Hydrodesulfurization with a metal halide-hydrogen halide catalyst
    52.
    发明授权
    Hydrodesulfurization with a metal halide-hydrogen halide catalyst 失效
    用金属卤化物 - 卤化氢催化剂加氢脱硫

    公开(公告)号:US4043900A

    公开(公告)日:1977-08-23

    申请号:US628588

    申请日:1975-11-04

    申请人: Michael Siskin

    发明人: Michael Siskin

    CPC分类号: C10G45/04 B01J27/08 B01J35/12

    摘要: Organic sulfur compounds are removed from hydrocarbon feedstocks by contacting said feedstocks with a catalyst system comprising a difficultly reducible metal halide and a hydrogen halide, said contacting being done in the presence of hydrogen. The preferred metal halide is tantalum pentafluoride, niobium pentafluoride or mixtures thereof. The preferred hydrogen halide is hydrogen fluoride.

    摘要翻译: 通过使所述原料与包含难以还原的金属卤化物和卤化氢的催化剂体系接触,从烃原料中除去有机硫化合物,所述接触在氢的存在下进行。 优选的金属卤化物是五氟化钽,五氟化铌或其混合物。 优选的卤化氢是氟化氢。

    High cyclic capacity amines for high efficiency CO2 scrubbing processes
    54.
    发明授权
    High cyclic capacity amines for high efficiency CO2 scrubbing processes 有权
    高循环量胺用于高效CO2洗涤工艺

    公开(公告)号:US09272242B2

    公开(公告)日:2016-03-01

    申请号:US13933614

    申请日:2013-07-02

    IPC分类号: B01D53/14 B01D53/62 C10L3/10

    摘要: A high cyclic capacity carbon dioxide scrubbing process contacts a gas stream containing carbon dioxide in a sorption zone with a liquid scrubbing solution of a low molecular weight sterically hindered amine, particularly a secondary alkanolamine or aminoether at a high concentration, typically at least 3.5M and at a temperature of at least 30° C. to sorb the carbon dioxide into the solution and form a rich stream of the sorbed carbon dioxide in the solution in the form of dissolved amine carbamate and/or alkanolamine bicarbonate. The rich stream is then passed from the sorption zone to at least one regeneration zone and the sorbed carbon dioxide is desorbed as gas from the solution to form a lean solution containing a reduced concentration of sorbed carbon dioxide relative to the rich stream; the lean stream is then returned to the sorption zone for a further sorption cycle.

    摘要翻译: 高循环容量的二氧化碳洗涤方法在吸附区中与含有低分子量空间位阻胺的液体洗涤溶液,特别是高浓度,典型地至少为3.5M的仲烷醇胺或氨基醚接触含有二氧化碳的气流, 在至少30℃的温度下将二氧化碳吸附到溶液中,并以溶解的胺氨基甲酸酯和/或链烷醇胺碳酸氢盐的形式在溶液中形成富含二氧化碳的富流。 然后将富流从吸附区传递到至少一个再生区,并且吸附的二氧化碳作为气体从溶液中解吸,形成相对于富流而含有降低浓度的吸附二氧化碳的贫溶液; 然后将贫流返回到吸附区以进一步吸附循环。

    HIGH CYCLIC CAPACITY AMINES FOR HIGH EFFICIENCY CO2 SCRUBBING PROCESSES
    57.
    发明申请
    HIGH CYCLIC CAPACITY AMINES FOR HIGH EFFICIENCY CO2 SCRUBBING PROCESSES 有权
    高效CO2二氧化碳清洗工艺的高循环性能

    公开(公告)号:US20140030177A1

    公开(公告)日:2014-01-30

    申请号:US13933614

    申请日:2013-07-02

    IPC分类号: B01D53/62

    摘要: A high cyclic capacity carbon dioxide scrubbing process contacts a gas stream containing carbon dioxide in a sorption zone with a liquid scrubbing solution of a low molecular weight sterically hindered amine, particularly a secondary alkanolamine or aminoether at a high concentration, typically at least 3.5M and at a temperature of at least 30° C. to sorb the carbon dioxide into the solution and form a rich stream of the sorbed carbon dioxide in the solution in the form of dissolved amine carbamate and/or alkanolamine bicarbonate. The rich stream is then passed from the sorption zone to at least one regeneration zone and the sorbed carbon dioxide is desorbed as gas from the solution to form a lean solution containing a reduced concentration of sorbed carbon dioxide relative to the rich stream; the lean stream is then returned to the sorption zone for a further sorption cycle.

