一种制备储存稳定型水凝胶模塑制品的方法，其储存稳定性可通过可控制的水解来建立。 在稳定性稳定的同时，将水凝胶在其最终包装中灭菌，并将水相的盐浓度优选调节至生理范围。
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58.发明授权Method and composition for incorporating radiation-absorbing agents into polymers 有权将辐射吸收剂掺入聚合物中的方法和组合物
公开(公告)号：US6149692A
公开(公告)日：2000-11-21
申请号：US141128
申请日：1998-08-27
申请人： John Martin Lally , Deborah Jean Mulcahy , Achim Muller , Beat Muller , Bernhard Seiferling , Friedrich Stockinger
发明人： John Martin Lally , Deborah Jean Mulcahy , Achim Muller , Beat Muller , Bernhard Seiferling , Friedrich Stockinger
CPC分类号： G02B1/043 , C08F290/04 , D06P1/0064 , D06P3/58 , D06P5/2005
摘要： A method of incorporating dyes into polymeric materials. The method involved contacting a functionalized dye with a high molecular weight crosslinkable polymer precursor, dispensing the solution into a mold and applying radiation, thereby forming a molded article having dye covalently bonded to the polymer backbone. A preferred product is a visibility tinted disposable contact lens comprising poly(vinyl alcohol). Various embodiments of the innovative method offer advantages in reduced fabrication cycles, reduced extractables, elimination of post-polymerization activation steps, elimination of post-polymerization extraction steps and reduced scrap and costs associated with lens handling.
摘要翻译： 将染料掺入聚合物材料的方法。 该方法包括使官能化染料与高分子量可交联聚合物前体接触，将溶液分配到模具中并施加辐射，从而形成具有共价键合到聚合物主链上的染料的模制品。 优选的产品是包括聚（乙烯醇）的可见度着色的一次性隐形眼镜。 创新方法的各种实施方案在减少制造周期，减少的可萃取物，消除后聚合活化步骤，消除后聚合萃取步骤以及降低的废料以及与透镜处理相关的成本方面提供了优点。
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公开(公告)号：US5665840A
公开(公告)日：1997-09-09
申请号：US552649
申请日：1995-11-03
CPC分类号： G02B1/043 , C08F8/44 , C08F2800/20 , C08F2810/50
摘要： The present invention describes a water-soluble crosslinkable prepolymer that comprises, in the copolymer chain, units derived from the following monomeric structural units: a vinyl lactam (a), vinyl alcohol (b), optionally a lower alkanecarboxylic acid vinyl ester (c), a vinylic crosslinking agent (d) and optionally a vinylic photoinitiator (e); a process for the preparation of the novel prepolymers; crosslinked water-insoluble polymeric networks therefrom; hydrogels and moulded articles made from the crosslinked water-insoluble polymeric networks, especially contact lenses; and a process for the manufacture of hydrogels and finished contact lenses using the mentioned crosslinkable water-soluble prepolymers.
摘要翻译： 本发明描述了一种水溶性可交联预聚物，其在共聚物链中包含衍生自以下单体结构单元的单元：乙烯基内酰胺（a），乙烯醇（b），任选的低级链烷羧酸乙烯基酯（c） 乙烯基交联剂（d）和任选的乙烯基光引发剂（e）; 一种制备新型预聚物的方法; 交联的水不溶性聚合物网络; 由交联的水不溶性聚合物网络制成的水凝胶和模塑制品，特别是隐形眼镜; 以及使用所述可交联水溶性预聚物制造水凝胶和成品隐形眼镜的方法。
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