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    Process for making fullerenes by the laser evaporation of carbon
    51.
    发明授权
    Process for making fullerenes by the laser evaporation of carbon 失效
    通过碳的激光蒸发制备富勒烯的方法

    公开(公告)号：US5300203A

    公开(公告)日：1994-04-05

    申请号：US799404

    申请日：1991-11-27

    申请人： Richard E. Smalley

    发明人： Richard E. Smalley

    IPC分类号： C01B31/02 ,  C01B31/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B31/0206 ,  C01B31/0213 ,  Y10S977/844

    摘要： Fullerenes are generated by vaporizing carbon with a laser beam and maintaining the vaporized carbon at conditions selected to promote fullerene growth and formation. This method of fullerene generation may be used to form new compounds including fullerenes surrounding one or more metal atoms, and fullerenes wherein one or more carbon atoms have been substituted with boron or nitrogen.

    摘要翻译： 富勒烯是通过用激光束蒸发碳而产生的，并且将气化碳保持在选择的条件下以促进富勒烯生长和形成。 产生富勒烯的方法可以用于形成包括一个或多个金属原子周围的富勒烯的新化合物，其中一个或多个碳原子被硼或氮取代的富勒烯。

    Functionalized single-wall carbon nanotubes
    55.
    发明授权
    Functionalized single-wall carbon nanotubes 有权
    功能化单壁碳纳米管

    公开(公告)号：US07527780B2

    公开(公告)日：2009-05-05

    申请号：US09809885

    申请日：2001-03-16

    申请人： John L. Margrave ,  Edward T. Mickelson ,  Robert Hauge ,  Peter Boul ,  Chad Huffman ,  Jie Liu ,  Richard E. Smalley ,  Ken Smith ,  Daniel T. Colbert

    发明人： John L. Margrave ,  Edward T. Mickelson ,  Robert Hauge ,  Peter Boul ,  Chad Huffman ,  Jie Liu ,  Richard E. Smalley ,  Ken Smith ,  Daniel T. Colbert

    IPC分类号： B82B1/00

    CPC分类号： B01J21/18 ,  B01J23/74 ,  B01J23/755 ,  B01J35/006 ,  B01J35/06 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  D01F11/121 ,  Y10S977/74 ,  Y10S977/748 ,  Y10S977/75 ,  Y10S977/843 ,  Y10S977/848

    摘要： This invention is directed to making chemical derivatives of carbon nanotubes and to uses for the derivatized nanotubes, including making arrays as a basis for synthesis of carbon fibers. In one embodiment, this invention also provides a method for preparing single wall carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce single wall carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents will, of course, be dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium. Alternatively, fluorine may be fully or partially removed from fluorine derivatized carbon nanotubes by reacting the fluorine derivatized carbon nanotubes with various amounts of hydrazine, substituted hydrazine or alkyl amine. The present invention also provides seed materials for growth of single wall carbon nanotubes comprising a plurality of single wall carbon nanotubes or short tubular molecules having a catalyst precursor moiety covalently bound or physisorbed on the outer surface of the sidewall to provide the optimum metal cluster size under conditions that result in migration of the metal moiety to the tube end.

    摘要翻译： 本发明涉及制备碳纳米管的化学衍生物和衍生纳米管的用途，包括制备阵列作为碳纤维合成的基础。 在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管，制备具有连接到纳米管侧壁上的取代基的单壁碳纳米管的方法，然后使氟衍生的碳纳米管与 亲核试剂 一些氟取代基被亲核取代取代。 如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管的侧壁上的取代基的单壁碳纳米管。 取代基当然取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。 或者，可以通过使氟衍生的碳纳米管与各种量的肼，取代的肼或烷基胺反应，从氟衍生的碳纳米管中完全或部分地除去氟。 本发明还提供用于生长单壁碳纳米管的种子材料，其包含多个单壁碳纳米管或具有在侧壁的外表面上共价结合或物理吸附的催化剂前体部分的短管状分子，以提供最佳金属簇尺寸 导致金属部分迁移到管端的条件。