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公开(公告)号：US4461696A
公开(公告)日：1984-07-24
申请号：US488172
申请日：1983-04-25
申请人： Jan Bock , Patrick P. McCall , Max L. Robbins , Michael Siskin
发明人： Jan Bock , Patrick P. McCall , Max L. Robbins , Michael Siskin
IPC分类号： C10G1/04
CPC分类号： C10G1/04
摘要： Disclosed is a process for converting organic material of oil-shale to predominantly liquids. The oil-shale is first heated to a temperature from about 360.degree. C. to 475.degree. C. in an inert atmosphere. The resulting liquids and gases are collected and the residue is extracted with a microemulsion capable of extracting organic material from the heat treated oil-shale.
摘要翻译： 公开了将油页岩的有机材料转化为主要液体的方法。 首先将油页岩在惰性气氛中加热至约360℃至475℃的温度。 收集所得液体和气体，并用能够从经热处理的油页岩中提取有机材料的微乳液提取残余物。
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公开(公告)号：US4458757A
公开(公告)日：1984-07-10
申请号：US488171
申请日：1983-04-25
申请人： Jan Bock , Patrick P. McCall , Max L. Robbins , Michael Siskin
发明人： Jan Bock , Patrick P. McCall , Max L. Robbins , Michael Siskin
摘要： Disclosed is a process for converting organic material of oil-shale to predominantly liquids. The oil-shale is first heated to a temperature from about 360.degree. C. to 475.degree. C. in an anionic atmosphere. The resulting liquids and gases are collected and the residue is extracted with a microemulsion capable of extracting organic material from the heat treated oil-shale.
摘要翻译： 公开了将油页岩的有机材料转化为主要液体的方法。 首先将油页岩在阴离子气氛中加热至约360℃至475℃的温度。 收集所得液体和气体，并用能够从经热处理的油页岩中提取有机材料的微乳液提取残余物。
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公开(公告)号：US5436160A
公开(公告)日：1995-07-25
申请号：US190391
申请日：1994-02-02
申请人： Ramesh Varadaraj , Jan Bock , Max L. Robbins
发明人： Ramesh Varadaraj , Jan Bock , Max L. Robbins
摘要： The bioremediation of hydrocarbon contaminated soil is enhanced by applying to the soil a hydrocarbon solution of a surfactant selected from the group consisting of: (a) mixture of a sorbitan ester of a C.sub.7 to C.sub.22 monocarboxylic acid and a polyoxyalkylene adduct of a sorbitan monoester of a C.sub.7 to C.sub.22 monocarboxylic acid, the adduct having from 6 to 50 polyoxyalkylene units, (b) an alkyl glycoside wherein the alkyl group has from about 8 to about 18 carbon atoms and the glycoside is a mono or diglycoside and (c) a mixture of (a) and (b) and (c) and thereafter applying microbial nutrients to the soil in amounts sufficient to promote the growth of indigenous microorganisms.
摘要翻译： 通过向土壤施用选自以下的表面活性剂的烃溶液来增强碳氢化合物污染土壤的生物修复：（a）C7至C22单羧酸的脱水山梨糖醇酯与脱水山梨糖醇单酯的聚氧化烯加合物的混合物 C7至C22单羧酸，加合物具有6至50个聚氧化烯单元，（b）烷基糖苷，其中烷基具有约8至约18个碳原子，糖苷为单或二糖苷和（c）混合物 （a）和（b）和（c），然后以足以促进本地微生物生长的量将微生物营养素施用于土壤。
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4.发明授权
公开(公告)号：US5624843A
公开(公告)日：1997-04-29
申请号：US395217
申请日：1995-02-27
申请人： Ramesh Varadaraj , Jan Bock , Max L. Robbins
发明人： Ramesh Varadaraj , Jan Bock , Max L. Robbins
摘要： The biodegradation of hydrocarbon contaminated water is enhanced by the adding to the contaminated water a hydrocarbon solution of (a) a mixture of a sorbitan ester of a C.sub.7 to C.sub.22 monocarboxylic acid and a polyoxyalkelene adduct of a sorbitan ester of a C.sub.7 to C.sub.22 monocarboxylic acid, the adduct having from 4 to 50 polyoxyalkelene units, (b) an alkyl glycoside wherein the alkyl group has from about 8 to 18 carbon atoms and the gylcoside is a mono or diglycoside, or a mixture thereof, in amounts sufficient to promote the growth of indigenous microorganisms.In another embodiment of the invention a source of microbial assimilable nitrogen and phosphorous also is supplied to the contaminated water.