    摘要翻译: 高循环容量的二氧化碳洗涤方法在吸附区中与含有低分子量空间位阻胺的液体洗涤溶液,特别是高浓度,典型地至少为3.5M的仲烷醇胺或氨基醚接触含有二氧化碳的气流, 在至少30℃的温度下将二氧化碳吸附到溶液中,并以溶解的胺氨基甲酸酯和/或链烷醇胺碳酸氢盐的形式在溶液中形成富含二氧化碳的富流。 然后将富流从吸附区传递到至少一个再生区,并且吸附的二氧化碳作为气体从溶液中解吸,形成相对于富流而含有降低浓度的吸附二氧化碳的贫溶液; 然后将贫流返回到吸附区以进一步吸附循环。

    Biomass conversion using carbon monoxide and water
    58.
    发明授权
    Biomass conversion using carbon monoxide and water 有权
    使用一氧化碳和水的生物质转化

    公开(公告)号:US08502003B2

    公开(公告)日:2013-08-06

    申请号:US13038060

    申请日:2011-03-01

    IPC分类号: C10L1/00

    摘要: A lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the biomass material with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass material from 0.5:1 to 5.0:1, to dissolve the biomass material into the reaction mixture and depolymerize, deoxygenate and hydrogenate the lignocellulose biomass material, so converting the biomass material into liquid transportation fuel precursors.

    摘要翻译: 木质纤维素生物质材料通过使生物质材料与水和一氧化碳在升高的温度(通常为280-350℃),升高的压力(通常为12-30MPa的总体系压力)接触而转化为液体烃运输燃料的前体 和5〜10MPa的CO分压和水:生物质材料的重量比为0.5:1至5.0:1,将生物质材料溶解到反应混合物中,解聚,脱氧和氢化木质纤维素生物质材料,从而转化 生物质材料成为液体运输燃料前体。

    Biomass oil conversion using carbon monoxide and water
    59.
    发明授权
    Biomass oil conversion using carbon monoxide and water 有权
    使用一氧化碳和水的生物质油转化

    公开(公告)号:US08500829B2

    公开(公告)日:2013-08-06

    申请号:US13038093

    申请日:2011-03-01

    IPC分类号: C10L1/00

    摘要: A pyrolysis oil derived from a lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the oil with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass oil from 0.5:1 to 5.0:1, to dissolve the oil into the reaction mixture and depolymerize, deoxygenate and hydrogenate the oil, so converting it into liquid transportation fuel precursors.

    摘要翻译: 衍生自木质纤维素生物质材料的热解油通过使油与水和一氧化碳在升高的温度(通常为280至350℃)下接触而转化为液体烃运输燃料的前体,升高的压力通常为 12〜30MPa,CO分压为5〜10MPa,水:生物质油的重量比为0.5:1〜5.0:1,将油溶解于反应混合物中,对油进行脱氧,氢化, 将其转化为液体运输燃料前体。

    Alkanolamine CO2 Scrubbing Process
    60.
    发明申请
    Alkanolamine CO2 Scrubbing Process 有权
    烷醇胺二氧化碳洗涤工艺

    公开(公告)号:US20120063980A1

    公开(公告)日:2012-03-15

    申请号:US13229174

    申请日:2011-09-09

    IPC分类号: B01D53/96 B01D53/62

    摘要: A CO2 amine scrubbing process uses an absorbent mixture consisting of an alkanolamine CO2 sorbent in combination with a non-nucleophilic base. The alkanolamine has oxygen and nitrogen sites capable of nucleophilic attack at the CO2 carbon atom. The nucleophilic addition is promoted in the presence of the non-nucleophilic, relatively stronger base, acting as a proton acceptor. The non-nucleophilic base promoter, which may also act as a solvent for the alkanolamine, can promote reaction with the CO2 at each of the reactive hydroxyl and nucleophilic amine group(s) of the alkanolamines. In the case of primary amino alkanolamines the CO2 may be taken up by a double carboxylation reaction in which two moles of CO2 are taken up by the reacting primary amine groups.

    摘要翻译: CO 2胺洗涤方法使用由链烷醇胺CO 2吸附剂与非亲核基团组合组成的吸收混合物。 链烷醇胺具有能够在CO 2碳原子上亲核攻击的氧和氮位点。 在非亲核相对较强的碱存在下促进亲核加成,作为质子受体。 还可以作为烷醇胺溶剂的非亲核碱基启动子可以促进与链烷醇胺的各反应性羟基和亲核胺基团中的CO 2的反应。 在伯氨基链烷醇胺的情况下,CO 2可以被双羧化反应吸收,其中两摩尔CO 2被伯胺基团反应。