摘要翻译： 通过向受污染的水中加入（a）C7至C22单羧酸的脱水山梨糖醇酯与C7至C22单羧酸的脱水山梨醇酯的聚氧代烯烃加合物的烃溶液，从而提高烃污染水的生物降解性 ，加合物具有4至50个聚氧化烯单元，（b）烷基糖苷，其中烷基具有约8至18个碳原子，并且gylcoside是单或二糖苷或其混合物，其量足以促进生长 的土着微生物。 在本发明的另一个实施方案中，也可将污染水中的微生物可同化氮和磷源。
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公开(公告)号：US4978459A
公开(公告)日：1990-12-18
申请号：US305139
申请日：1989-02-02
申请人： Jan Bock , Gerard P. Canevari , Max L. Robbins
发明人： Jan Bock , Gerard P. Canevari , Max L. Robbins
CPC分类号： C02F1/682 , B01F17/00 , B01F17/0085 , C09K3/32 , F02B3/06 , Y10S210/925 , Y10S516/03 , Y10S516/04 , Y10S516/05
摘要： A method for dispersing an oil spill on sea water, which method comprises applying to the oil spill surface an effective amount of: (i) a blend of one or more hydrophilic and one or more lipophilic surfactants so balanced that they will form microemulsions with the sea water and the oil to be dispersed; (ii) a solvent which is miscible with the oil to be dispersed and in which the blend of surfactants is substantially soluble; and (iii) from 0 to about 10 weight percent water, wherein the blend of surfactants is such that it lowers the interfacial tension between the oil to be dispersed and the sea water to less than about 250 mdynes/cm when the blend is used at a treat rate of less than about 1 to 100 by weight, based on the oil to be dispersed, wherein the solvent is a hydrocarbon solvent selected from the group consisting of No. 2 diesel fuel oil, kerosene and white oil.
摘要翻译： 一种将溢油分散在海水上的方法，该方法包括向油溢出表面施加有效量的：（i）一种或多种亲水表面活性剂和一种或多种亲脂性表面活性剂的共混物，其平衡以致它们将形成微乳液， 海水和油分散; （ii）与要分散的油混溶的溶剂，其中表面活性剂的共混物基本上可溶; 和（iii）0至约10重量％的水，其中所述表面活性剂的共混物使得当所述共混物用于所述共混物时，将所述待分散的油和所述海水之间的界面张力降低至小于约250mdynes / 基于待分散的油，小于约1至100重量％的处理速率，其中所述溶剂是选自2号柴油燃料油，煤油和白油的烃溶剂。
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公开(公告)号：US4599250A
公开(公告)日：1986-07-08
申请号：US442879
申请日：1982-11-19
申请人： Virgil H. Cargle , Max L. Robbins , Jan Bock
发明人： Virgil H. Cargle , Max L. Robbins , Jan Bock
摘要： A method for treating particulate solids such as coal to reduce the cohesive strength of such solids when frozen which consists of spraying said solids with a hydrocarbon liquid solution of a balanced blend of surfactants which blend will form a single phase microemulsion at 20.degree. C. when added to water at the salinity of the water on said solids at a water to hydrocarbon ratio in the range between 99:1 and 85:15, said blend represented by the monoethanol amine salt of dodecyl o-xylene sulfonic acid and a dinonylphenol reacted with 9 moles of ethylene oxide, onto the wetted surface of said solids to form a single phase microemulsion which is optimally designed to undergo a lipophilic shift upon contacting the surface of said particles whereby an in-situ water-in-oil coarse emulsion is formed on the surfaces of said particles.
摘要翻译： 一种处理颗粒固体如煤的方法，用于降低冷冻时固体的内聚强度，该方法包括将表面活性剂的平衡混合物的烃液体溶液喷雾，所述表面活性剂的混合物将在20℃下形成单相微乳液， 以99:1至85:15范围内的水与烃的比例在所述固体上的水的盐度下加入到水中，所述由十二烷基邻二甲苯磺酸的单乙醇胺盐和二壬基苯酚反应的共混物与 9摩尔环氧乙烷到所述固体的润湿表面上以形成单相微乳液，其被最佳地设计成在接触所述颗粒的表面时经历亲脂性变换，由此在所述颗粒上形成原位上的水包油粗乳液 所述颗粒的表面。
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公开(公告)号：US4684473A
公开(公告)日：1987-08-04
申请号：US846007
申请日：1986-03-31
申请人： Jan Bock , Darrell W. Brownawell , Antonio Gutierrez , Max L. Robbins , Harold Shaub , Peter L. Steyn
发明人： Jan Bock , Darrell W. Brownawell , Antonio Gutierrez , Max L. Robbins , Harold Shaub , Peter L. Steyn
IPC分类号： C10M141/10 , C10M161/00 , C10M125/24 , C10M129/92
CPC分类号： C10M141/10 , C10M161/00 , C10M2207/021 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2209/102 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricating oil composition having improved friction reducing properties and the method of reducing friction in internal combustion engines by lubricating said engines with said lubricating oil which contains an effective friction reducing amount of an additive which is the reaction product of dimer carboxylic acid and a polyhydric alcohol having at least 2 hydroxyl groups in combination with an oil soluble alkanol or an oil soluble alkyl phosphate.
摘要翻译： 一种具有改善的摩擦降低性能的润滑油组合物和通过用所述润滑油润滑所述发动机来减少内燃机中的摩擦的方法，所述润滑油含有有效减摩量的作为二聚羧酸和多元醇的反应产物的添加剂 具有至少2个羟基与油溶性链烷醇或油溶性烷基磷酸酯组合。
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公开(公告)号：US4938877A
公开(公告)日：1990-07-03
申请号：US309632
申请日：1989-02-13
申请人： Jan Bock , Max L. Robbins , Gerard P. Canevari
发明人： Jan Bock , Max L. Robbins , Gerard P. Canevari
CPC分类号： C02F11/12 , B01D17/00 , B01D17/047
摘要： The present invention relates to a method for separating water and oil from a sludge which contains water, oil and solids which method comprises (1) contacting the sludge with an effective amount of 1 or more surfactants chosen and balanced to form certain types of microemulsions with equal volumes of decane and 3% aqueous NaCl, (2) mixing said surfactants and sludge with sufficient agitation to obtain a uniform mixture, (3) allowing said mixture to stand under gravitational settling or centrifugation to obtain the separation from the bottom sediment of an aqueous phase which may contain solubilized oil with or without an additional floating oil phase, (4) decanting separately the oil and aqueous phases and (5) further treating the aqueous phase with heat and/or NaCl to separate the solubilized oil or further treating the bottom sediment with selected surfactants to release adhering oil.
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公开(公告)号：US4764285A
公开(公告)日：1988-08-16
申请号：US50
申请日：1987-01-02
申请人： Max L. Robbins , Gerard P. Canevari , Jan Bock
发明人： Max L. Robbins , Gerard P. Canevari , Jan Bock
CPC分类号： B01F17/0085 , B01F17/00 , C02F1/682 , C09K3/32 , F02B3/06 , Y10S210/925 , Y10S516/03 , Y10S516/04 , Y10S516/05 , Y10S516/907 , Y10S516/908 , Y10S516/909 , Y10S516/91 , Y10S516/914 , Y10S516/915 , Y10S516/916 , Y10S516/918 , Y10S516/92
摘要： Disclosed is a method for dispersing an oil spill on sea water which method comprises applying to the oil spill surface an effective amount of: (i) a blend of one or more hydrophilic and one or more lipophilic surfactants whose ratio is so adjusted that they will form microemulsions with the sea water and the oil to be dispersed, (ii) a solvent which is miscible with the oil to be dispersed and in which the blend of surfactants is substantially soluble, and (iii) from 0 to about 10 wt. % water. The blend of surfactants is such that it lowers the interfacial tension between the oil to be dispersed and the sea water to less than about 250 mdynes/cm when the blend is used at a treat rate of less than about 1 to 100 by weight, based on the weight of the oil to be dispersed.
摘要翻译： 公开了一种将漏油泄漏到海水上的方法，该方法包括向溢油表面施加有效量的：（i）一种或多种亲水和一种或多种亲脂性表面活性剂的混合物，其比例如此调节， 与海水和油分散形成微乳液，（ii）与要分散的油混溶并且其中表面活性剂的共混物基本上可溶的溶剂，和（iii）0至约10wt。 ％ 水。 表面活性剂的混合物使得当共混物以小于约1至100重量％的处理速率使用时，其将要分散的油和海水之间的界面张力降低至小于约250mdynes / cm，基于 关于要分散的油的重量。
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10.发明授权Surface active metal chelated nutrients for bioremediation of hydrocarbon contaminated soils and water 失效表面活性金属螯合营养物质用于碳氢化合物污染土壤和水的生物修复
公开(公告)号：US5571715A
公开(公告)日：1996-11-05
申请号：US375748
申请日：1995-01-20
CPC分类号： C02F1/682 , B09C1/10 , C11D3/32 , C12N1/38 , Y10S210/925 , Y10S516/02 , Y10S516/07
摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a composition comprising of a metal chelated macrocyclic amido amines or mixtures thereof represented by the structural formula: ##STR1## where R is selected from linear or branched alkanes with 8 to 22 carbons, linear or branched alkenes with 4 to 22 carbon atoms;T.sub.1, T.sub.2 and T.sub.3 are independently selected from ethylene, trimethylene, CH.sub.2 CH.sub.2 (NHCH.sub.2 CH.sub.2).sub.x where x is an integer from 1 to 10;MaQb is a metal compound wherein M is a cation selected from cations of Fe, Co, Ni, Cu, Zn, and Mn; and,Q is an anion selected from nitrate, phosphate anions; and a and b are integers from 1 to 3 necessary to satisfy the valence requirements of M and Q.a phosphorous source, and a diluent.
摘要翻译： 本发明通过用包含金属螯合的大环酰氨基胺或其混合物的组合物处理土壤或水来提供碳氢化合物污染的土壤和水的增强的生物修复，其结构式如下：其中R选自直链或支链烷烃 具有8至22个碳，具有4至22个碳原子的直链或支链烯烃; T1，T2和T3独立地选自乙烯，三亚甲基，CH 2 CH 2（NHCH 2 CH 2）x，其中x是1至10的整数; MaQb是金属化合物，其中M是选自Fe，Co，Ni，Cu，Zn和Mn的阳离子的阳离子; Q为选自硝酸盐，磷酸盐阴离子的阴离子; a和b是满足M和Q价态要求所必需的1至3的整数，磷源和稀释剂。
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